In general, electrochemical (EC) systems are non-linear, which means they respond nonlinearly to a frequency-dependent periodic input perturbation of high amplitude imposed around a steady-state. In addition, the kinetics of EC reactions are quite complex and different rivalling model presentations can be formulated for certain EC reaction. While standard electrochemical methods (steady-state and electrochemical impedance spectroscopy) showed low sensitivity towards the model discrimination, non-linear frequency response analysis (NLFRA) of EC kinetics can appear advantageous for this purpose. In this work, NLFRA is applied in experimental and theoretical study of ferrocyanide oxidation as a model EC reaction.
TY - CONF
AU - Panić, Vladimir
AU - Vidaković-Koch, Tanja
AU - Živković, Luka
AU - Petkovska, Menka
AU - Sundmacher, Kai
PY - 2010
UR - http://www.aseee.eu/index.php/rsesee2-home
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3538
AB - In general, electrochemical (EC) systems are non-linear, which means they respond nonlinearly to a frequency-dependent periodic input perturbation of high amplitude imposed around a steady-state. In addition, the kinetics of EC reactions are quite complex and different rivalling model presentations can be formulated for certain EC reaction. While standard electrochemical methods (steady-state and electrochemical impedance spectroscopy) showed low sensitivity towards the model discrimination, non-linear frequency response analysis (NLFRA) of EC kinetics can appear advantageous for this purpose. In this work, NLFRA is applied in experimental and theoretical study of ferrocyanide oxidation as a model EC reaction.
PB - Serbian Chemical Society, Belgrade
C3 - Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts
T1 - Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics
SP - 80
EP - 80
UR - https://hdl.handle.net/21.15107/rcub_cer_3538
ER -
@conference{
author = "Panić, Vladimir and Vidaković-Koch, Tanja and Živković, Luka and Petkovska, Menka and Sundmacher, Kai",
year = "2010",
abstract = "In general, electrochemical (EC) systems are non-linear, which means they respond nonlinearly to a frequency-dependent periodic input perturbation of high amplitude imposed around a steady-state. In addition, the kinetics of EC reactions are quite complex and different rivalling model presentations can be formulated for certain EC reaction. While standard electrochemical methods (steady-state and electrochemical impedance spectroscopy) showed low sensitivity towards the model discrimination, non-linear frequency response analysis (NLFRA) of EC kinetics can appear advantageous for this purpose. In this work, NLFRA is applied in experimental and theoretical study of ferrocyanide oxidation as a model EC reaction.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts",
title = "Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics",
pages = "80-80",
url = "https://hdl.handle.net/21.15107/rcub_cer_3538"
}
Panić, V., Vidaković-Koch, T., Živković, L., Petkovska, M.,& Sundmacher, K.. (2010). Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts
Serbian Chemical Society, Belgrade., 80-80.
https://hdl.handle.net/21.15107/rcub_cer_3538
Panić V, Vidaković-Koch T, Živković L, Petkovska M, Sundmacher K. Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics. in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts. 2010;:80-80.
https://hdl.handle.net/21.15107/rcub_cer_3538 .
Panić, Vladimir, Vidaković-Koch, Tanja, Živković, Luka, Petkovska, Menka, Sundmacher, Kai, "Non-linear frequency response analysis of the kinetics of electrochemical reactions: a case study – ferrocyanide oxidation kinetics" in Second Regional Symposium on Electrochemistry South-East Europe, RSE-SEE, Program and Book of Abstracts (2010):80-80,
https://hdl.handle.net/21.15107/rcub_cer_3538 .
