Experimental densities and derived thermodynamic properties of pure p-cymene, α-pinene, limonene and citral under high pressure conditions
Само за регистроване кориснике
2020
Аутори
Ilić-Pajić, JovanaIvaniš, Gorica
Radović, Ivona
Grujić, Aleksandar
Stajić-Trošić, Jasna
Stijepović, Mirko Z.
Kijevčanin, Mirjana
Чланак у часопису (Објављена верзија)
,
Elsevier Ltd.
Метаподаци
Приказ свих података о документуАпстракт
In order to reduce negative influence of fossil fuels on environment, use of various renewable resources is highly promoted. Terpenes, naturally occurring in plants, can be added to petroleum fuel as its substitute up to a certain share. Thermodynamic properties of a fuel under high pressure and moderate temperature conditions are of significant importance for engine efficiency. This work reports density measurements of pure p-cymene, α-pinene, limonene and citral at temperatures (293.15–413.15) K and pressures (0.1–60) MPa, applying an Anton Paar DMA HP measuring cell. Density data were fitted by modified Tammann-Tait equation where the absolute average percentage deviation between measured and calculated densities was about 0.010%. The obtained parameters were used to estimate the isothermal compressibility, the isobaric thermal expansion coefficient, the internal pressure, and the difference between specific heat capacity at constant pressure and at constant volume. For examined com...pounds, all thermodynamic properties, except the internal pressure, decrease with pressure rise along an isotherm and increase as temperature increases at a constant pressure. The intersection point of isotherms for the isobaric thermal expansion coefficient for pure citral was registered at pressure 47 MPa, while for other analyzed terpenes the intersection point is above 60 MPa, outside the measurements pressure range.
Кључне речи:
Pure terpenes / High pressure / Density / Thermodynamic propertiesИзвор:
The Journal of Chemical Thermodynamics, 2020, 144, 106065-Издавач:
- Elsevier
Финансирање / пројекти:
- Утицај рударског отпада из РТБ-а Бор на загађење водотокова са предлогом мера и поступака за смањење штетног дејства на животну средину (RS-MESTD-Technological Development (TD or TR)-37001)
- Синтеза, развој технологија добијања и примена наноструктурних мултифункционалних материјала дефинисаних својстава (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
- Нови индустријски и еколошки аспекти примене хемијске термодинамике на унапређење хемијских процеса са вишефазним и вишекомпонентним системима (RS-MESTD-Basic Research (BR or ON)-172063)
DOI: 10.1016/j.jct.2020.106065
ISSN: 0021-9614
WoS: 000517501200011
Scopus: 2-s2.0-85078750759
Институција/група
IHTMTY - JOUR AU - Ilić-Pajić, Jovana AU - Ivaniš, Gorica AU - Radović, Ivona AU - Grujić, Aleksandar AU - Stajić-Trošić, Jasna AU - Stijepović, Mirko Z. AU - Kijevčanin, Mirjana PY - 2020 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3784 AB - In order to reduce negative influence of fossil fuels on environment, use of various renewable resources is highly promoted. Terpenes, naturally occurring in plants, can be added to petroleum fuel as its substitute up to a certain share. Thermodynamic properties of a fuel under high pressure and moderate temperature conditions are of significant importance for engine efficiency. This work reports density measurements of pure p-cymene, α-pinene, limonene and citral at temperatures (293.15–413.15) K and pressures (0.1–60) MPa, applying an Anton Paar DMA HP measuring cell. Density data were fitted by modified Tammann-Tait equation where the absolute average percentage deviation between measured and calculated densities was about 0.010%. The obtained parameters were used to estimate the isothermal compressibility, the isobaric thermal expansion coefficient, the internal pressure, and the difference between specific heat capacity at constant pressure and at constant volume. For examined compounds, all thermodynamic properties, except the internal pressure, decrease with pressure rise along an isotherm and increase as temperature increases at a constant pressure. The intersection point of isotherms for the isobaric thermal expansion coefficient for pure citral was registered at pressure 47 MPa, while for other analyzed terpenes the intersection point is above 60 MPa, outside the measurements pressure range. PB - Elsevier T2 - The Journal of Chemical Thermodynamics T1 - Experimental densities and derived thermodynamic properties of pure p-cymene, α-pinene, limonene and citral under high pressure conditions VL - 144 SP - 106065 DO - 10.1016/j.jct.2020.106065 ER -
@article{ author = "Ilić-Pajić, Jovana and Ivaniš, Gorica and Radović, Ivona and Grujić, Aleksandar and Stajić-Trošić, Jasna and Stijepović, Mirko Z. and Kijevčanin, Mirjana", year = "2020", abstract = "In order to reduce negative influence of fossil fuels on environment, use of various renewable resources is highly promoted. Terpenes, naturally occurring in plants, can be added to petroleum fuel as its substitute up to a certain share. Thermodynamic properties of a fuel under high pressure and moderate temperature conditions are of significant importance for engine efficiency. This work reports density measurements of pure p-cymene, α-pinene, limonene and citral at temperatures (293.15–413.15) K and pressures (0.1–60) MPa, applying an Anton Paar DMA HP measuring cell. Density data were fitted by modified Tammann-Tait equation where the absolute average percentage deviation between measured and calculated densities was about 0.010%. The obtained parameters were used to estimate the isothermal compressibility, the isobaric thermal expansion coefficient, the internal pressure, and the difference between specific heat capacity at constant pressure and at constant volume. For examined compounds, all thermodynamic properties, except the internal pressure, decrease with pressure rise along an isotherm and increase as temperature increases at a constant pressure. The intersection point of isotherms for the isobaric thermal expansion coefficient for pure citral was registered at pressure 47 MPa, while for other analyzed terpenes the intersection point is above 60 MPa, outside the measurements pressure range.", publisher = "Elsevier", journal = "The Journal of Chemical Thermodynamics", title = "Experimental densities and derived thermodynamic properties of pure p-cymene, α-pinene, limonene and citral under high pressure conditions", volume = "144", pages = "106065", doi = "10.1016/j.jct.2020.106065" }
Ilić-Pajić, J., Ivaniš, G., Radović, I., Grujić, A., Stajić-Trošić, J., Stijepović, M. Z.,& Kijevčanin, M.. (2020). Experimental densities and derived thermodynamic properties of pure p-cymene, α-pinene, limonene and citral under high pressure conditions. in The Journal of Chemical Thermodynamics Elsevier., 144, 106065. https://doi.org/10.1016/j.jct.2020.106065
Ilić-Pajić J, Ivaniš G, Radović I, Grujić A, Stajić-Trošić J, Stijepović MZ, Kijevčanin M. Experimental densities and derived thermodynamic properties of pure p-cymene, α-pinene, limonene and citral under high pressure conditions. in The Journal of Chemical Thermodynamics. 2020;144:106065. doi:10.1016/j.jct.2020.106065 .
Ilić-Pajić, Jovana, Ivaniš, Gorica, Radović, Ivona, Grujić, Aleksandar, Stajić-Trošić, Jasna, Stijepović, Mirko Z., Kijevčanin, Mirjana, "Experimental densities and derived thermodynamic properties of pure p-cymene, α-pinene, limonene and citral under high pressure conditions" in The Journal of Chemical Thermodynamics, 144 (2020):106065, https://doi.org/10.1016/j.jct.2020.106065 . .