Boron and phosphorus doped glassy carbon: I. Surface properties
Authorized Users Only
1997
Authors
Đurkić, TatjanaPerić-Grujić, Aleksandra A.

Laušević, Mila D.
Dekanski, Aleksandar

Nešković, Olivera M.
Veljković, Miomir V.
Laušević, Zoran

Article (Published version)

Metadata
Show full item recordAbstract
The effects of boron and phosphorus incorporation in phenolic resin precursor on the surface properties of glassy carbon (GC) have been studied. Characterization of the surface properties using X-ray photoelectron spectroscopy and mass spectrometry analysis of desorption products showed that boron and phosphorus doped GC contained more carbon-oxygen complexes on the surface than undoped GC. The thermal decomposition of the surface oxide species, resulting in desorption of CO and CO2 as major gas products, showed that the presence of heteroatoms affects the nature of the surface oxide species and contributes to their increased stability. The presence of stable surface oxide species promotes the increased oxidation resistance of doped GC samples.
Keywords:
glass-like carbon / bulk doping / photoelectron spectroscopy / surface propertiesSource:
Carbon, 1997, 35, 10-11, 1567-1572Publisher:
- Elsevier
DOI: 10.1016/S0008-6223(97)00113-9
ISSN: 0008-6223; 0008-6223
WoS: 000071081300014
Scopus: 2-s2.0-0031383031
Collections
Institution/Community
IHTMTY - JOUR AU - Đurkić, Tatjana AU - Perić-Grujić, Aleksandra A. AU - Laušević, Mila D. AU - Dekanski, Aleksandar AU - Nešković, Olivera M. AU - Veljković, Miomir V. AU - Laušević, Zoran PY - 1997 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4194 AB - The effects of boron and phosphorus incorporation in phenolic resin precursor on the surface properties of glassy carbon (GC) have been studied. Characterization of the surface properties using X-ray photoelectron spectroscopy and mass spectrometry analysis of desorption products showed that boron and phosphorus doped GC contained more carbon-oxygen complexes on the surface than undoped GC. The thermal decomposition of the surface oxide species, resulting in desorption of CO and CO2 as major gas products, showed that the presence of heteroatoms affects the nature of the surface oxide species and contributes to their increased stability. The presence of stable surface oxide species promotes the increased oxidation resistance of doped GC samples. PB - Elsevier T2 - Carbon T1 - Boron and phosphorus doped glassy carbon: I. Surface properties VL - 35 IS - 10-11 SP - 1567 EP - 1572 DO - 10.1016/S0008-6223(97)00113-9 ER -
@article{ author = "Đurkić, Tatjana and Perić-Grujić, Aleksandra A. and Laušević, Mila D. and Dekanski, Aleksandar and Nešković, Olivera M. and Veljković, Miomir V. and Laušević, Zoran", year = "1997", abstract = "The effects of boron and phosphorus incorporation in phenolic resin precursor on the surface properties of glassy carbon (GC) have been studied. Characterization of the surface properties using X-ray photoelectron spectroscopy and mass spectrometry analysis of desorption products showed that boron and phosphorus doped GC contained more carbon-oxygen complexes on the surface than undoped GC. The thermal decomposition of the surface oxide species, resulting in desorption of CO and CO2 as major gas products, showed that the presence of heteroatoms affects the nature of the surface oxide species and contributes to their increased stability. The presence of stable surface oxide species promotes the increased oxidation resistance of doped GC samples.", publisher = "Elsevier", journal = "Carbon", title = "Boron and phosphorus doped glassy carbon: I. Surface properties", volume = "35", number = "10-11", pages = "1567-1572", doi = "10.1016/S0008-6223(97)00113-9" }
Đurkić, T., Perić-Grujić, A. A., Laušević, M. D., Dekanski, A., Nešković, O. M., Veljković, M. V.,& Laušević, Z.. (1997). Boron and phosphorus doped glassy carbon: I. Surface properties. in Carbon Elsevier., 35(10-11), 1567-1572. https://doi.org/10.1016/S0008-6223(97)00113-9
Đurkić T, Perić-Grujić AA, Laušević MD, Dekanski A, Nešković OM, Veljković MV, Laušević Z. Boron and phosphorus doped glassy carbon: I. Surface properties. in Carbon. 1997;35(10-11):1567-1572. doi:10.1016/S0008-6223(97)00113-9 .
Đurkić, Tatjana, Perić-Grujić, Aleksandra A., Laušević, Mila D., Dekanski, Aleksandar, Nešković, Olivera M., Veljković, Miomir V., Laušević, Zoran, "Boron and phosphorus doped glassy carbon: I. Surface properties" in Carbon, 35, no. 10-11 (1997):1567-1572, https://doi.org/10.1016/S0008-6223(97)00113-9 . .