Molecular Structure of Metal Enolates
Abstract
Ligand properties such as coordination activity, bond length and orientation of donor atoms are among the key functions in designing organic structures. β-Diketones and their metal complexes are among the first groups studied. Numerous classes of various metal complexes are the product of their versatility and flexibility to adopt different coordination modes. They typically act in monoanionic form as bidentate oxygen donor in enol form or in keto form as neutral molecule. In that form ligand coordination can take place through the carbon atom or as a monodentate oxygen donor in enol form, or as bridging ligand donor.
Keywords:
Metal enolates / ligand properties / coordination activity / acetylacetone / UV-VIS spectra / Vibrational spectra / review / EPR spectra / Mass spectra / Molecular CharacteristicsSource:
PATAI'S Chemistry of Functional Groups, 2009Publisher:
- Wiley
Funding / projects:
Collections
Institution/Community
IHTMTY - CHAP PY - 2009 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3673 AB - Ligand properties such as coordination activity, bond length and orientation of donor atoms are among the key functions in designing organic structures. β-Diketones and their metal complexes are among the first groups studied. Numerous classes of various metal complexes are the product of their versatility and flexibility to adopt different coordination modes. They typically act in monoanionic form as bidentate oxygen donor in enol form or in keto form as neutral molecule. In that form ligand coordination can take place through the carbon atom or as a monodentate oxygen donor in enol form, or as bridging ligand donor. PB - Wiley T2 - PATAI'S Chemistry of Functional Groups T1 - Molecular Structure of Metal Enolates DO - 10.1002/9780470682531.pat0418 ER -
@inbook{ year = "2009", abstract = "Ligand properties such as coordination activity, bond length and orientation of donor atoms are among the key functions in designing organic structures. β-Diketones and their metal complexes are among the first groups studied. Numerous classes of various metal complexes are the product of their versatility and flexibility to adopt different coordination modes. They typically act in monoanionic form as bidentate oxygen donor in enol form or in keto form as neutral molecule. In that form ligand coordination can take place through the carbon atom or as a monodentate oxygen donor in enol form, or as bridging ligand donor.", publisher = "Wiley", journal = "PATAI'S Chemistry of Functional Groups", booktitle = "Molecular Structure of Metal Enolates", doi = "10.1002/9780470682531.pat0418" }
(2009). Molecular Structure of Metal Enolates. in PATAI'S Chemistry of Functional Groups Wiley.. https://doi.org/10.1002/9780470682531.pat0418
Molecular Structure of Metal Enolates. in PATAI'S Chemistry of Functional Groups. 2009;. doi:10.1002/9780470682531.pat0418 .
"Molecular Structure of Metal Enolates" in PATAI'S Chemistry of Functional Groups (2009), https://doi.org/10.1002/9780470682531.pat0418 . .