Bio-membrane based on modified cellulose, lignin, and tannic acid for cation and oxyanion removal: Experimental and theoretical study
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2021
Authors
Perendija, Jovana
Veličković, Zlate S.

Cvijetić, Ilija

Lević, Steva
Marinković, Aleksandar D.

Milošević, Milena

Onjia, Antonije

Article (Published version)

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Two optimized methods, based on epoxy-amino reactivity of the Cellulose fibres (Cell) modified with diethylenetriamine (Cell‒DETA), (3-Glycidyloxypropyl)trimethoxysilane (Cell-Glymo), Lignin modified with epichlorohydrine (EL) and Tannic acid (TA), as an additional crosslinker, were developed for the production of the bio-renewable Cell-EL and Cell-EL-TA membranes. The influences of pH, contact time, adsorbent dose, and temperature on adsorption performances were studied by batch adsorption tests. The calculated capacities: 53.9, 99.9, 97.8 and 63.5, 115.8, 127.5 mg g−1 for Ni2+, Pb2+, Cr(VI) using Cell-EL and Cell-EL-TA, respectively, were obtained from Langmuir model fitting at 25 °C. The thermodynamic parameters indicated spontaneous and low endothermic processes. The results of the kinetic study, i.e. pseudo-second-order (PSO) and Weber-Morris (W-M), suggest an intra-particle diffusion as a rate-limiting step. The semi-empirical quantum chemical calculations aided the analysis of t...he non-specific and specific adsorbent/adsorbate interactions and their contribution to the overall bonding mechanism. Membrane utility was confirmed by performing a bed column study. In general, three main environmental issues of the present study, biodegradability of the used membrane, desorption efficiency, and development of the technology for the effective effluent water treatment and safe disposal of by-products highly conform to the demand of integrated environmental management system applicability in practice.
Keywords:
Batch and column study / Cellulose membrane / Semi-empirical calculations / Sustainable developmentSource:
Process Safety and Environmental Protection, 2021, 147, 609-625Publisher:
- Institution of Chemical Engineers
- Elsevier
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-200135)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200288 (Innovation Center of the Faculty of Chemistry) (RS-200288)
DOI: 10.1016/j.psep.2020.12.027
ISSN: 0957-5820; 1744-3598
WoS: 000623811400050
Scopus: 2-s2.0-85098779116
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Institution/Community
IHTMTY - JOUR AU - Perendija, Jovana AU - Veličković, Zlate S. AU - Cvijetić, Ilija AU - Lević, Steva AU - Marinković, Aleksandar D. AU - Milošević, Milena AU - Onjia, Antonije PY - 2021 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4229 AB - Two optimized methods, based on epoxy-amino reactivity of the Cellulose fibres (Cell) modified with diethylenetriamine (Cell‒DETA), (3-Glycidyloxypropyl)trimethoxysilane (Cell-Glymo), Lignin modified with epichlorohydrine (EL) and Tannic acid (TA), as an additional crosslinker, were developed for the production of the bio-renewable Cell-EL and Cell-EL-TA membranes. The influences of pH, contact time, adsorbent dose, and temperature on adsorption performances were studied by batch adsorption tests. The calculated capacities: 53.9, 99.9, 97.8 and 63.5, 115.8, 127.5 mg g−1 for Ni2+, Pb2+, Cr(VI) using Cell-EL and Cell-EL-TA, respectively, were obtained from Langmuir model fitting at 25 °C. The thermodynamic parameters indicated spontaneous and low endothermic processes. The results of the kinetic study, i.e. pseudo-second-order (PSO) and Weber-Morris (W-M), suggest an intra-particle diffusion as a rate-limiting step. The semi-empirical quantum chemical calculations aided the analysis of the non-specific and specific adsorbent/adsorbate interactions and their contribution to the overall bonding mechanism. Membrane utility was confirmed by performing a bed column study. In general, three main environmental issues of the present study, biodegradability of the used membrane, desorption efficiency, and development of the technology for the effective effluent water treatment and safe disposal of by-products highly conform to the demand of integrated environmental management system applicability in practice. PB - Institution of Chemical Engineers PB - Elsevier T2 - Process Safety and Environmental Protection T1 - Bio-membrane based on modified cellulose, lignin, and tannic acid for cation and oxyanion removal: Experimental and theoretical study VL - 147 SP - 609 EP - 625 DO - 10.1016/j.psep.2020.12.027 ER -
@article{ author = "Perendija, Jovana and Veličković, Zlate S. and Cvijetić, Ilija and Lević, Steva and Marinković, Aleksandar D. and Milošević, Milena and Onjia, Antonije", year = "2021", abstract = "Two optimized methods, based on epoxy-amino reactivity of the Cellulose fibres (Cell) modified with diethylenetriamine (Cell‒DETA), (3-Glycidyloxypropyl)trimethoxysilane (Cell-Glymo), Lignin modified with epichlorohydrine (EL) and Tannic acid (TA), as an additional crosslinker, were developed for the production of the bio-renewable Cell-EL and Cell-EL-TA membranes. The influences of pH, contact time, adsorbent dose, and temperature on adsorption performances were studied by batch adsorption tests. The calculated capacities: 53.9, 99.9, 97.8 and 63.5, 115.8, 127.5 mg g−1 for Ni2+, Pb2+, Cr(VI) using Cell-EL and Cell-EL-TA, respectively, were obtained from Langmuir model fitting at 25 °C. The thermodynamic parameters indicated spontaneous and low endothermic processes. The results of the kinetic study, i.e. pseudo-second-order (PSO) and Weber-Morris (W-M), suggest an intra-particle diffusion as a rate-limiting step. The semi-empirical quantum chemical calculations aided the analysis of the non-specific and specific adsorbent/adsorbate interactions and their contribution to the overall bonding mechanism. Membrane utility was confirmed by performing a bed column study. In general, three main environmental issues of the present study, biodegradability of the used membrane, desorption efficiency, and development of the technology for the effective effluent water treatment and safe disposal of by-products highly conform to the demand of integrated environmental management system applicability in practice.", publisher = "Institution of Chemical Engineers, Elsevier", journal = "Process Safety and Environmental Protection", title = "Bio-membrane based on modified cellulose, lignin, and tannic acid for cation and oxyanion removal: Experimental and theoretical study", volume = "147", pages = "609-625", doi = "10.1016/j.psep.2020.12.027" }
Perendija, J., Veličković, Z. S., Cvijetić, I., Lević, S., Marinković, A. D., Milošević, M.,& Onjia, A.. (2021). Bio-membrane based on modified cellulose, lignin, and tannic acid for cation and oxyanion removal: Experimental and theoretical study. in Process Safety and Environmental Protection Institution of Chemical Engineers., 147, 609-625. https://doi.org/10.1016/j.psep.2020.12.027
Perendija J, Veličković ZS, Cvijetić I, Lević S, Marinković AD, Milošević M, Onjia A. Bio-membrane based on modified cellulose, lignin, and tannic acid for cation and oxyanion removal: Experimental and theoretical study. in Process Safety and Environmental Protection. 2021;147:609-625. doi:10.1016/j.psep.2020.12.027 .
Perendija, Jovana, Veličković, Zlate S., Cvijetić, Ilija, Lević, Steva, Marinković, Aleksandar D., Milošević, Milena, Onjia, Antonije, "Bio-membrane based on modified cellulose, lignin, and tannic acid for cation and oxyanion removal: Experimental and theoretical study" in Process Safety and Environmental Protection, 147 (2021):609-625, https://doi.org/10.1016/j.psep.2020.12.027 . .