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Photolysis of Steroidal 20-Aryl-Substituted 11-Nitrites

Authorized Users Only
1997
Authors
Kalvoda, Jaroslav
Grob, Jüren
Bjelaković, Mira
Lorenc, Ljubinka
Mihailović, Milhailo Lj.
Article (Published version)
Metadata
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Abstract
The two structurally similar 20‐phenyl‐ and 20‐(4‐methoxyphenyl)‐11‐(nitrosooxy)pregnan‐20‐ol derivatives 4 and 7 behave differently under photolytic conditions, the former nitrous acid ester affording, as a main product, the benzo‐fused hexacyclic compound 9, and the latter the 21‐nitro derivative 12. Mechanistic aspects of these transformations are discussed.
Keywords:
Steroids / Photolysis / rearrangement
Source:
Helvetica Chimica Acta, 1997, 80, 4, 1221-1228
Publisher:
  • Wiley
Funding / projects:
  • Serbian Academy of Sciences and Arts
  • Ministry of Sciences and Technology of Serbia

DOI: 10.1002/hlca.19970800419

ISSN: 0018-019X

Scopus: 2-s2.0-0009548873
[ Google Scholar ]
2
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4188
Collections
  • Radovi istraživača pre dolaska u IHTM / Researchers' papers before joining ICTM
Institution/Community
IHTM
TY  - JOUR
AU  - Kalvoda, Jaroslav
AU  - Grob, Jüren
AU  - Bjelaković, Mira
AU  - Lorenc, Ljubinka
AU  - Mihailović, Milhailo Lj.
PY  - 1997
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4188
AB  - The two structurally similar 20‐phenyl‐ and 20‐(4‐methoxyphenyl)‐11‐(nitrosooxy)pregnan‐20‐ol derivatives 4 and 7 behave differently under photolytic conditions, the former nitrous acid ester affording, as a main product, the benzo‐fused hexacyclic compound 9, and the latter the 21‐nitro derivative 12. Mechanistic aspects of these transformations are discussed.
PB  - Wiley
T2  - Helvetica Chimica Acta
T1  - Photolysis of Steroidal 20-Aryl-Substituted 11-Nitrites
VL  - 80
IS  - 4
SP  - 1221
EP  - 1228
DO  - 10.1002/hlca.19970800419
ER  - 
@article{
author = "Kalvoda, Jaroslav and Grob, Jüren and Bjelaković, Mira and Lorenc, Ljubinka and Mihailović, Milhailo Lj.",
year = "1997",
abstract = "The two structurally similar 20‐phenyl‐ and 20‐(4‐methoxyphenyl)‐11‐(nitrosooxy)pregnan‐20‐ol derivatives 4 and 7 behave differently under photolytic conditions, the former nitrous acid ester affording, as a main product, the benzo‐fused hexacyclic compound 9, and the latter the 21‐nitro derivative 12. Mechanistic aspects of these transformations are discussed.",
publisher = "Wiley",
journal = "Helvetica Chimica Acta",
title = "Photolysis of Steroidal 20-Aryl-Substituted 11-Nitrites",
volume = "80",
number = "4",
pages = "1221-1228",
doi = "10.1002/hlca.19970800419"
}
Kalvoda, J., Grob, J., Bjelaković, M., Lorenc, L.,& Mihailović, M. Lj.. (1997). Photolysis of Steroidal 20-Aryl-Substituted 11-Nitrites. in Helvetica Chimica Acta
Wiley., 80(4), 1221-1228.
https://doi.org/10.1002/hlca.19970800419
Kalvoda J, Grob J, Bjelaković M, Lorenc L, Mihailović ML. Photolysis of Steroidal 20-Aryl-Substituted 11-Nitrites. in Helvetica Chimica Acta. 1997;80(4):1221-1228.
doi:10.1002/hlca.19970800419 .
Kalvoda, Jaroslav, Grob, Jüren, Bjelaković, Mira, Lorenc, Ljubinka, Mihailović, Milhailo Lj., "Photolysis of Steroidal 20-Aryl-Substituted 11-Nitrites" in Helvetica Chimica Acta, 80, no. 4 (1997):1221-1228,
https://doi.org/10.1002/hlca.19970800419 . .

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