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Phenomenology of a formation of a honeycomb-like structure during copper electrodeposition

Authorized Users Only
2007
Authors
Nikolić, Nebojša D.
Popov, Konstantin I.
Pavlović, Lj.J.
Pavlović, Miomir
Article (Published version)
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Abstract
In this paper, the phenomenology of a formation of a honeycomb-like structure was considered. Copper deposits obtained at overpotential of 1000 mV were examined by scanning electron microscopy (SEM) technique. It was shown that two groups of craters or holes were formed by the electrodeposition at this overpotential. The origin of one group is associated with hydrogen evolution and the attachment of hydrogen bubbles at the surface area of an electrode. For the origin of the other group, a current distribution at the growing surface was very important. The effect of preparing a working electrode onto the formation of a honeycomb-like structure is also considered.
Keywords:
Copper / Crater or hole / Electroplating / Hydrogen evolution / Scanning electron microscopy (SEM)
Source:
Journal of Solid State Electrochemistry, 2007, 11, 5, 667-675
Funding / projects:
  • Deposition of ultrafinepowders of metals and alloys and nanostructured surfaces by electrochemical techniques (RS-142032)

DOI: 10.1007/s10008-006-0222-z

ISSN: 1432-8488

WoS: 000244199400013

Scopus: 2-s2.0-33847248524
[ Google Scholar ]
55
52
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/367
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Nikolić, Nebojša D.
AU  - Popov, Konstantin I.
AU  - Pavlović, Lj.J.
AU  - Pavlović, Miomir
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/367
AB  - In this paper, the phenomenology of a formation of a honeycomb-like structure was considered. Copper deposits obtained at overpotential of 1000 mV were examined by scanning electron microscopy (SEM) technique. It was shown that two groups of craters or holes were formed by the electrodeposition at this overpotential. The origin of one group is associated with hydrogen evolution and the attachment of hydrogen bubbles at the surface area of an electrode. For the origin of the other group, a current distribution at the growing surface was very important. The effect of preparing a working electrode onto the formation of a honeycomb-like structure is also considered.
T2  - Journal of Solid State Electrochemistry
T1  - Phenomenology of a formation of a honeycomb-like structure during copper electrodeposition
VL  - 11
IS  - 5
SP  - 667
EP  - 675
DO  - 10.1007/s10008-006-0222-z
ER  - 
@article{
author = "Nikolić, Nebojša D. and Popov, Konstantin I. and Pavlović, Lj.J. and Pavlović, Miomir",
year = "2007",
abstract = "In this paper, the phenomenology of a formation of a honeycomb-like structure was considered. Copper deposits obtained at overpotential of 1000 mV were examined by scanning electron microscopy (SEM) technique. It was shown that two groups of craters or holes were formed by the electrodeposition at this overpotential. The origin of one group is associated with hydrogen evolution and the attachment of hydrogen bubbles at the surface area of an electrode. For the origin of the other group, a current distribution at the growing surface was very important. The effect of preparing a working electrode onto the formation of a honeycomb-like structure is also considered.",
journal = "Journal of Solid State Electrochemistry",
title = "Phenomenology of a formation of a honeycomb-like structure during copper electrodeposition",
volume = "11",
number = "5",
pages = "667-675",
doi = "10.1007/s10008-006-0222-z"
}
Nikolić, N. D., Popov, K. I., Pavlović, Lj.J.,& Pavlović, M.. (2007). Phenomenology of a formation of a honeycomb-like structure during copper electrodeposition. in Journal of Solid State Electrochemistry, 11(5), 667-675.
https://doi.org/10.1007/s10008-006-0222-z
Nikolić ND, Popov KI, Pavlović L, Pavlović M. Phenomenology of a formation of a honeycomb-like structure during copper electrodeposition. in Journal of Solid State Electrochemistry. 2007;11(5):667-675.
doi:10.1007/s10008-006-0222-z .
Nikolić, Nebojša D., Popov, Konstantin I., Pavlović, Lj.J., Pavlović, Miomir, "Phenomenology of a formation of a honeycomb-like structure during copper electrodeposition" in Journal of Solid State Electrochemistry, 11, no. 5 (2007):667-675,
https://doi.org/10.1007/s10008-006-0222-z . .

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