Surface properties of RuO2 + IrO2 mixed oxide electrodes
Само за регистроване кориснике
1986
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The surface properties of RuO2 + IrO2 mixed oxide layers deposited on Ti by thermal decomposition of the corresponding chlorides in aqueous solutions have been investigated by means of cyclic voltammetry and ex situ UHV (AES and XPS) techniques. The data obtained have shown that the surface is enriched with Ir and also that the bulk composition is likely to be inhomogenous. The surface composition estimated on the basis of the voltammetric curves has been found to agree excellently with the results of ex situ surface analysis. Finally, the samples have been found to "absorb" protons from the solution through a mechanism which does not interfere with the estimation of the electrochemically active surface area on the basis of the voltammetric charge.
Кључне речи:
RuO2 / IrO2 / mixed oxide layers / thermal decomposition / ElectrochemistryИзвор:
Journal of Electroanalytical Chemistry, 1986, 214, 1-2, 535-546Издавач:
- Elsevier
Финансирање / пројекти:
- U.S.-Yugoslav Fund for Scientific and Technological Cooperation (D-0-E. Grant No. 567).
Институција/група
IHTMTY - JOUR AU - Angelinetta, Claudio AU - Trasatti, Sergio P. AU - Atanasoska, Ljiljana L. AU - Atanasoski, Radoslav T. PY - 1986 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4158 AB - The surface properties of RuO2 + IrO2 mixed oxide layers deposited on Ti by thermal decomposition of the corresponding chlorides in aqueous solutions have been investigated by means of cyclic voltammetry and ex situ UHV (AES and XPS) techniques. The data obtained have shown that the surface is enriched with Ir and also that the bulk composition is likely to be inhomogenous. The surface composition estimated on the basis of the voltammetric curves has been found to agree excellently with the results of ex situ surface analysis. Finally, the samples have been found to "absorb" protons from the solution through a mechanism which does not interfere with the estimation of the electrochemically active surface area on the basis of the voltammetric charge. PB - Elsevier T2 - Journal of Electroanalytical Chemistry T1 - Surface properties of RuO2 + IrO2 mixed oxide electrodes VL - 214 IS - 1-2 SP - 535 EP - 546 DO - 10.1016/0022-0728(86)80122-X ER -
@article{ author = "Angelinetta, Claudio and Trasatti, Sergio P. and Atanasoska, Ljiljana L. and Atanasoski, Radoslav T.", year = "1986", abstract = "The surface properties of RuO2 + IrO2 mixed oxide layers deposited on Ti by thermal decomposition of the corresponding chlorides in aqueous solutions have been investigated by means of cyclic voltammetry and ex situ UHV (AES and XPS) techniques. The data obtained have shown that the surface is enriched with Ir and also that the bulk composition is likely to be inhomogenous. The surface composition estimated on the basis of the voltammetric curves has been found to agree excellently with the results of ex situ surface analysis. Finally, the samples have been found to "absorb" protons from the solution through a mechanism which does not interfere with the estimation of the electrochemically active surface area on the basis of the voltammetric charge.", publisher = "Elsevier", journal = "Journal of Electroanalytical Chemistry", title = "Surface properties of RuO2 + IrO2 mixed oxide electrodes", volume = "214", number = "1-2", pages = "535-546", doi = "10.1016/0022-0728(86)80122-X" }
Angelinetta, C., Trasatti, S. P., Atanasoska, L. L.,& Atanasoski, R. T.. (1986). Surface properties of RuO2 + IrO2 mixed oxide electrodes. in Journal of Electroanalytical Chemistry Elsevier., 214(1-2), 535-546. https://doi.org/10.1016/0022-0728(86)80122-X
Angelinetta C, Trasatti SP, Atanasoska LL, Atanasoski RT. Surface properties of RuO2 + IrO2 mixed oxide electrodes. in Journal of Electroanalytical Chemistry. 1986;214(1-2):535-546. doi:10.1016/0022-0728(86)80122-X .
Angelinetta, Claudio, Trasatti, Sergio P., Atanasoska, Ljiljana L., Atanasoski, Radoslav T., "Surface properties of RuO2 + IrO2 mixed oxide electrodes" in Journal of Electroanalytical Chemistry, 214, no. 1-2 (1986):535-546, https://doi.org/10.1016/0022-0728(86)80122-X . .