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The chicken eggshell calcium oxide ultrasonically dispersed over lignite coal fly ash-based cancrinite zeolite support as a catalyst for biodiesel production

Authorized Users Only
2021
Authors
Pavlović, Stefan
Marinković, Dalibor
Kostić, Milan
Lončarević, Davor
Mojović, Ljiljana
Stanković, Miroslav
Veljković, Vlada B.
Article (Published version)
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Abstract
Lignite coal fly ash (FA) from a domestic thermal power plant was converted into a pure cancrinite zeolitic material (ZMFA) using a novel, custom-made, rotating autoclave reactor system by a short-term alkali activation process. The obtained ZMFA was used as catalyst support of calcium oxide as an active component derived from waste chicken eggshells (ES). The ZMFA supported calcium oxide catalyst (xCaO/ZMFA) was synthesized by means of the ultrasound-assisted method. The influence of different concentrations of dispersed calcium oxide (x = 5–20 wt%) over ZMFA and thermal treatment at different temperatures (450–600 °C) were studied. The structural and morphological characterization showed that the original cancrinite structure was preserved. The basicity and textural properties indicated the presence of strong active sites in a well-defined pore network suitable for the reactions of bulky organic compounds such as triacylglycerols (TAGs). The highest activity (96.5% of fatty acid meth...yl esters) in the methanolysis of sunflower oil was achieved with the 20CaO/ZMFA catalyst under reaction conditions: temperature of 60 °C, methanol/oil molar ratio of 12:1, catalyst concentration of 4 wt%, and reaction time of 2 h. It was found that the optimal calcination temperature of the catalyst precursor was 550 °C. At calcination temperatures above 550 °C, the melting of the glassy phase became more intense whereby the molten phase partially reacted with calcium oxide forming the catalytically inactive calcium silicate compounds (wollastonite, larnite, etc.). The rate constants of the two tested kinetic models were correlated with the concentrations of active calcium oxide. The MRPD of both models was low indicating their reliability.

Keywords:
lignite coal fly ash / cancrinite / chicken eggshell / Ultrasound-assisted dispersion / Supported catalyst / biodiesel
Source:
Fuel, 2021, 289, 119912-
Publisher:
  • Elsevier
Funding / projects:
  • Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200133 (Univeristy of Niš, Faculty of Technology, Leskovac) (RS-200133)

DOI: 10.1016/j.fuel.2020.119912

ISSN: 0016-2361

WoS: 000612062400006

Scopus: 2-s2.0-85098673473
[ Google Scholar ]
11
5
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4035
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Pavlović, Stefan
AU  - Marinković, Dalibor
AU  - Kostić, Milan
AU  - Lončarević, Davor
AU  - Mojović, Ljiljana
AU  - Stanković, Miroslav
AU  - Veljković, Vlada B.
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4035
AB  - Lignite coal fly ash (FA) from a domestic thermal power plant was converted into a pure cancrinite zeolitic material (ZMFA) using a novel, custom-made, rotating autoclave reactor system by a short-term alkali activation process. The obtained ZMFA was used as catalyst support of calcium oxide as an active component derived from waste chicken eggshells (ES). The ZMFA supported calcium oxide catalyst (xCaO/ZMFA) was synthesized by means of the ultrasound-assisted method. The influence of different concentrations of dispersed calcium oxide (x = 5–20 wt%) over ZMFA and thermal treatment at different temperatures (450–600 °C) were studied. The structural and morphological characterization showed that the original cancrinite structure was preserved. The basicity and textural properties indicated the presence of strong active sites in a well-defined pore network suitable for the reactions of bulky organic compounds such as triacylglycerols (TAGs). The highest activity (96.5% of fatty acid methyl esters) in the methanolysis of sunflower oil was achieved with the 20CaO/ZMFA catalyst under reaction conditions: temperature of 60 °C, methanol/oil molar ratio of 12:1, catalyst concentration of 4 wt%, and reaction time of 2 h. It was found that the optimal calcination temperature of the catalyst precursor was 550 °C. At calcination temperatures above 550 °C, the melting of the glassy phase became more intense whereby the molten phase partially reacted with calcium oxide forming the catalytically inactive calcium silicate compounds (wollastonite, larnite, etc.). The rate constants of the two tested kinetic models were correlated with the concentrations of active calcium oxide. The MRPD of both models was low indicating their reliability.
PB  - Elsevier
T2  - Fuel
T1  - The chicken eggshell calcium oxide ultrasonically dispersed over lignite coal fly ash-based cancrinite zeolite support as a catalyst for biodiesel production
VL  - 289
SP  - 119912
DO  - 10.1016/j.fuel.2020.119912
ER  - 
@article{
author = "Pavlović, Stefan and Marinković, Dalibor and Kostić, Milan and Lončarević, Davor and Mojović, Ljiljana and Stanković, Miroslav and Veljković, Vlada B.",
year = "2021",
abstract = "Lignite coal fly ash (FA) from a domestic thermal power plant was converted into a pure cancrinite zeolitic material (ZMFA) using a novel, custom-made, rotating autoclave reactor system by a short-term alkali activation process. The obtained ZMFA was used as catalyst support of calcium oxide as an active component derived from waste chicken eggshells (ES). The ZMFA supported calcium oxide catalyst (xCaO/ZMFA) was synthesized by means of the ultrasound-assisted method. The influence of different concentrations of dispersed calcium oxide (x = 5–20 wt%) over ZMFA and thermal treatment at different temperatures (450–600 °C) were studied. The structural and morphological characterization showed that the original cancrinite structure was preserved. The basicity and textural properties indicated the presence of strong active sites in a well-defined pore network suitable for the reactions of bulky organic compounds such as triacylglycerols (TAGs). The highest activity (96.5% of fatty acid methyl esters) in the methanolysis of sunflower oil was achieved with the 20CaO/ZMFA catalyst under reaction conditions: temperature of 60 °C, methanol/oil molar ratio of 12:1, catalyst concentration of 4 wt%, and reaction time of 2 h. It was found that the optimal calcination temperature of the catalyst precursor was 550 °C. At calcination temperatures above 550 °C, the melting of the glassy phase became more intense whereby the molten phase partially reacted with calcium oxide forming the catalytically inactive calcium silicate compounds (wollastonite, larnite, etc.). The rate constants of the two tested kinetic models were correlated with the concentrations of active calcium oxide. The MRPD of both models was low indicating their reliability.",
publisher = "Elsevier",
journal = "Fuel",
title = "The chicken eggshell calcium oxide ultrasonically dispersed over lignite coal fly ash-based cancrinite zeolite support as a catalyst for biodiesel production",
volume = "289",
pages = "119912",
doi = "10.1016/j.fuel.2020.119912"
}
Pavlović, S., Marinković, D., Kostić, M., Lončarević, D., Mojović, L., Stanković, M.,& Veljković, V. B.. (2021). The chicken eggshell calcium oxide ultrasonically dispersed over lignite coal fly ash-based cancrinite zeolite support as a catalyst for biodiesel production. in Fuel
Elsevier., 289, 119912.
https://doi.org/10.1016/j.fuel.2020.119912
Pavlović S, Marinković D, Kostić M, Lončarević D, Mojović L, Stanković M, Veljković VB. The chicken eggshell calcium oxide ultrasonically dispersed over lignite coal fly ash-based cancrinite zeolite support as a catalyst for biodiesel production. in Fuel. 2021;289:119912.
doi:10.1016/j.fuel.2020.119912 .
Pavlović, Stefan, Marinković, Dalibor, Kostić, Milan, Lončarević, Davor, Mojović, Ljiljana, Stanković, Miroslav, Veljković, Vlada B., "The chicken eggshell calcium oxide ultrasonically dispersed over lignite coal fly ash-based cancrinite zeolite support as a catalyst for biodiesel production" in Fuel, 289 (2021):119912,
https://doi.org/10.1016/j.fuel.2020.119912 . .

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