Electrochemical behavior of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives studied by cyclic voltammetry
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This study demonstrates the electrochemical activity of selected 2-alkylidene-4-oxothiazolidine compounds containing different substituents at the C5-position on the Pt-electrode in 0.1 M TBAHFP + MeCN in the potential range from -2 V to 2 V. The mechanism of electrode processes is discussed. It is shown that a chemical step is involved in irreversible electrochemical processes. The effect of the substituent at the C5-position on reduction and oxidation potentials is also noted. The regions of a linear dependence of the current peak on the concentration of the compounds examined are determined.
Извор:Russian Journal of Physical Chemistry A, 2007, 81, 9, 1458-1462
- Maik Nauka/Interperiodica/Springer, New York