The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °...C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.
TY - JOUR
AU - Dodevski, Vladimir
AU - Pagnacco, Maja
AU - Radović, Ivana
AU - Rosić, Milena
AU - Janković, Bojan
AU - Stojmenović, Marija
AU - Mitić, Vojislav V.
PY - 2020
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3436
AB - The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.
PB - Elsevier
T2 - Materials Chemistry and Physics
T1 - Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization
VL - 245
SP - 122768
DO - 10.1016/j.matchemphys.2020.122768
ER -
@article{
author = "Dodevski, Vladimir and Pagnacco, Maja and Radović, Ivana and Rosić, Milena and Janković, Bojan and Stojmenović, Marija and Mitić, Vojislav V.",
year = "2020",
abstract = "The aim of this research was to obtain a carbon solid residue by the carbonization process of biomass in an inert atmosphere which, through physical activation and chemical treatment (using TEOS - tetraethyl orthosilicate) would allow creation of highly porous and spatially distinct ordered bio-SiC ceramics. The results of carbonization experiments at several operating temperatures and activation of carbons with multiple-cycle treatments TEOS clearly showed the possibility of obtaining SiC nano-structures, after performing the carbothermal reduction at 1400 °C. The increase in the activation temperature and the duration time starts the development of the SiC particles inside the porous structure. The XRPD analysis showed that the major SiC polytype has cubic SiC (β-SiC) structure and remainder is hexagonal SiC polytypic (α-SiC) structure. It was established that the carbons obtained from carbonization of the Platanus orientalis L. plane tree fruit (PTF) precursor and activated at 850 °C with longer holding times (1 and 2 h) exhibit β-SiC (cubic) nano-wires. A possible nano-wires increment mechanism was suggested. The obtained results represent significant contribution in understanding the process as well as the main characteristics of SiC nano-materials and their possible applications.",
publisher = "Elsevier",
journal = "Materials Chemistry and Physics",
title = "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization",
volume = "245",
pages = "122768",
doi = "10.1016/j.matchemphys.2020.122768"
}
Dodevski, V., Pagnacco, M., Radović, I., Rosić, M., Janković, B., Stojmenović, M.,& Mitić, V. V.. (2020). Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics
Elsevier., 245, 122768.
https://doi.org/10.1016/j.matchemphys.2020.122768
Dodevski V, Pagnacco M, Radović I, Rosić M, Janković B, Stojmenović M, Mitić VV. Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization. in Materials Chemistry and Physics. 2020;245:122768.
doi:10.1016/j.matchemphys.2020.122768 .
Dodevski, Vladimir, Pagnacco, Maja, Radović, Ivana, Rosić, Milena, Janković, Bojan, Stojmenović, Marija, Mitić, Vojislav V., "Characterization of silicon carbide ceramics obtained from porous carbon structure achieved by plant carbonization" in Materials Chemistry and Physics, 245 (2020):122768,
https://doi.org/10.1016/j.matchemphys.2020.122768 . .
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