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RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction

Authorized Users Only
1999
Authors
Panić, Vladimir
Dekanski, Aleksandar
Milonjić, Slobodan K.
Atanasoski, Radoslav
Nikolić, Branislav Ž.
Article (Published version)
,
Elsevier
Metadata
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Abstract
TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis at elevated temperature. The Ti supported coatings were obtained by the sol–gel method using a sol mixture in which the metal content was Ru(40%)–Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was examined by X-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows a considerably higher lifetime for sol–gel coated anodes than for those obtained by the usual thermal decomposition method.
Keywords:
RuO2 sol / TiO2 sol / Coated titanium anodes / Chlorine evolution / Corrosion stability
Source:
Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1999, 157, 1-3, 269-274
Publisher:
  • Elsevier
Funding / projects:
  • Ministry of Science and Technology of the Republic of Serbia

DOI: 10.1016/S0927-7757(99)00094-1

ISSN: 0927-7757; 1873-4359

WoS: 000083136700027

Scopus: 2-s2.0-0032854708
[ Google Scholar ]
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57
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4078
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar
AU  - Milonjić, Slobodan K.
AU  - Atanasoski, Radoslav
AU  - Nikolić, Branislav Ž.
PY  - 1999
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4078
AB  - TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis
at elevated temperature. The Ti supported coatings were obtained by the sol–gel method using a sol mixture in which
the metal content was Ru(40%)–Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was
examined by X-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron
microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to
obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was
applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows
a considerably higher lifetime for sol–gel coated anodes than for those obtained by the usual thermal decomposition
method.
PB  - Elsevier
T2  - Colloids and Surfaces A: Physicochemical and Engineering Aspects
T1  - RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction
VL  - 157
IS  - 1-3
SP  - 269
EP  - 274
DO  - 10.1016/S0927-7757(99)00094-1
ER  - 
@article{
author = "Panić, Vladimir and Dekanski, Aleksandar and Milonjić, Slobodan K. and Atanasoski, Radoslav and Nikolić, Branislav Ž.",
year = "1999",
abstract = "TiO2 and RuO2 sols were obtained from RuCl3 and TiCl3 aqueous solutions by condensation and forced hydrolysis
at elevated temperature. The Ti supported coatings were obtained by the sol–gel method using a sol mixture in which
the metal content was Ru(40%)–Ti(60%). The crystal structure of the solid phase of the sols and their mixtures was
examined by X-ray diffraction. The surface and morphology of the coatings were characterized by scanning electron
microscopy and scanning tunneling microscopy. Polarization measurements and cyclic voltammetry were used to
obtain information about the electrochemical properties of the obtained anodes. An accelerated corrosion test was
applied to quantify the anode stability for the chlorine evolution reaction. A stability comparison of the anodes shows
a considerably higher lifetime for sol–gel coated anodes than for those obtained by the usual thermal decomposition
method.",
publisher = "Elsevier",
journal = "Colloids and Surfaces A: Physicochemical and Engineering Aspects",
title = "RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction",
volume = "157",
number = "1-3",
pages = "269-274",
doi = "10.1016/S0927-7757(99)00094-1"
}
Panić, V., Dekanski, A., Milonjić, S. K., Atanasoski, R.,& Nikolić, B. Ž.. (1999). RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction. in Colloids and Surfaces A: Physicochemical and Engineering Aspects
Elsevier., 157(1-3), 269-274.
https://doi.org/10.1016/S0927-7757(99)00094-1
Panić V, Dekanski A, Milonjić SK, Atanasoski R, Nikolić BŽ. RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction. in Colloids and Surfaces A: Physicochemical and Engineering Aspects. 1999;157(1-3):269-274.
doi:10.1016/S0927-7757(99)00094-1 .
Panić, Vladimir, Dekanski, Aleksandar, Milonjić, Slobodan K., Atanasoski, Radoslav, Nikolić, Branislav Ž., "RuO2–TiO2 coated titanium anodes obtained by the sol–gel procedure and their electrochemical behaviour in the chlorine evolution reaction" in Colloids and Surfaces A: Physicochemical and Engineering Aspects, 157, no. 1-3 (1999):269-274,
https://doi.org/10.1016/S0927-7757(99)00094-1 . .

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