Приказ основних података о документу
Acid-catalyzed rearrangement of some steroidal isoxazolidines
dc.creator | Rajković, Milica M. | |
dc.creator | Lorenc, Ljubinka B. | |
dc.creator | Juranić, Ivan | |
dc.creator | Vitnik, Željko | |
dc.creator | Mihailović, Milhailo Lj. | |
dc.date.accessioned | 2021-03-24T13:04:41Z | |
dc.date.available | 2021-03-24T13:04:41Z | |
dc.date.issued | 1999 | |
dc.identifier.issn | 0040-4020 | |
dc.identifier.issn | 1464-5416 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/4391 | |
dc.description.abstract | Acid-catalyzed reaction of the steroidal Δ 1 -unsaturated 3β,5β- epoxyimino compound 2 and Δ 3 -unsaturated 1β,5β-epoxyimino products 3 and 7, results in intramolecular rearrangement involving the N-CH 3 group to give the corresponding perhydro-3,1-oxazine derivatives 9-11. Under similar reaction conditions, the saturated analogues 4, 6 and 8 remain unchanged. The difference in reactivity between the unsaturated and saturated compounds is studied and elucidated by the semiempirical molecular orbital MNDO-PM3 method. | sr |
dc.language.iso | en | sr |
dc.publisher | Elsevier | sr |
dc.relation | The Serbian Academy of Science and Arts | sr |
dc.relation | The Serbian Ministry of Sciences and Technology | sr |
dc.rights | restrictedAccess | sr |
dc.source | Tetrahedron | sr |
dc.subject | steroidal | sr |
dc.subject | rearrangement | sr |
dc.subject | Acid-catalyzed reaction | sr |
dc.subject | semiempirical molecular orbital MNDO-PM3 method | sr |
dc.subject | Isoxazolidines | sr |
dc.subject | Molecular rearrangement | sr |
dc.subject | Perhydro-oxazines | sr |
dc.subject | Seco steroids | sr |
dc.title | Acid-catalyzed rearrangement of some steroidal isoxazolidines | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dcterms.abstract | Рајковић, Милица М.; Витник, Жељко Ј.; Михаиловíћ, Милхаило Љ.; Јуранић, Иван О.; Лоренц, Љубинка Б.; | |
dc.citation.volume | 55 | |
dc.citation.issue | 21 | |
dc.citation.spage | 6681 | |
dc.citation.epage | 6690 | |
dc.identifier.doi | 10.1016/S0040-4020(99)00314-2 | |
dc.identifier.scopus | 2-s2.0-0033591170 | |
dc.type.version | publishedVersion | sr |