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Improved electrolyte for zinc-polyaniline batteries

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2010
220.pdf (312.3Kb)
Authors
Jugović, Branimir
Trišović, Tomislav
Stevanović, Jasmina
Gvozdenović, Milica M.
Grgur, Branimir N.
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Abstract
Poster presented at the 37th International conference of the Slovak Society of Chemical Engineering, Vysoké Tatry, Slovakia, May 24-28, 2010
Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl2 and 0.50 M NH4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164 mAh g-1
Keywords:
zinc-polyaniline batteries / electrolytes
Source:
2010
Funding / projects:
  • Modifikacija metalnih i nemetalnih materijala elektroprovodnim polimerima za primenu u novim tehnologijama (RS-142044)
Note:
  • Paper: https://cer.ihtm.bg.ac.rs/handle/123456789/2613
[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_dais_3498
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/3997
Collections
  • Posteri / Posters
Institution/Community
IHTM
TY  - CONF
AU  - Jugović, Branimir
AU  - Trišović, Tomislav
AU  - Stevanović, Jasmina
AU  - Gvozdenović, Milica M.
AU  - Grgur, Branimir N.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3997
AB  - Poster presented at the 37th International conference of the Slovak Society of Chemical Engineering, Vysoké Tatry, Slovakia, May 24-28, 2010
AB  - Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl2 and 0.50 M NH4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164 mAh g-1
T1  - Improved electrolyte for zinc-polyaniline batteries
UR  - https://hdl.handle.net/21.15107/rcub_dais_3498
ER  - 
@conference{
author = "Jugović, Branimir and Trišović, Tomislav and Stevanović, Jasmina and Gvozdenović, Milica M. and Grgur, Branimir N.",
year = "2010",
abstract = "Poster presented at the 37th International conference of the Slovak Society of Chemical Engineering, Vysoké Tatry, Slovakia, May 24-28, 2010, Electrochemical behavior of zinc and polyaniline (PANI) electrode polymerized from 0.1 M HCl and 0.1 M aniline on graphite electrode, in 0.2 M ZnCl2 and 0.50 M NH4Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte for the zinc electrode negative shift of the open circuit potential of 150 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation, were observed. In citrate/chloride electrolyte zinc dendrite formation were completely suppressed. PANI electrodes show better discharge characteristic in chloride/citrate electrolyte with determined maximum discharge capacity of 164 mAh g-1",
title = "Improved electrolyte for zinc-polyaniline batteries",
url = "https://hdl.handle.net/21.15107/rcub_dais_3498"
}
Jugović, B., Trišović, T., Stevanović, J., Gvozdenović, M. M.,& Grgur, B. N.. (2010). Improved electrolyte for zinc-polyaniline batteries. .
https://hdl.handle.net/21.15107/rcub_dais_3498
Jugović B, Trišović T, Stevanović J, Gvozdenović MM, Grgur BN. Improved electrolyte for zinc-polyaniline batteries. 2010;.
https://hdl.handle.net/21.15107/rcub_dais_3498 .
Jugović, Branimir, Trišović, Tomislav, Stevanović, Jasmina, Gvozdenović, Milica M., Grgur, Branimir N., "Improved electrolyte for zinc-polyaniline batteries" (2010),
https://hdl.handle.net/21.15107/rcub_dais_3498 .

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