CER - Central Repository
Institute of Chemistry, Technology and Metallurgy
    • English
    • Српски
    • Српски (Serbia)
  • English 
    • English
    • Serbian (Cyrilic)
    • Serbian (Latin)
  • Login
View Item 
  •   Central Repository
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
  •   Central Repository
  • IHTM
  • Radovi istraživača / Researchers' publications
  • View Item
JavaScript is disabled for your browser. Some features of this site may not work without it.

Aluminum/zirconium alloys obtained by Al underpotential deposition onto Zr from low temperature AlCl3+NaCl molten salts

Thumbnail
2019
0352-51391900073C.pdf (4.297Mb)
Authors
Cvetković, Vesna S.
Jovićević, Niko
Vukićević, Nataša
Jovićević, Jovan N.
Article (Published version)
Metadata
Show full item record
Abstract
Contrary to the widely accepted hypothesis that it is not possible, aluminum underpotential deposition (UPD) onto zirconium from a low temperature (200, 250 and 300 °C) equimolar chloroaluminate melt was recorded. Furthermore, it was shown that aluminum UPD facilitates alloy formation between the deposited aluminum monolayer and the zirconium substrate by interdiffusion. The aluminum/zirconium alloys formed at temperatures substantially lower than those needed for thermal preparation of the same alloys were Al3Zr2 and Al3Zr. The experimental techniques linear sweep voltammetry, potential step, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction were used for the characterization of the obtained electrode surfaces.
Keywords:
electrochemical metal deposition / chloroaluminate melt / solid state interdiffusion / intermetallics
Source:
Journal of the Serbian Chemical Society, 2019, 84, 11, 1329-1344
Publisher:
  • Serbian Chemical Society

DOI: 10.2298/JSC190620073C

ISSN: 0352-5139

WoS: 000500748300012

Scopus: 2-s2.0-85076341234
[ Google Scholar ]
1
URI
http://cer.ihtm.bg.ac.rs/handle/123456789/3381
Collections
  • Radovi istraživača / Researchers' publications
Institution
IHTM

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

OpenAIRERCUB
 

 

All of DSpaceInstitutionsAuthorsTitlesSubjectsThis institutionAuthorsTitlesSubjects

Statistics

View Usage Statistics

DSpace software copyright © 2002-2015  DuraSpace
About CeR – Central Repository | Send Feedback

OpenAIRERCUB