The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride

dc.creator	Andrejević Vladimir
dc.creator	Bjelaković, Mira
dc.creator	Mihailović, Milan M.
dc.creator	Mihailović, Milhailo Lj.
dc.date.accessioned	2021-02-02T06:45:45Z
dc.date.available	2021-02-02T06:45:45Z
dc.date.issued	1985
dc.identifier.issn	0018-019X
dc.identifier.issn	1522-2675
dc.identifier.uri	https://cer.ihtm.bg.ac.rs/handle/123456789/4185
dc.description.abstract	Unsubstituted medium‐ring 1,2‐epoxycycloalkanes and certain vic‐epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAlH4 alone is used as reducing agent. However, the combination of LiAlH4 and AlCl3, in a 2:1 molar ratio (with respect to 1 mol‐equiv. of epoxide) used in refluxing Et2O, greatly enhances these reductions, rendering them of interest for practical purposes.
dc.publisher	Wiley	de
dc.rights	restrictedAccess
dc.source	Helvetica Chimica Acta	de
dc.subject	1,2‐epoxycycloalkanes
dc.subject	Reduction
dc.subject	alcohols
dc.subject	LiAlH4
dc.subject	AlCl3
dc.title	The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride	de
dc.type	article	en
dc.rights.license	ARR
dcterms.abstract	Михаиловић, Михаило Љ.; Михаиловић, Милан М.; Бјелаковић, Мира; Aндрејевић Владимир;
dc.citation.volume	68
dc.citation.issue	7
dc.citation.spage	2030
dc.citation.epage	2032
dc.identifier.doi	10.1002/hlca.19850680727
dc.identifier.scopus	2-s2.0-84987472492
dc.type.version	publishedVersion