Copper(II) complexes of aminopolycarboxylate ligands with N2O2, N2O3 and N2O4 donor sets. The relationship between the ligand structure and molecular geometry of the complex
Abstract
The article presents an overview of the results achieved during the last several decades on the synthesis and structural characterization of copper(II) complexes with different aminopolycarboxylates. Considering the structural varieties in designing aminopolycarboxylate ligands and significant stereochemical flexibility of the corresponding copper(II) complexes to adopt a wide range of coordination geometries, this review is mainly focused on the results related to the crystallographic characterization of the synthesized complexes. The ligands used for the synthesis of copper(II) complexes described in this article contain two amine nitrogen atoms and different number of the carboxylate oxygen donor atoms (N2O2, N2O3 and N2O4-type of ligands). Giving the importance to the biological relevance of the Cu(II) ion and broad aspects of potential application of aminopolycarboxylate ligands in human practice, the presented results could have some important implications for coordination chemis...ts dealing with structural properties of aminopolycarboxylate-copper(II) complexes and their potential medicinal and biological applications.
Keywords:
Aminopolycarboxylate ligands / Copper(II) / Crystal structure analysis / Structural characterizationSource:
Journal of Molecular Structure, 2021, 1232, 130001-Publisher:
- Elsevier
Projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200122 (University of Kragujevac, Faculty of Science) (RS-200122)
- The Serbian Academy of Sciences and Arts under strategic projects programme - grant agreement No. 01-2019-F65 and project of this institution No. F128.
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Institution
IHTMTY - JOUR AU - Stanojević, Ivana M. AU - Glišić, Biljana Đ. AU - Radanović, Dušanka AU - Đuran, Miloš I. PY - 2021 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4369 AB - The article presents an overview of the results achieved during the last several decades on the synthesis and structural characterization of copper(II) complexes with different aminopolycarboxylates. Considering the structural varieties in designing aminopolycarboxylate ligands and significant stereochemical flexibility of the corresponding copper(II) complexes to adopt a wide range of coordination geometries, this review is mainly focused on the results related to the crystallographic characterization of the synthesized complexes. The ligands used for the synthesis of copper(II) complexes described in this article contain two amine nitrogen atoms and different number of the carboxylate oxygen donor atoms (N2O2, N2O3 and N2O4-type of ligands). Giving the importance to the biological relevance of the Cu(II) ion and broad aspects of potential application of aminopolycarboxylate ligands in human practice, the presented results could have some important implications for coordination chemists dealing with structural properties of aminopolycarboxylate-copper(II) complexes and their potential medicinal and biological applications. PB - Elsevier T2 - Journal of Molecular Structure T1 - Copper(II) complexes of aminopolycarboxylate ligands with N2O2, N2O3 and N2O4 donor sets. The relationship between the ligand structure and molecular geometry of the complex VL - 1232 SP - 130001 DO - 10.1016/j.molstruc.2021.130001 ER -
@article{ author = "Stanojević, Ivana M. and Glišić, Biljana Đ. and Radanović, Dušanka and Đuran, Miloš I.", year = "2021", url = "https://cer.ihtm.bg.ac.rs/handle/123456789/4369", abstract = "The article presents an overview of the results achieved during the last several decades on the synthesis and structural characterization of copper(II) complexes with different aminopolycarboxylates. Considering the structural varieties in designing aminopolycarboxylate ligands and significant stereochemical flexibility of the corresponding copper(II) complexes to adopt a wide range of coordination geometries, this review is mainly focused on the results related to the crystallographic characterization of the synthesized complexes. The ligands used for the synthesis of copper(II) complexes described in this article contain two amine nitrogen atoms and different number of the carboxylate oxygen donor atoms (N2O2, N2O3 and N2O4-type of ligands). Giving the importance to the biological relevance of the Cu(II) ion and broad aspects of potential application of aminopolycarboxylate ligands in human practice, the presented results could have some important implications for coordination chemists dealing with structural properties of aminopolycarboxylate-copper(II) complexes and their potential medicinal and biological applications.", publisher = "Elsevier", journal = "Journal of Molecular Structure", title = "Copper(II) complexes of aminopolycarboxylate ligands with N2O2, N2O3 and N2O4 donor sets. The relationship between the ligand structure and molecular geometry of the complex", volume = "1232", pages = "130001", doi = "10.1016/j.molstruc.2021.130001" }
Stanojević IM, Glišić BĐ, Radanović D, Đuran MI. Copper(II) complexes of aminopolycarboxylate ligands with N2O2, N2O3 and N2O4 donor sets. The relationship between the ligand structure and molecular geometry of the complex. Journal of Molecular Structure. 2021;1232:130001
Stanojević, I. M., Glišić, B. Đ., Radanović, D.,& Đuran, M. I. (2021). Copper(II) complexes of aminopolycarboxylate ligands with N2O2, N2O3 and N2O4 donor sets. The relationship between the ligand structure and molecular geometry of the complex. Journal of Molecular StructureElsevier., 1232, 130001. https://doi.org/10.1016/j.molstruc.2021.130001
Stanojević Ivana M., Glišić Biljana Đ., Radanović Dušanka, Đuran Miloš I., "Copper(II) complexes of aminopolycarboxylate ligands with N2O2, N2O3 and N2O4 donor sets. The relationship between the ligand structure and molecular geometry of the complex" 1232 (2021):130001, https://doi.org/10.1016/j.molstruc.2021.130001 .