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Photolysis of Steroidal 20-Aryl-Substituted 11-Nitrites

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1997
Authors
Kalvoda, Jaroslav
Grob, Jüren
Bjelaković, Mira
Lorenc, Ljubinka
Mihailović, Mihailo Lj.
Article (Published version)
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Abstract
The two structurally similar 20‐phenyl‐ and 20‐(4‐methoxyphenyl)‐11‐(nitrosooxy)pregnan‐20‐ol derivatives 4 and 7 behave differently under photolytic conditions, the former nitrous acid ester affording, as a main product, the benzo‐fused hexacyclic compound 9, and the latter the 21‐nitro derivative 12. Mechanistic aspects of these transformations are discussed.
Keywords:
Steroids / Photolysis / rearrangement
Source:
Helvetica Chimica Acta, 1997, 80, 4, 1221-1228
Publisher:
  • Wiley
Projects:
  • Serbian Academy of Sciences and Arts
  • Ministry of Sciences and Technology of Serbia

DOI: 10.1002/hlca.19970800419

ISSN: 0018-019X

Scopus: 2-s2.0-0009548873
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2
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4188
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  • Radovi istraživača pre dolaska u IHTM / Researchers' papers before joining ICTM
Institution
IHTM

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