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dc.creatorPagnacco, Maja
dc.creatorMaksimović, Jelena
dc.creatorMudrinić, Tihana
dc.creatorBanković, Predrag
dc.creatorNedić-Vasiljević, Bojana
dc.creatorMilutinović Nikolić, Aleksandra
dc.date.accessioned2020-08-19T07:07:41Z
dc.date.available2020-08-19T07:07:41Z
dc.date.issued2020
dc.identifier.issn2365-6549
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/3616
dc.description.abstractThe oscillatory Briggs‐Rauscher (BR) reaction was applied on solid insoluble materials i. e. bentonite clays. Under the same BR experimental conditions, the addition of identical masses of bentonite of different origin resulted in different effects on oscillatory time duration (τ): no influence, quenching, or prolongation. It was found that the following bentonite properties: montmorillonite/beidellite ratio; cation exchange capacity; principal exchange cation; extent of iron leaching in acidic environment of BR reaction; and specific surface area of clay were not exclusively responsible for observed behavior. On the other hand, the influence of added mass, for all investigated clays, resulted in the same behavior pattern. The increase of the mass of added clay increased τ up to the certain maximal value (τmax, mmax) characteristic for each clay. Further increase of mass resulted in quenching. Therefore, (τmax, mmax) pair can be regarded as the “fingerprint” characteristic of bentonite useful for identification of its origin. Furthermore, the addition of naturally occurring and non‐toxic clay in an oscillatory reaction can offer a versatile approach to tune the oscillation dynamics of nonlinear chemical systems.en
dc.language.isoensr
dc.publisherWileysr
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200146/RS//sr
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200026/RS//sr
dc.rightsrestrictedAccesssr
dc.sourceChemistry Selectsr
dc.subjectOscillatory Briggs‐Rauscher reactionsr
dc.subjectBentonite clayssr
dc.subjectOscillatory time durationsr
dc.subjectOscillation dynamicssr
dc.subjectNonlinear chemical systemssr
dc.titleOscillatory Briggs-Rauscher Reaction as “Fingerprint” for Bentonite Identification: The Fine-Tuning of Oscillatory Dynamics with Addition of Clayen
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractМаксимовић, Јелена; Милутиновић Николић, Aлександра; Пагнаццо, Маја; Недић-Васиљевић, Бојана; Мудринић, Тихана; Банковић, Предраг;
dc.citation.volume5
dc.citation.issue27
dc.citation.spage8137
dc.citation.epage8141
dc.citation.rankM23~
dc.identifier.doi10.1002/slct.202000874
dc.identifier.scopus2-s2.0-85088381217
dc.identifier.wos000551242200013
dc.type.versionpublishedVersionsr


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