The osmotic coefficient of ZnCl2 (aq) has been measured at T = 298.15 K by the isopiestic method over the range of molalities from (0.4 to 2.4)mol·kg -1 with KCl(aq) as the reference solution. The available literature data on the osmotic coefficient of ZnCl 2 (aq) at T = 298.15 K, and new experimental data were treated by the Clegg-Pitzer- Brimblecombe equation and the extended Pitzer's equation. These equations were used to calculate the activity coefficient of ZnCl 2 at T=298.15 K. The formation of the ZnCl + complex has been taken into account by means of the Clegg-Pitzer-Brimblecombe equation.
TY - JOUR
AU - Miladinović, Jelena
AU - Ninković, Rozalija
AU - Todorović, Milica
AU - Jovanović, Vladislava M.
PY - 2003
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/3655
AB - The osmotic coefficient of ZnCl2 (aq) has been measured at T = 298.15 K by the isopiestic method over the range of molalities from (0.4 to 2.4)mol·kg -1 with KCl(aq) as the reference solution. The available literature data on the osmotic coefficient of ZnCl 2 (aq) at T = 298.15 K, and new experimental data were treated by the Clegg-Pitzer- Brimblecombe equation and the extended Pitzer's equation. These equations were used to calculate the activity coefficient of ZnCl 2 at T=298.15 K. The formation of the ZnCl + complex has been taken into account by means of the Clegg-Pitzer-Brimblecombe equation.
PB - Elsevier
T2 - Journal of Chemical Thermodynamics
T1 - Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K
VL - 35
IS - 7
SP - 1073
EP - 1082
DO - 10.1016/S0021-9614(03)00048-X
ER -
@article{
author = "Miladinović, Jelena and Ninković, Rozalija and Todorović, Milica and Jovanović, Vladislava M.",
year = "2003",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/3655",
abstract = "The osmotic coefficient of ZnCl2 (aq) has been measured at T = 298.15 K by the isopiestic method over the range of molalities from (0.4 to 2.4)mol·kg -1 with KCl(aq) as the reference solution. The available literature data on the osmotic coefficient of ZnCl 2 (aq) at T = 298.15 K, and new experimental data were treated by the Clegg-Pitzer- Brimblecombe equation and the extended Pitzer's equation. These equations were used to calculate the activity coefficient of ZnCl 2 at T=298.15 K. The formation of the ZnCl + complex has been taken into account by means of the Clegg-Pitzer-Brimblecombe equation.",
publisher = "Elsevier",
journal = "Journal of Chemical Thermodynamics",
title = "Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K",
volume = "35",
number = "7",
pages = "1073-1082",
doi = "10.1016/S0021-9614(03)00048-X"
}
Miladinović, J., Ninković, R., Todorović, M.,& Jovanović, V. M. (2003). Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K.
Journal of Chemical Thermodynamics
Elsevier., 35(7), 1073-1082.
https://doi.org/10.1016/S0021-9614(03)00048-X
Miladinović J, Ninković R, Todorović M, Jovanović VM. Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K. Journal of Chemical Thermodynamics. 2003;35(7):1073-1082
Miladinović Jelena, Ninković Rozalija, Todorović Milica, Jovanović Vladislava M., "Osmotic coefficient of the ZnCl2(aq) at T = 298.15 K" Journal of Chemical Thermodynamics, 35, no. 7 (2003):1073-1082,
https://doi.org/10.1016/S0021-9614(03)00048-X .
