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Determination of all pK(a) values of some di- and tri-carboxylic unsaturated and epoxy acids and their polylinear correlation with the carboxylic group atomic charges

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2003
Authors
Pfendt, Lidija
Dražić, Branka
Popović, Gordana
Drakulić, Branko
Vitnik, Željko
Juranić, Ivan
Article (Published version)
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Abstract
For a series of seven unsaturated and seven epoxy di- and tricarboxylic acids, pK(a)(a) values were determined potentiometrically in aqueous media at 25 degreesC and an ionic strength of 0.1 M (NaCl). The thermodynamic pKaa values were correlated with the atomic charges of carboxylic group calculated by the MNDO-PM3 semiempirical MO method.
Keywords:
Dicarboxylic epoxy acid / Polylinear correlation / Tricarboxylic epoxy acid
Source:
Journal of Chemical Research - Part S, 2003, 5, 247-248
Publisher:
  • Scientific Reviews Ltd.

DOI: 10.3184/030823403103173732

ISSN: 0308-2342

WoS: 000185578100001

Scopus: 2-s2.0-0141791078
[ Google Scholar ]
3
2
URI
http://farfar.pharmacy.bg.ac.rs/handle/123456789/457
http://cer.ihtm.bg.ac.rs/handle/123456789/3510
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