dc.creator | Fitzpatrick, Anthony J. | |
dc.creator | Stepanović, Stepan | |
dc.creator | Mueller-Bunz, Helge | |
dc.creator | Gruden-Pavlović, Maja | |
dc.creator | Garcia-Fernandez, Pablo | |
dc.creator | Morgan, Grace G. | |
dc.date.accessioned | 2020-08-19T15:09:20Z | |
dc.date.available | 2017-03-07 | |
dc.date.issued | 2016 | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/3625 | |
dc.description.abstract | Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation is dependent on the nature of the charge-balancing anion, with small anions yielding a planar elongation and large anions freezing out a preferential axial elongation along one of the amine-Mn-imine directions within that same plane. Modulation of the lattice by changing the charge balancing anion results in mixing of the orbital symmetry due to vibrational perturbation. | en |
dc.publisher | Royal Soc Chemistry, Cambridge | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS// | |
dc.relation | COST Action [CM1305] | |
dc.relation | Ramon y Cajal fellowship [RYC-2013-12515] | |
dc.relation | Cultural Service of the French Embassy in Ireland | |
dc.relation | Science Foundation Ireland [12/IP/1703] | |
dc.relation | Irish Higher Education Authority | |
dc.relation | National University of Ireland | |
dc.relation | University College Dublin | |
dc.rights | embargoedAccess | |
dc.source | Dalton Transactions | |
dc.title | Challenges in assignment of orbital populations in a high spin manganese(III) complex | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Фитзпатрицк, Aнтхонy Ј.; Груден-Павловић, Маја; Гарциа-Фернандез, Пабло; Муеллер-Бунз, Хелге; Морган, Граце Г.; Степановић, Степан; | |
dc.citation.volume | 45 | |
dc.citation.issue | 15 | |
dc.citation.spage | 6702 | |
dc.citation.epage | 6708 | |
dc.citation.other | 45(15): 6702-6708 | |
dc.citation.rank | M21 | |
dc.description.other | Published version: [http://cer.ihtm.bg.ac.rs/handle/123456789/3624] | |
dc.description.other | This is peer-reviewed version of the following article: Fitzpatrick, A. J.; Stepanovic, S.; Müller-Bunz, H.; Gruden-Pavlović, M. A.; García-Fernández, P.; Morgan, G. G. Challenges in Assignment of Orbital Populations in a High Spin Manganese(Iii) Complex. Dalton Transactions 2016, 45 (15), 6702–6708. [https://doi.org/10.1039/c5dt03914b] | |
dc.identifier.pmid | 26974518 | |
dc.identifier.doi | 10.1039/c5dt03914b | |
dc.identifier.fulltext | https://cer.ihtm.bg.ac.rs/bitstream/id/17161/Acc_C5DT03914B.pdf | |
dc.identifier.scopus | 2-s2.0-84964680292 | |
dc.identifier.wos | 000373994800044 | |
dc.type.version | acceptedVersion | en |