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dc.creatorFitzpatrick, Anthony J.
dc.creatorStepanović, Stepan
dc.creatorMueller-Bunz, Helge
dc.creatorGruden-Pavlović, Maja
dc.creatorGarcia-Fernandez, Pablo
dc.creatorMorgan, Grace G.
dc.date.accessioned2020-08-19T15:09:20Z
dc.date.available2017-03-07
dc.date.issued2016
dc.identifier.issn1477-9226
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/3625
dc.description.abstractMagnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation is dependent on the nature of the charge-balancing anion, with small anions yielding a planar elongation and large anions freezing out a preferential axial elongation along one of the amine-Mn-imine directions within that same plane. Modulation of the lattice by changing the charge balancing anion results in mixing of the orbital symmetry due to vibrational perturbation.en
dc.publisherRoyal Soc Chemistry, Cambridge
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS//
dc.relationCOST Action [CM1305]
dc.relationRamon y Cajal fellowship [RYC-2013-12515]
dc.relationCultural Service of the French Embassy in Ireland
dc.relationScience Foundation Ireland [12/IP/1703]
dc.relationIrish Higher Education Authority
dc.relationNational University of Ireland
dc.relationUniversity College Dublin
dc.rightsembargoedAccess
dc.sourceDalton Transactions
dc.titleChallenges in assignment of orbital populations in a high spin manganese(III) complexen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractФитзпатрицк, Aнтхонy Ј.; Груден-Павловић, Маја; Гарциа-Фернандез, Пабло; Муеллер-Бунз, Хелге; Морган, Граце Г.; Степановић, Степан;
dc.citation.volume45
dc.citation.issue15
dc.citation.spage6702
dc.citation.epage6708
dc.citation.other45(15): 6702-6708
dc.citation.rankM21
dc.description.otherPublished version: [http://cer.ihtm.bg.ac.rs/handle/123456789/3624]
dc.description.otherThis is peer-reviewed version of the following article: Fitzpatrick, A. J.; Stepanovic, S.; Müller-Bunz, H.; Gruden-Pavlović, M. A.; García-Fernández, P.; Morgan, G. G. Challenges in Assignment of Orbital Populations in a High Spin Manganese(Iii) Complex. Dalton Transactions 2016, 45 (15), 6702–6708. [https://doi.org/10.1039/c5dt03914b]
dc.identifier.pmid26974518
dc.identifier.doi10.1039/c5dt03914b
dc.identifier.rcubKon_3031
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs/bitstream/id/17161/Acc_C5DT03914B.pdf
dc.identifier.scopus2-s2.0-84964680292
dc.identifier.wos000373994800044
dc.type.versionacceptedVersionen


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