Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction
Само за регистроване кориснике
1987
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Some of the well-known criteria for analysing rotating disk measurements have been examined. It has been shown that for reactions with complex mechanisms the number of electrons exchanged per reactant is a function of the potential of the electrode and cannot be evaluated theoretically in a simple manner. Also, it has been shown that none of the prescribed methods of obtaining the overall reaction order will give a proper answer unless the number of electrons is known a priori. This couling of the number of electrons exchanged and the overall reaction order is inherent in the rotating disk experiment. Therefore the use of the rotating disk in elucidating the overall kinetic parameters of the process is much more limited than previously thought.
Кључне речи:
rotating disk / Electrochemistry / KinteicsИзвор:
Journal of Electroanalytical Chemistry, 1987, 218, 1-2, 53-63Издавач:
- Elsevier
Финансирање / пројекти:
- The Research Fund of Serbia, Yugoslavia
- The Yugoslav-Amencan Fund for Sclentlflc and Technological Cooperation
- Department of Energy (Project no 553)
DOI: 10.1016/0022-0728(87)87005-5
ISSN: 00220728; 1572-6657
Scopus: 2-s2.0-0001780920
Институција/група
IHTMTY - JOUR AU - Vešović, V. B. AU - Anastasijević, Nikola A. AU - Adžić, Radoslav R. PY - 1987 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4208 AB - Some of the well-known criteria for analysing rotating disk measurements have been examined. It has been shown that for reactions with complex mechanisms the number of electrons exchanged per reactant is a function of the potential of the electrode and cannot be evaluated theoretically in a simple manner. Also, it has been shown that none of the prescribed methods of obtaining the overall reaction order will give a proper answer unless the number of electrons is known a priori. This couling of the number of electrons exchanged and the overall reaction order is inherent in the rotating disk experiment. Therefore the use of the rotating disk in elucidating the overall kinetic parameters of the process is much more limited than previously thought. PB - Elsevier T2 - Journal of Electroanalytical Chemistry T1 - Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction VL - 218 IS - 1-2 SP - 53 EP - 63 DO - 10.1016/0022-0728(87)87005-5 ER -
@article{ author = "Vešović, V. B. and Anastasijević, Nikola A. and Adžić, Radoslav R.", year = "1987", abstract = "Some of the well-known criteria for analysing rotating disk measurements have been examined. It has been shown that for reactions with complex mechanisms the number of electrons exchanged per reactant is a function of the potential of the electrode and cannot be evaluated theoretically in a simple manner. Also, it has been shown that none of the prescribed methods of obtaining the overall reaction order will give a proper answer unless the number of electrons is known a priori. This couling of the number of electrons exchanged and the overall reaction order is inherent in the rotating disk experiment. Therefore the use of the rotating disk in elucidating the overall kinetic parameters of the process is much more limited than previously thought.", publisher = "Elsevier", journal = "Journal of Electroanalytical Chemistry", title = "Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction", volume = "218", number = "1-2", pages = "53-63", doi = "10.1016/0022-0728(87)87005-5" }
Vešović, V. B., Anastasijević, N. A.,& Adžić, R. R.. (1987). Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction. in Journal of Electroanalytical Chemistry Elsevier., 218(1-2), 53-63. https://doi.org/10.1016/0022-0728(87)87005-5
Vešović VB, Anastasijević NA, Adžić RR. Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction. in Journal of Electroanalytical Chemistry. 1987;218(1-2):53-63. doi:10.1016/0022-0728(87)87005-5 .
Vešović, V. B., Anastasijević, Nikola A., Adžić, Radoslav R., "Rotating disk electrode: A re-examination of some kinetic criteria with a special reference to oxygen reduction" in Journal of Electroanalytical Chemistry, 218, no. 1-2 (1987):53-63, https://doi.org/10.1016/0022-0728(87)87005-5 . .