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Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K

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2003
Authors
Miladinović, Jelena
Ninković, Rozalija
Todorović, Milica
Jovanović, Vladislava M.
Article (Published version)
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Abstract
The osmotic coefficient of ZnCl2 (aq) has been measured at T = 298.15 K by the isopiestic method over the range of molalities from (0.4 to 2.4)mol·kg -1 with KCl(aq) as the reference solution. The available literature data on the osmotic coefficient of ZnCl 2 (aq) at T = 298.15 K, and new experimental data were treated by the Clegg-Pitzer- Brimblecombe equation and the extended Pitzer's equation. These equations were used to calculate the activity coefficient of ZnCl 2 at T=298.15 K. The formation of the ZnCl + complex has been taken into account by means of the Clegg-Pitzer-Brimblecombe equation.
Keywords:
Activity coefficient / Clegg-Pitzer-Brimblecombe equations / Complex formation / Electric charge / Electrolytes / Extended Pitzer's equations / Isopiestic measurements / Lithium batteries / Nuclear magnetic resonance spectroscopy / Osmosis / Osmotic coefficient / Precipitation (chemical) / Transition metals / Zinc chloride
Source:
Journal of Chemical Thermodynamics, 2003, 35, 7, 1073-1082
Publisher:
  • Elsevier
Funding / projects:
  • inistry for Science, Technology and Development of the Republic of Serbia (Project No. 1891)

DOI: 10.1016/S0021-9614(03)00048-X

ISSN: 0021-9614

WoS: 000183868300003

Scopus: 2-s2.0-3242740980
[ Google Scholar ]
4
4
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/3655
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Miladinović, Jelena
AU  - Ninković, Rozalija
AU  - Todorović, Milica
AU  - Jovanović, Vladislava M.
PY  - 2003
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3655
AB  - The osmotic coefficient of ZnCl2 (aq) has been measured at T = 298.15 K by the isopiestic method over the range of molalities from (0.4 to 2.4)mol·kg -1 with KCl(aq) as the reference solution. The available literature data on the osmotic coefficient of ZnCl 2 (aq) at T = 298.15 K, and new experimental data were treated by the Clegg-Pitzer- Brimblecombe equation and the extended Pitzer's equation. These equations were used to calculate the activity coefficient of ZnCl 2 at T=298.15 K. The formation of the ZnCl + complex has been taken into account by means of the Clegg-Pitzer-Brimblecombe equation.
PB  - Elsevier
T2  - Journal of Chemical Thermodynamics
T1  - Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K
VL  - 35
IS  - 7
SP  - 1073
EP  - 1082
DO  - 10.1016/S0021-9614(03)00048-X
ER  - 
@article{
author = "Miladinović, Jelena and Ninković, Rozalija and Todorović, Milica and Jovanović, Vladislava M.",
year = "2003",
abstract = "The osmotic coefficient of ZnCl2 (aq) has been measured at T = 298.15 K by the isopiestic method over the range of molalities from (0.4 to 2.4)mol·kg -1 with KCl(aq) as the reference solution. The available literature data on the osmotic coefficient of ZnCl 2 (aq) at T = 298.15 K, and new experimental data were treated by the Clegg-Pitzer- Brimblecombe equation and the extended Pitzer's equation. These equations were used to calculate the activity coefficient of ZnCl 2 at T=298.15 K. The formation of the ZnCl + complex has been taken into account by means of the Clegg-Pitzer-Brimblecombe equation.",
publisher = "Elsevier",
journal = "Journal of Chemical Thermodynamics",
title = "Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K",
volume = "35",
number = "7",
pages = "1073-1082",
doi = "10.1016/S0021-9614(03)00048-X"
}
Miladinović, J., Ninković, R., Todorović, M.,& Jovanović, V. M.. (2003). Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K. in Journal of Chemical Thermodynamics
Elsevier., 35(7), 1073-1082.
https://doi.org/10.1016/S0021-9614(03)00048-X
Miladinović J, Ninković R, Todorović M, Jovanović VM. Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K. in Journal of Chemical Thermodynamics. 2003;35(7):1073-1082.
doi:10.1016/S0021-9614(03)00048-X .
Miladinović, Jelena, Ninković, Rozalija, Todorović, Milica, Jovanović, Vladislava M., "Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K" in Journal of Chemical Thermodynamics, 35, no. 7 (2003):1073-1082,
https://doi.org/10.1016/S0021-9614(03)00048-X . .

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