Structural effects in electrocatalysis: Oxidation of ethylene glycol on single crystal gold electrodes in alkaline solutions
Samo za registrovane korisnike
1986
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Ethylene glycol is a potential fuel of practical interest whose electrooxidation has not been studied in detail. This is a complex reaction whose mechanism is far from being understood. It is quite clear, however, that some kind of strongly bound intermediate is formed in the oxidation of ethylene glycol on platinum. This is indicated also by the effects of foreign metal adatoms covering a part of the Pt surface. Thus, pronounced catalytic effects of Pb, Tl and Bi have been observed in alkaline solutions and these are partly based on a suppression of formation and/or adsorption of strongly bound intermediates. In this work the oxidation of ethylene glycol on gold single crystals with the (100), (110) and (111) orientations has been studied with the aim of investigating whether there is structural sensitivity in this reaction. Structural sensitivity, as well as the role of AuOH species formed on surfaces, could be of interest for both electrocatalysis and catalysis.
Ključne reči:
Oxidation of ethylene glycol / alkaline solutions / single crystal gold electrodes / electrode / gold electrode / electrocatalysis / single crystalIzvor:
Journal of Catalysis, 1986, 101, 2, 532-535Izdavač:
- Elsevier
Finansiranje / projekti:
- The Research Fund of SR Serbia, Yugoslavia
- The Department of Energy, Washington, Contract Energy 427
DOI: 10.1016/0021-9517(86)90282-4
ISSN: 0021-9517; 1090-2694
Scopus: 2-s2.0-0342526133
Institucija/grupa
IHTMTY - JOUR AU - Adžić, Radoslav R. AU - Avramov Ivić, Milka PY - 1986 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4312 AB - Ethylene glycol is a potential fuel of practical interest whose electrooxidation has not been studied in detail. This is a complex reaction whose mechanism is far from being understood. It is quite clear, however, that some kind of strongly bound intermediate is formed in the oxidation of ethylene glycol on platinum. This is indicated also by the effects of foreign metal adatoms covering a part of the Pt surface. Thus, pronounced catalytic effects of Pb, Tl and Bi have been observed in alkaline solutions and these are partly based on a suppression of formation and/or adsorption of strongly bound intermediates. In this work the oxidation of ethylene glycol on gold single crystals with the (100), (110) and (111) orientations has been studied with the aim of investigating whether there is structural sensitivity in this reaction. Structural sensitivity, as well as the role of AuOH species formed on surfaces, could be of interest for both electrocatalysis and catalysis. PB - Elsevier T2 - Journal of Catalysis T1 - Structural effects in electrocatalysis: Oxidation of ethylene glycol on single crystal gold electrodes in alkaline solutions VL - 101 IS - 2 SP - 532 EP - 535 DO - 10.1016/0021-9517(86)90282-4 ER -
@article{ author = "Adžić, Radoslav R. and Avramov Ivić, Milka", year = "1986", abstract = "Ethylene glycol is a potential fuel of practical interest whose electrooxidation has not been studied in detail. This is a complex reaction whose mechanism is far from being understood. It is quite clear, however, that some kind of strongly bound intermediate is formed in the oxidation of ethylene glycol on platinum. This is indicated also by the effects of foreign metal adatoms covering a part of the Pt surface. Thus, pronounced catalytic effects of Pb, Tl and Bi have been observed in alkaline solutions and these are partly based on a suppression of formation and/or adsorption of strongly bound intermediates. In this work the oxidation of ethylene glycol on gold single crystals with the (100), (110) and (111) orientations has been studied with the aim of investigating whether there is structural sensitivity in this reaction. Structural sensitivity, as well as the role of AuOH species formed on surfaces, could be of interest for both electrocatalysis and catalysis.", publisher = "Elsevier", journal = "Journal of Catalysis", title = "Structural effects in electrocatalysis: Oxidation of ethylene glycol on single crystal gold electrodes in alkaline solutions", volume = "101", number = "2", pages = "532-535", doi = "10.1016/0021-9517(86)90282-4" }
Adžić, R. R.,& Avramov Ivić, M.. (1986). Structural effects in electrocatalysis: Oxidation of ethylene glycol on single crystal gold electrodes in alkaline solutions. in Journal of Catalysis Elsevier., 101(2), 532-535. https://doi.org/10.1016/0021-9517(86)90282-4
Adžić RR, Avramov Ivić M. Structural effects in electrocatalysis: Oxidation of ethylene glycol on single crystal gold electrodes in alkaline solutions. in Journal of Catalysis. 1986;101(2):532-535. doi:10.1016/0021-9517(86)90282-4 .
Adžić, Radoslav R., Avramov Ivić, Milka, "Structural effects in electrocatalysis: Oxidation of ethylene glycol on single crystal gold electrodes in alkaline solutions" in Journal of Catalysis, 101, no. 2 (1986):532-535, https://doi.org/10.1016/0021-9517(86)90282-4 . .