Bray–Liebhafsky oscillatory reaction as the matrix system for the kinetic determination of microquantities of alizarin and purpurin
Authorized Users Only
2020
Authors
Maksimović, Jelena
Čupić, Željko

Manojlović, Nedeljko

Đerić, Aleksandra
Anić, Slobodan
Kolar-Anić, Ljiljana

Article (Published version)

Metadata
Show full item recordAbstract
Two hydroxyanthraquinones, alizarin and purpurin, that have been used throughout
history as a natural pigment, were extracted from roots of Rubia tinctorum from
Serbia. As substances with important chemical activities and, therefore, with wide
applications (for example in dyeing textile fabrics as well as in pharmacy because of
their anti-inflammatory, anti-cancer, antiviral, antimicrobial and antioxidant activities,
etc.) they were analyzed in the kinetically very sensitive Bray–Liebhafsky (BL)
oscillatory reaction. However, although they are both, hydroxyanthraquinones it is
shown that their interactions with BL nonlinear reaction system differ significantly.
Consequently, two different reactions were used to explain the mechanism of their
chemical activities. The numerical simulations based on a standard model of the BL
oscillatory reaction together with proposed reactions due to alizarin/purpurin interactions
with a matrix are correlated with experimental investigations.... Moreover, it
is shown that very small amounts of alizarin and purpurin (from about 1 × 10–7 M)
produce the response of the BL matrix such that micro-quantitative analysis based
on the BL oscillatory reaction can be successfully performed in this reaction system.
The linear response of the BL matrix on the presence of alizarin and purpurin
(necessary for microquantitative determination) is analyzed as a function of two
concentration sensitive parameters: pre-oscillatory period τ1 and potential shift after
perturbation ΔE.
Keywords:
Kinetic determination of alizarin and purpurin / Bray–Liebhafsky oscillatory reaction as the matrix system / Microquantitative determination of alizarin and purpurin / Mechanism of interaction / Extraction of alizarin and purpurin from roots of Rubia tinctorumSource:
Reaction Kinetics, Mechanisms and Catalysis, 2020, 130, 655-688Publisher:
- Springer Nature Switzerland AG 2020
Funding / projects:
- Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions (RS-172015)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200111 (University of Kragujevac, Faculty of Medicine) (RS-200111)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200146 (University of Belgrade, Faculty of Physical Chemistry) (RS-200146)
- Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)
DOI: 10.1007/s11144-020-01798-5
ISSN: 1878-5190; 1878-5204
WoS: 000539198600001
Scopus: 2-s2.0-85086167239
Collections
Institution/Community
IHTMTY - JOUR AU - Maksimović, Jelena AU - Čupić, Željko AU - Manojlović, Nedeljko AU - Đerić, Aleksandra AU - Anić, Slobodan AU - Kolar-Anić, Ljiljana PY - 2020 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3603 AB - Two hydroxyanthraquinones, alizarin and purpurin, that have been used throughout history as a natural pigment, were extracted from roots of Rubia tinctorum from Serbia. As substances with important chemical activities and, therefore, with wide applications (for example in dyeing textile fabrics as well as in pharmacy because of their anti-inflammatory, anti-cancer, antiviral, antimicrobial and antioxidant activities, etc.) they were analyzed in the kinetically very sensitive Bray–Liebhafsky (BL) oscillatory reaction. However, although they are both, hydroxyanthraquinones it is shown that their interactions with BL nonlinear reaction system differ significantly. Consequently, two different reactions were used to explain the mechanism of their chemical activities. The numerical simulations based on a standard model of the BL oscillatory reaction together with proposed reactions due to alizarin/purpurin interactions with a matrix are correlated with experimental investigations. Moreover, it is shown that very small amounts of alizarin and purpurin (from about 1 × 10–7 M) produce the response of the BL matrix such that micro-quantitative analysis based on the BL oscillatory reaction can be successfully performed in this reaction system. The linear response of the BL matrix on the presence of alizarin and purpurin (necessary for microquantitative determination) is analyzed as a function of two concentration sensitive parameters: pre-oscillatory period τ1 and potential shift after perturbation ΔE. PB - Springer Nature Switzerland AG 2020 T2 - Reaction Kinetics, Mechanisms and Catalysis T1 - Bray–Liebhafsky oscillatory reaction as the matrix system for the kinetic determination of microquantities of alizarin and purpurin VL - 130 SP - 655 EP - 688 DO - 10.1007/s11144-020-01798-5 ER -
@article{ author = "Maksimović, Jelena and Čupić, Željko and Manojlović, Nedeljko and Đerić, Aleksandra and Anić, Slobodan and Kolar-Anić, Ljiljana", year = "2020", abstract = "Two hydroxyanthraquinones, alizarin and purpurin, that have been used throughout history as a natural pigment, were extracted from roots of Rubia tinctorum from Serbia. As substances with important chemical activities and, therefore, with wide applications (for example in dyeing textile fabrics as well as in pharmacy because of their anti-inflammatory, anti-cancer, antiviral, antimicrobial and antioxidant activities, etc.) they were analyzed in the kinetically very sensitive Bray–Liebhafsky (BL) oscillatory reaction. However, although they are both, hydroxyanthraquinones it is shown that their interactions with BL nonlinear reaction system differ significantly. Consequently, two different reactions were used to explain the mechanism of their chemical activities. The numerical simulations based on a standard model of the BL oscillatory reaction together with proposed reactions due to alizarin/purpurin interactions with a matrix are correlated with experimental investigations. Moreover, it is shown that very small amounts of alizarin and purpurin (from about 1 × 10–7 M) produce the response of the BL matrix such that micro-quantitative analysis based on the BL oscillatory reaction can be successfully performed in this reaction system. The linear response of the BL matrix on the presence of alizarin and purpurin (necessary for microquantitative determination) is analyzed as a function of two concentration sensitive parameters: pre-oscillatory period τ1 and potential shift after perturbation ΔE.", publisher = "Springer Nature Switzerland AG 2020", journal = "Reaction Kinetics, Mechanisms and Catalysis", title = "Bray–Liebhafsky oscillatory reaction as the matrix system for the kinetic determination of microquantities of alizarin and purpurin", volume = "130", pages = "655-688", doi = "10.1007/s11144-020-01798-5" }
Maksimović, J., Čupić, Ž., Manojlović, N., Đerić, A., Anić, S.,& Kolar-Anić, L.. (2020). Bray–Liebhafsky oscillatory reaction as the matrix system for the kinetic determination of microquantities of alizarin and purpurin. in Reaction Kinetics, Mechanisms and Catalysis Springer Nature Switzerland AG 2020., 130, 655-688. https://doi.org/10.1007/s11144-020-01798-5
Maksimović J, Čupić Ž, Manojlović N, Đerić A, Anić S, Kolar-Anić L. Bray–Liebhafsky oscillatory reaction as the matrix system for the kinetic determination of microquantities of alizarin and purpurin. in Reaction Kinetics, Mechanisms and Catalysis. 2020;130:655-688. doi:10.1007/s11144-020-01798-5 .
Maksimović, Jelena, Čupić, Željko, Manojlović, Nedeljko, Đerić, Aleksandra, Anić, Slobodan, Kolar-Anić, Ljiljana, "Bray–Liebhafsky oscillatory reaction as the matrix system for the kinetic determination of microquantities of alizarin and purpurin" in Reaction Kinetics, Mechanisms and Catalysis, 130 (2020):655-688, https://doi.org/10.1007/s11144-020-01798-5 . .