RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction
Authorized Users Only
1999
Authors
Panić, Vladimir
Dekanski, Aleksandar

Milonjić, Slobodan K.

Atanasoski, Radoslav
Nikolić, Branislav Ž.
Article (Published version)

Elsevier
Metadata
Show full item recordAbstract
TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis
at elevated temperature. The Ti supported coatings were obtained by the sol–gel method using a sol mixture in which
the metal content was Ru(40%)–Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was
examined by X-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron
microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to
obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was
applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows
a considerably higher lifetime for sol–gel coated anodes than for those obtained by the usual thermal decomposition
method.
Keywords:
RuO2 sol / TiO2 sol / Coated titanium anodes / Chlorine evolution / Corrosion stabilitySource:
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1999, 157, 1-3, 269-274Publisher:
- Elsevier
Funding / projects:
- Ministry of Science and Technology of the Republic of Serbia
DOI: 10.1016/S0927-7757(99)00094-1
ISSN: 0927-7757; 1873-4359
WoS: 000083136700027
Scopus: 2-s2.0-0032854708
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IHTMTY - JOUR AU - Panić, Vladimir AU - Dekanski, Aleksandar AU - Milonjić, Slobodan K. AU - Atanasoski, Radoslav AU - Nikolić, Branislav Ž. PY - 1999 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4078 AB - TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis at elevated temperature. The Ti supported coatings were obtained by the sol–gel method using a sol mixture in which the metal content was Ru(40%)–Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was examined by X-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows a considerably higher lifetime for sol–gel coated anodes than for those obtained by the usual thermal decomposition method. PB - Elsevier T2 - Colloids and Surfaces A: Physicochemical and Engineering Aspects T1 - RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction VL - 157 IS - 1-3 SP - 269 EP - 274 DO - 10.1016/S0927-7757(99)00094-1 ER -
@article{ author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Atanasoski, Radoslav and Nikolić, Branislav Ž.", year = "1999", abstract = "TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis at elevated temperature. The Ti supported coatings were obtained by the sol–gel method using a sol mixture in which the metal content was Ru(40%)–Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was examined by X-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows a considerably higher lifetime for sol–gel coated anodes than for those obtained by the usual thermal decomposition method.", publisher = "Elsevier", journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects", title = "RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction", volume = "157", number = "1-3", pages = "269-274", doi = "10.1016/S0927-7757(99)00094-1" }
Panić, V., Dekanski, A., Milonjić, S. K., Atanasoski, R.,& Nikolić, B. Ž.. (1999). RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction. in Colloids and Surfaces A: Physicochemical and Engineering Aspects Elsevier., 157(1-3), 269-274. https://doi.org/10.1016/S0927-7757(99)00094-1
Panić V, Dekanski A, Milonjić SK, Atanasoski R, Nikolić BŽ. RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction. in Colloids and Surfaces A: Physicochemical and Engineering Aspects. 1999;157(1-3):269-274. doi:10.1016/S0927-7757(99)00094-1 .
Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Atanasoski, Radoslav, Nikolić, Branislav Ž., "RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction" in Colloids and Surfaces A: Physicochemical and Engineering Aspects, 157, no. 1-3 (1999):269-274, https://doi.org/10.1016/S0927-7757(99)00094-1 . .