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dc.creatorHusinec, Suren
dc.creatorPetković, Miloš
dc.creatorSavić, Vladimir
dc.creatorSimić, Milena
dc.date.accessioned2021-01-28T21:36:03Z
dc.date.available2021-01-28T21:36:03Z
dc.date.issued2012
dc.identifier.issn0039-7881
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/4173
dc.description.abstractpi-Allylpalladium intermediates are known to participate efficiently in transformations involving nucleophilic species. Exploring these processes, we have developed a method for the preparation of allyl acetates via palladium-catalysed functionalisation of allenes and 1,3-dienes. Reactions of aryl iodides with either of these two classes of compounds and excess sodium acetate in the presence of Pd(OAc) (2) and Ph3P as the catalytic system afforded the respective allyl acetates in moderate to good yields. The scope of this process has been investigated. The described method is an addition to the synthetic repertoire for the preparation of allyl acetates, and may be useful, in particular, for the synthesis of structurally complex compounds of this type.en
dc.publisherStuttgart : Georg Thieme Verlag Kg
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172009/RS//
dc.rightsrestrictedAccess
dc.sourceSynthesis
dc.subjectallyl acetatesen
dc.subjectpalladium catalysisen
dc.subjectallenesen
dc.subjectdienesen
dc.subjectsynthesisen
dc.titleSynthesis of Allyl Acetates via Palladium-Catalysed Functionalisation of Allenes and 1,3-Dienesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractПетковић, Милош; Хусинец, Сурен; Симић, Милена; Савић, Владимир;
dc.citation.volume44
dc.citation.issue3
dc.citation.spage399
dc.citation.epage408
dc.citation.other44(3): 399-408
dc.citation.rankM22
dc.identifier.doi10.1055/s-0031-1289658
dc.identifier.rcubconv_2588
dc.identifier.scopus2-s2.0-84856231784
dc.identifier.wos000300255100013
dc.type.versionpublishedVersion


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