Приказ основних података о документу

dc.creatorJanjić, Goran
dc.creatorJelić, Stefan
dc.creatorTrišović, Nemanja
dc.creatorPopović, Dragan
dc.creatorĐorđević, Ivana
dc.creatorMilčić, Miloš
dc.date.accessioned2020-11-30T07:39:10Z
dc.date.available2020-11-30T07:39:10Z
dc.date.issued2020
dc.identifier.issn1528-7483
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/3882
dc.description.abstractFluorination of compounds causes an increase in the proton-donating ability and a decrease in the proton-accepting capacity of groups in their vicinity. The formation of F···F interactions is followed by the shift of the electron density in the area of F···F contact, which creates a new region with a larger surface area, a higher negative potential, and, hence, a more pronounced accepting ability. The new region also has a greater ability to form multiple (simultaneous) interactions with species from the environment, thus compensating for the reduction of the accepting capacity of the groups in the vicinity. This phenomenon explains not only the abundance of F···F interactions in crystal structures, but also a large number of structures with F···O interactions. Only C–H···F interactions are more numerous than F···F interactions in crystal structures, which indicates a high affinity of fluorinated compounds for nonpolar groups.en
dc.language.isoensr
dc.publisherAmerican Chemical Society (ACS)sr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS//sr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172023/RS//sr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/171017/RS//sr
dc.rightsrestrictedAccesssr
dc.sourceCrystal Growth and Designsr
dc.subjectFluorinationsr
dc.subjectFluorine–Fluorine Interactionssr
dc.subjectCrystal Structuressr
dc.titleNew Theoretical Insight into Fluorination and Fluorine–Fluorine Interactions as a Driving Force in Crystal Structuresen
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractЂорђевић, Ивана С.; Јелић, Стефан Т.; Милчић, Милош К.; Тришовић, Немања П.; Поповић, Драган М.; Јањић, Горан В.;
dc.rights.holderAmerican Chemical Society (ACS)sr
dc.citation.volume20
dc.citation.issue5
dc.citation.spage2943
dc.citation.epage2951
dc.citation.rankM21~
dc.identifier.doi10.1021/acs.cgd.9b01565
dc.identifier.scopus2-s2.0-85085149156
dc.identifier.wos000535174000017
dc.type.versionpublishedVersionsr


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Приказ основних података о документу