Приказ основних података о документу

dc.creatorTripković, Amalija
dc.creatorPopović, Ksenija
dc.creatorMomčilović, J. D.
dc.creatorDražić, Dragutin M.
dc.date.accessioned2021-02-04T11:11:51Z
dc.date.available2021-02-04T11:11:51Z
dc.date.issued1996
dc.identifier.issn1572-6657
dc.identifier.issn1873-2569
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/4199
dc.description.abstractA comparative study of methanol oxidation on a Pt(111) surface was carried out in bicarbonate, carbonate and different pH values of sodium hydroxide solutions. The surface activity was directly correlated to the OHad species coverage. It was shown that the 'poisoning species', produced in methanol oxidation, participate in the reaction although they partially block the surface, particularly at lower potentials. A dual path reaction mechanism, common to all alkaline solutions used, was proposed. It was based on the assumptions that HCO is a reactive intermediate and that formate is a reaction product in the main path, while CO2 is a product of 'poisoning species' oxidation in a parallel reaction path.sr
dc.language.isoensr
dc.publisherElseviersr
dc.rightsrestrictedAccesssr
dc.sourceJournal of Electroanalytical Chemistrysr
dc.subjectPt(111)electrodesr
dc.subjectmethanol oxidationsr
dc.subjectalkaline solutionssr
dc.subjectOH adsorptionsr
dc.subjectreaction mechanismsr
dc.titleKinetic and mechanistic study of methanol oxidation on a Pt(111) surface in alkaline mediasr
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractМомчиловић, Ј. Д.; Дражић, Драгутин М.; Трипковић, Aмалија; Поповић, Ксенија;
dc.citation.volume418
dc.citation.issue1-2
dc.citation.spage9
dc.citation.epage20
dc.identifier.doi10.1016/S0022-0728(96)04849-8
dc.identifier.scopus2-s2.0-0030289494
dc.identifier.wosA1996WA97600002
dc.type.versionpublishedVersionsr


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Приказ основних података о документу