dc.creator | Perendija, Jovana | |
dc.creator | Veličković, Zlate S. | |
dc.creator | Cvijetić, Ilija | |
dc.creator | Rusmirović, Jelena | |
dc.creator | Ugrinović, Vukašin | |
dc.creator | Marinković, Aleksandar D. | |
dc.creator | Onjia, Antonije E. | |
dc.date.accessioned | 2020-08-26T09:02:57Z | |
dc.date.available | 2020-08-26T09:02:57Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0969-0239 | |
dc.identifier.issn | 1572-882X | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/3633 | |
dc.description.abstract | Abstract: An optimized method is presented to make magnetite (MG) modified cellulose membrane (Cell-MG) from 3-aminopropyltriethoxysilane and diethylenetriaminepentaacetic acid dianhydride functionalized waste cell fibers; (Cell-NH2 and Cell-DTPA), and amino-modified diatomite. Functionalized Cell-NH2, Cell-DTPA fibers, and diatomite were structurally and morphologically characterized using FT-IR, Raman, and FE-SEM analysis. Amino and carboxyl group content was determined via standard volumetric methods. Response surface method was applied to rationalize the number of experiments related to Cell-MG synthesis and heavy metal ions column adsorption experiments. The effects of pH, contact time, temperature, and initial concentration of pollutants on adsorption and kinetics were studied in a batch, while initial concentration and flow rate were studied in a flow system. The calculated capacities of 88.2, 100.7, 95.8 and 78.2 mg g−1 for Ni2+, Pb2+, Cr(VI) and As(V) ions, respectively, were obtained from Langmuir model fitting. Intra-particle diffusion as a rate-limiting step was evaluated from pseudo-second-order and Weber–Morris model fitting. Thermodynamic parameters indicated spontaneous and low endothermic processes. The results from reusability study, wastewater purification and fixed-bed column study proved the high applicability of Cell-MG. Additionally, high removal capacity of four dyes together with density functional theory and molecular interaction fields, help in the establishment of relation between the adsorption performances and contribution of non-specific and specific interactions at adsorbate/adsorbent interface. | en |
dc.language.iso | en | sr |
dc.publisher | Springer | sr |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200026/RS// | sr |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200325/RS// | sr |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200288/RS// | sr |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200135/RS// | sr |
dc.rights | restrictedAccess | sr |
dc.source | Cellulose | sr |
dc.subject | Cellulose membrane | sr |
dc.subject | Magnetite | sr |
dc.subject | Batch adsorption | sr |
dc.subject | Fixed-bed column adsorption study | sr |
dc.subject | Pollutant | sr |
dc.title | Batch and column adsorption of cations, oxyanions and dyes on a magnetite modified cellulose-based membrane | en |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dcterms.abstract | Угриновић, Вукашин; Цвијетић, Илија; Перендија, Јована; Величковић, Злате С.; Русмировић, Јелена; Оњиа, Aнтоније; Маринковић, Aлександар Д.; | |
dc.rights.holder | Springer | sr |
dc.citation.volume | 27 | |
dc.citation.spage | 8215 | |
dc.citation.epage | 8235 | |
dc.citation.rank | aM21~ | |
dc.identifier.doi | 10.1007/s10570-020-03352-x | |
dc.identifier.scopus | 2-s2.0-85088278515 | |
dc.identifier.wos | 000550616700002 | |
dc.type.version | publishedVersion | sr |