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dc.creatorNikolić, Nebojša D.
dc.creatorŽivković, Predrag M.
dc.creatorPavlović, Miomir
dc.creatorBaščarević, Zvezdana
dc.date.accessioned2020-01-26T16:12:53Z
dc.date.available2020-01-26T16:12:53Z
dc.date.issued2019
dc.identifier.issn0352-5139
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/3380
dc.description.abstractThe morphologies of copper dendritic forms obtained in both potentiostatic and galvanostatic regimes of electrolysis with various amounts of the electricity were analyzed by the scanning electron microscopy (SEM) technique. Irrespective of amount of passed electricity, 3D (three dimensional) pine-like dendrites with sharp tips were formed in the potentiostatic regime of electrolysis. On the other hand, the amount of passed electricity had a strong effect on the shape of the 3D pine-like dendrites formed in the galvanostatic regime of electrolysis. Dendrites with sharp tips were formed with smaller amount of passed electricity, while dendrites with globular tips were formed with larger amounts. The change in the shape of the galvanostatically synthesized 3D pine-like dendrites was explained by comparison with copper deposits obtained potentiostatically at overpotentials that corresponded to the final overpotentials during galvanostatic regime of electrolysis for the analyzed amounts of electricity. Based on the similarity of the obtained morphologies at the macro level, it was concluded that the overpotential plays a crucial role in the formation of the electrolytically synthesized dendrites and that the controlled conditions of electrolysis could represent a suitable way for a synthesis of spherical Cu particles by electrolysis.en
dc.language.isoensr
dc.publisherSerbian Chemical Societysr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS//sr
dc.rightsopenAccesssr
dc.sourceJournal of the Serbian Chemical Societysr
dc.subjectelectrolysissr
dc.subjectcoppersr
dc.subjectpowdersr
dc.subjectdendritesr
dc.subjectscanning electron microscope (SEM)sr
dc.titleOverpotential controls the morphology of electrolytically produced copper dendritic formsen
dc.typearticlesr
dc.rights.licenseBY-NC-NDsr
dcterms.abstractНиколић, Небојша Д.; Живковић, Предраг М.; Павловић, Миомир Г.; Башчаревић, Звездана;
dc.citation.volume84
dc.citation.issue11
dc.citation.spage1209
dc.citation.epage1220
dc.citation.rankM23~
dc.identifier.doi10.2298/JSC190522066N
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs/bitstream/id/16001/0352-51391900066N.pdf
dc.identifier.scopus2-s2.0-85076381290
dc.identifier.wos000500748300003
dc.type.versionpublishedVersionsr


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