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Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics

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2010
rSE_SEE_6proc.pdf (2.134Mb)
Authors
Panić, Vladimir
Vidaković-Koch, Tanja
Živković, Luka
Petkovska, Menka
Sundmacher, Kai
Conference object (Published version)
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Abstract
In general, electrochemical (EC) systems are non-linear, which means they respond nonlinearly to a frequency-dependent periodic input perturbation of high amplitude imposed around a steady-state. In addition, the kinetics of EC reactions are quite complex and different rivalling model presentations can be formulated for certain EC reaction. While standard electrochemical methods (steady-state and electrochemical impedance spectroscopy) showed low sensitivity towards the model discrimination, non-linear frequency response analysis (NLFRA) of EC kinetics can appear advantageous for this purpose. In this work, NLFRA is applied in experimental and theoretical study of ferrocyanide oxidation as a model EC reaction.
Keywords:
Electrochemical reactions / Kinetics / Ferrocyanide oxidation
Source:
Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings, 2010, 145-148
Publisher:
  • Serbian Chemical Society, Belgrade
Note:
  • Belgrade, Serbia, June 6-10, 2010
  • Related to the http://cer.ihtm.bg.ac.rs/handle/123456789/3538

ISBN: 978-86-7132-044-3

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_cer_3539
URI
http://www.aseee.eu/index.php/rsesee2-home
https://cer.ihtm.bg.ac.rs/handle/123456789/3539
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - CONF
AU  - Panić, Vladimir
AU  - Vidaković-Koch, Tanja
AU  - Živković, Luka
AU  - Petkovska, Menka
AU  - Sundmacher, Kai
PY  - 2010
UR  - http://www.aseee.eu/index.php/rsesee2-home
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3539
AB  - In general, electrochemical (EC) systems are non-linear, which means they respond nonlinearly to a frequency-dependent periodic input perturbation of high amplitude imposed around a steady-state. In addition, the kinetics of EC reactions are quite complex and different rivalling model presentations can be formulated for certain EC reaction. While standard electrochemical methods (steady-state and electrochemical impedance spectroscopy) showed low sensitivity towards the model discrimination, non-linear frequency response analysis (NLFRA) of EC kinetics can appear advantageous for this purpose. In this work, NLFRA is applied in experimental and theoretical study of ferrocyanide oxidation as a model EC reaction.
PB  - Serbian Chemical Society, Belgrade
C3  - Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings
T1  - Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics
SP  - 145
EP  - 148
UR  - https://hdl.handle.net/21.15107/rcub_cer_3539
ER  - 
@conference{
author = "Panić, Vladimir and Vidaković-Koch, Tanja and Živković, Luka and Petkovska, Menka and Sundmacher, Kai",
year = "2010",
abstract = "In general, electrochemical (EC) systems are non-linear, which means they respond nonlinearly to a frequency-dependent periodic input perturbation of high amplitude imposed around a steady-state. In addition, the kinetics of EC reactions are quite complex and different rivalling model presentations can be formulated for certain EC reaction. While standard electrochemical methods (steady-state and electrochemical impedance spectroscopy) showed low sensitivity towards the model discrimination, non-linear frequency response analysis (NLFRA) of EC kinetics can appear advantageous for this purpose. In this work, NLFRA is applied in experimental and theoretical study of ferrocyanide oxidation as a model EC reaction.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings",
title = "Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics",
pages = "145-148",
url = "https://hdl.handle.net/21.15107/rcub_cer_3539"
}
Panić, V., Vidaković-Koch, T., Živković, L., Petkovska, M.,& Sundmacher, K.. (2010). Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings
Serbian Chemical Society, Belgrade., 145-148.
https://hdl.handle.net/21.15107/rcub_cer_3539
Panić V, Vidaković-Koch T, Živković L, Petkovska M, Sundmacher K. Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings. 2010;:145-148.
https://hdl.handle.net/21.15107/rcub_cer_3539 .
Panić, Vladimir, Vidaković-Koch, Tanja, Živković, Luka, Petkovska, Menka, Sundmacher, Kai, "Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics" in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Proceedings (2010):145-148,
https://hdl.handle.net/21.15107/rcub_cer_3539 .

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