Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum
Samo za registrovane korisnike
1975
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within the framewor of existing data on the formic acid oxidation and the underpotential deposition. It was found that the catalytic effect of foreign metal monolayers originates in the decrease of hydrogen adsorption thus preventing the formation of the main poisoning species COH. At the same time these experiments confirm the previously postulated mechanism of formation of the poisoning species involving adsorbed hydrogen.
Ključne reči:
foreign metal monolayers / underpotential deposition / catalytic effect / formic acid / platinum / hydrogen adsorption / poisoning / adsorbed hydrogenIzvor:
Journal of Electroanalytical Chemistry, 1975, 65, 2, 587-601Izdavač:
- Elsevier
Finansiranje / projekti:
- Funds for Research of the Republic of Serbia and of the Serbian Academy of Science and Arts
DOI: 10.1016/0368-1874(75)85146-X
ISSN: 1572-6657; 0368-1874
Scopus: 2-s2.0-3242683550
Institucija/grupa
IHTMTY - JOUR AU - Adžić, Radoslav R. AU - Simić, D. N. AU - Despić, Aleksandar R. AU - Dražić, Dragutin M. PY - 1975 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4212 AB - It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within the framewor of existing data on the formic acid oxidation and the underpotential deposition. It was found that the catalytic effect of foreign metal monolayers originates in the decrease of hydrogen adsorption thus preventing the formation of the main poisoning species COH. At the same time these experiments confirm the previously postulated mechanism of formation of the poisoning species involving adsorbed hydrogen. PB - Elsevier T2 - Journal of Electroanalytical Chemistry T1 - Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum VL - 65 IS - 2 SP - 587 EP - 601 DO - 10.1016/0368-1874(75)85146-X ER -
@article{ author = "Adžić, Radoslav R. and Simić, D. N. and Despić, Aleksandar R. and Dražić, Dragutin M.", year = "1975", abstract = "It was demonstrated that some foreign metal monolayers formed by underpotential deposition have pronounced catalytic effects on the oxidation of formic acid on platinum. The explanation of these effects was sought within the framewor of existing data on the formic acid oxidation and the underpotential deposition. It was found that the catalytic effect of foreign metal monolayers originates in the decrease of hydrogen adsorption thus preventing the formation of the main poisoning species COH. At the same time these experiments confirm the previously postulated mechanism of formation of the poisoning species involving adsorbed hydrogen.", publisher = "Elsevier", journal = "Journal of Electroanalytical Chemistry", title = "Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum", volume = "65", number = "2", pages = "587-601", doi = "10.1016/0368-1874(75)85146-X" }
Adžić, R. R., Simić, D. N., Despić, A. R.,& Dražić, D. M.. (1975). Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum. in Journal of Electroanalytical Chemistry Elsevier., 65(2), 587-601. https://doi.org/10.1016/0368-1874(75)85146-X
Adžić RR, Simić DN, Despić AR, Dražić DM. Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum. in Journal of Electroanalytical Chemistry. 1975;65(2):587-601. doi:10.1016/0368-1874(75)85146-X .
Adžić, Radoslav R., Simić, D. N., Despić, Aleksandar R., Dražić, Dragutin M., "Electrocatalysis by foreign metal monolayers: Oxidation of formic acid on platinum" in Journal of Electroanalytical Chemistry, 65, no. 2 (1975):587-601, https://doi.org/10.1016/0368-1874(75)85146-X . .