It is shown that the equation for the potentials of semiconductive sulphide membranes given by Sato 25 years ago is valid also for the calculation of E0 values of "cyanide-sensitive" ion-selective electrodes. The only requirement for such an approach to the problem is information on the activities of relevant species in both the solid and the liquid phases. In this way, the E0 value given by Pungor and Toth for the silver iodide membrane in cyanide solution was confirmed, and E0 for silver sulphide in cyanide solution was evaluated for the first time.
TY - JOUR
AU - Jovanović, Vladislava M.
AU - Jovanović, Momir S.
PY - 1990
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3663
AB - It is shown that the equation for the potentials of semiconductive sulphide membranes given by Sato 25 years ago is valid also for the calculation of E0 values of "cyanide-sensitive" ion-selective electrodes. The only requirement for such an approach to the problem is information on the activities of relevant species in both the solid and the liquid phases. In this way, the E0 value given by Pungor and Toth for the silver iodide membrane in cyanide solution was confirmed, and E0 for silver sulphide in cyanide solution was evaluated for the first time.
T2 - Analytica Chimica Acta
T1 - Standard potential values of "cyanide-sensitive" silver iodide and silver sulphide ion-selective electrodes
VL - 233
IS - C
SP - 329
EP - 333
DO - 10.1016/S0003-2670(00)83499-6
ER -
@article{
author = "Jovanović, Vladislava M. and Jovanović, Momir S.",
year = "1990",
abstract = "It is shown that the equation for the potentials of semiconductive sulphide membranes given by Sato 25 years ago is valid also for the calculation of E0 values of "cyanide-sensitive" ion-selective electrodes. The only requirement for such an approach to the problem is information on the activities of relevant species in both the solid and the liquid phases. In this way, the E0 value given by Pungor and Toth for the silver iodide membrane in cyanide solution was confirmed, and E0 for silver sulphide in cyanide solution was evaluated for the first time.",
journal = "Analytica Chimica Acta",
title = "Standard potential values of "cyanide-sensitive" silver iodide and silver sulphide ion-selective electrodes",
volume = "233",
number = "C",
pages = "329-333",
doi = "10.1016/S0003-2670(00)83499-6"
}
Jovanović, V. M.,& Jovanović, M. S.. (1990). Standard potential values of "cyanide-sensitive" silver iodide and silver sulphide ion-selective electrodes. in Analytica Chimica Acta, 233(C), 329-333.
https://doi.org/10.1016/S0003-2670(00)83499-6
Jovanović VM, Jovanović MS. Standard potential values of "cyanide-sensitive" silver iodide and silver sulphide ion-selective electrodes. in Analytica Chimica Acta. 1990;233(C):329-333.
doi:10.1016/S0003-2670(00)83499-6 .
Jovanović, Vladislava M., Jovanović, Momir S., "Standard potential values of "cyanide-sensitive" silver iodide and silver sulphide ion-selective electrodes" in Analytica Chimica Acta, 233, no. C (1990):329-333,
https://doi.org/10.1016/S0003-2670(00)83499-6 . .
