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Experimental and thermodynamic description of ternary Bi-Cu-Ga system

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2017
osnovni rad (5.807Mb)
Authors
Minić, D.
Du, Y.
Premović, Milena
Manasijević, Dragan
Talijan, Nadežda M.
Milisavljević, D.
Marković, A.
Đorđević, A.
Tomović, M.
Article (Published version)
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Abstract
Phase diagram of the Bi-Cu-Ga ternary system has been investigated experimentally with 27 alloys and analytically by using a Calphad method. Thirteen annealed alloys at 200 °C were investigated by using scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) methods. Temperatures of phase transformation were determined with 14 alloys which are lying along three vertical sections Bi-Cu0.5Ga0.5, Cu-Bi0.5Ga0.5 and Ga-Bi0.5Cu0.5 by using differential thermal analysis (DTA). Based on the experimental result and by using Calphad method, ternary phase diagrams were constructed with a new description of liquidus phase. Calculated phase diagram and experimentally obtained results are in good agreement. Liquidus projection and invariant reaction were calculated by using new thermodynamic parameters for liquidus phase.
Keywords:
Ternary Bi-Cu-Ga system / Calphad method / Experimental results / Liquidus projection
Source:
Journal of Mining and Metallurgy. Section B: Metallurgy, 2017, 53, 3, 189-201
Publisher:
  • Serbia : Technical Faculty Bor
Funding / projects:
  • Advanced multicomponent metal systems and nanostructured materials with diverse functional properties (RS-172037)
  • 2011 Union-Innovative center of the Central South University of China

DOI: 10.2298/JMMB170505017M

ISSN: 1450-5339; 2217-7175

WoS: 000417723500005

Scopus: 2-s2.0-85032569850
[ Google Scholar ]
3
3
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/3962
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Minić, D.
AU  - Du, Y.
AU  - Premović, Milena
AU  - Manasijević, Dragan
AU  - Talijan, Nadežda M.
AU  - Milisavljević, D.
AU  - Marković, A.
AU  - Đorđević, A.
AU  - Tomović, M.
PY  - 2017
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3962
AB  - Phase diagram of the Bi-Cu-Ga ternary system has been investigated experimentally with 27 alloys and analytically by
using a Calphad method. Thirteen annealed alloys at 200 °C were investigated by using scanning electron microscopy
(SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) methods. Temperatures of phase
transformation were determined with 14 alloys which are lying along three vertical sections Bi-Cu0.5Ga0.5, Cu-Bi0.5Ga0.5
and Ga-Bi0.5Cu0.5 by using differential thermal analysis (DTA). Based on the experimental result and by using Calphad
method, ternary phase diagrams were constructed with a new description of liquidus phase. Calculated phase diagram and
experimentally obtained results are in good agreement. Liquidus projection and invariant reaction were calculated by using
new thermodynamic parameters for liquidus phase.
PB  - Serbia : Technical Faculty Bor
T2  - Journal of Mining and Metallurgy. Section B: Metallurgy
T1  - Experimental and thermodynamic description of ternary Bi-Cu-Ga system
VL  - 53
IS  - 3
SP  - 189
EP  - 201
DO  - 10.2298/JMMB170505017M
ER  - 
@article{
author = "Minić, D. and Du, Y. and Premović, Milena and Manasijević, Dragan and Talijan, Nadežda M. and Milisavljević, D. and Marković, A. and Đorđević, A. and Tomović, M.",
year = "2017",
abstract = "Phase diagram of the Bi-Cu-Ga ternary system has been investigated experimentally with 27 alloys and analytically by
using a Calphad method. Thirteen annealed alloys at 200 °C were investigated by using scanning electron microscopy
(SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) methods. Temperatures of phase
transformation were determined with 14 alloys which are lying along three vertical sections Bi-Cu0.5Ga0.5, Cu-Bi0.5Ga0.5
and Ga-Bi0.5Cu0.5 by using differential thermal analysis (DTA). Based on the experimental result and by using Calphad
method, ternary phase diagrams were constructed with a new description of liquidus phase. Calculated phase diagram and
experimentally obtained results are in good agreement. Liquidus projection and invariant reaction were calculated by using
new thermodynamic parameters for liquidus phase.",
publisher = "Serbia : Technical Faculty Bor",
journal = "Journal of Mining and Metallurgy. Section B: Metallurgy",
title = "Experimental and thermodynamic description of ternary Bi-Cu-Ga system",
volume = "53",
number = "3",
pages = "189-201",
doi = "10.2298/JMMB170505017M"
}
Minić, D., Du, Y., Premović, M., Manasijević, D., Talijan, N. M., Milisavljević, D., Marković, A., Đorđević, A.,& Tomović, M.. (2017). Experimental and thermodynamic description of ternary Bi-Cu-Ga system. in Journal of Mining and Metallurgy. Section B: Metallurgy
Serbia : Technical Faculty Bor., 53(3), 189-201.
https://doi.org/10.2298/JMMB170505017M
Minić D, Du Y, Premović M, Manasijević D, Talijan NM, Milisavljević D, Marković A, Đorđević A, Tomović M. Experimental and thermodynamic description of ternary Bi-Cu-Ga system. in Journal of Mining and Metallurgy. Section B: Metallurgy. 2017;53(3):189-201.
doi:10.2298/JMMB170505017M .
Minić, D., Du, Y., Premović, Milena, Manasijević, Dragan, Talijan, Nadežda M., Milisavljević, D., Marković, A., Đorđević, A., Tomović, M., "Experimental and thermodynamic description of ternary Bi-Cu-Ga system" in Journal of Mining and Metallurgy. Section B: Metallurgy, 53, no. 3 (2017):189-201,
https://doi.org/10.2298/JMMB170505017M . .

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