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Boron and phosphorus doped glassy carbon: I. Surface properties

Authorized Users Only
1997
Authors
Đurkić, Tatjana
Perić-Grujić, Aleksandra A.
Laušević, Mila D.
Dekanski, Aleksandar
Nešković, Olivera M.
Veljković, Miomir V.
Laušević, Zoran
Article (Published version)
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Abstract
The effects of boron and phosphorus incorporation in phenolic resin precursor on the surface properties of glassy carbon (GC) have been studied. Characterization of the surface properties using X-ray photoelectron spectroscopy and mass spectrometry analysis of desorption products showed that boron and phosphorus doped GC contained more carbon-oxygen complexes on the surface than undoped GC. The thermal decomposition of the surface oxide species, resulting in desorption of CO and CO2 as major gas products, showed that the presence of heteroatoms affects the nature of the surface oxide species and contributes to their increased stability. The presence of stable surface oxide species promotes the increased oxidation resistance of doped GC samples.
Keywords:
glass-like carbon / bulk doping / photoelectron spectroscopy / surface properties
Source:
Carbon, 1997, 35, 10-11, 1567-1572
Publisher:
  • Elsevier

DOI: 10.1016/S0008-6223(97)00113-9

ISSN: 0008-6223; 0008-6223

WoS: 000071081300014

Scopus: 2-s2.0-0031383031
[ Google Scholar ]
62
58
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4194
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Đurkić, Tatjana
AU  - Perić-Grujić, Aleksandra A.
AU  - Laušević, Mila D.
AU  - Dekanski, Aleksandar
AU  - Nešković, Olivera M.
AU  - Veljković, Miomir V.
AU  - Laušević, Zoran
PY  - 1997
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4194
AB  - The effects of boron and phosphorus incorporation in phenolic resin precursor on the surface properties of glassy carbon (GC) have been studied. Characterization of the surface properties using X-ray photoelectron spectroscopy and mass spectrometry analysis of desorption products showed that boron and phosphorus doped GC contained more carbon-oxygen complexes on the surface than undoped GC. The thermal decomposition of the surface oxide species, resulting in desorption of CO and CO2 as major gas products, showed that the presence of heteroatoms affects the nature of the surface oxide species and contributes to their increased stability. The presence of stable surface oxide species promotes the increased oxidation resistance of doped GC samples.
PB  - Elsevier
T2  - Carbon
T1  - Boron and phosphorus doped glassy carbon: I. Surface properties
VL  - 35
IS  - 10-11
SP  - 1567
EP  - 1572
DO  - 10.1016/S0008-6223(97)00113-9
ER  - 
@article{
author = "Đurkić, Tatjana and Perić-Grujić, Aleksandra A. and Laušević, Mila D. and Dekanski, Aleksandar and Nešković, Olivera M. and Veljković, Miomir V. and Laušević, Zoran",
year = "1997",
abstract = "The effects of boron and phosphorus incorporation in phenolic resin precursor on the surface properties of glassy carbon (GC) have been studied. Characterization of the surface properties using X-ray photoelectron spectroscopy and mass spectrometry analysis of desorption products showed that boron and phosphorus doped GC contained more carbon-oxygen complexes on the surface than undoped GC. The thermal decomposition of the surface oxide species, resulting in desorption of CO and CO2 as major gas products, showed that the presence of heteroatoms affects the nature of the surface oxide species and contributes to their increased stability. The presence of stable surface oxide species promotes the increased oxidation resistance of doped GC samples.",
publisher = "Elsevier",
journal = "Carbon",
title = "Boron and phosphorus doped glassy carbon: I. Surface properties",
volume = "35",
number = "10-11",
pages = "1567-1572",
doi = "10.1016/S0008-6223(97)00113-9"
}
Đurkić, T., Perić-Grujić, A. A., Laušević, M. D., Dekanski, A., Nešković, O. M., Veljković, M. V.,& Laušević, Z.. (1997). Boron and phosphorus doped glassy carbon: I. Surface properties. in Carbon
Elsevier., 35(10-11), 1567-1572.
https://doi.org/10.1016/S0008-6223(97)00113-9
Đurkić T, Perić-Grujić AA, Laušević MD, Dekanski A, Nešković OM, Veljković MV, Laušević Z. Boron and phosphorus doped glassy carbon: I. Surface properties. in Carbon. 1997;35(10-11):1567-1572.
doi:10.1016/S0008-6223(97)00113-9 .
Đurkić, Tatjana, Perić-Grujić, Aleksandra A., Laušević, Mila D., Dekanski, Aleksandar, Nešković, Olivera M., Veljković, Miomir V., Laušević, Zoran, "Boron and phosphorus doped glassy carbon: I. Surface properties" in Carbon, 35, no. 10-11 (1997):1567-1572,
https://doi.org/10.1016/S0008-6223(97)00113-9 . .

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