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dc.creatorCvetković, Vesna S.
dc.creatorVukićević, Nataša
dc.creatorMilićević-Neumann, Ksenija
dc.creatorStopić, Srećko
dc.creatorFriedrich, Bernd
dc.creatorJovićević, Jovan N.
dc.date.accessioned2020-01-25T12:55:38Z
dc.date.available2020-01-25T12:55:38Z
dc.date.issued2020
dc.identifier.issn2075-4701
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/3377
dc.description.abstractAl-Ti alloys were electrodeposited from equimolar chloroaluminate molten salts containing up to 0.1 M of titanium ions, which were added to the electrolyte by potentiostatic dissolution of metallic Ti. Titanium dissolution and titanium and aluminium deposition were investigated by linear sweep voltammetry and chronoamperometry at 200 and 300 °C. Working electrodes used were titanium and glassy carbon. The voltammograms on Ti obtained in the electrolyte without added Ti ions indicated titanium deposition and dissolution proceeding in three reversible steps: Ti4+ ⇄ Ti3+, Ti3+ ⇄ Ti2+ and Ti2+ ⇄ Ti. The voltammograms recorded with glassy carbon in the electrolyte containing added titanium ions did not always clearly register all of the three processes. However, peak currents, which were characteristics of Al, Ti and Al-Ti alloy deposition and dissolution, were evident in voltammograms on both working electrodes used. A constant potential electrodeposition regime was used to obtain deposits on the glassy carbon working electrode. The obtained deposits were characterized by SEM, energy-dispersive spectrometry and XRD. In the deposits on the glassy carbon electrode, the analysis identified an Al and AlTi3 alloy formed at 200 °C and an Al2Ti and Al3Ti alloy obtained at 300 °C.en
dc.publisherMDPIen
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.sourceMetalsen
dc.subjectAl-Ti alloy
dc.subjectelectrochemical co-deposition
dc.subjectchloroaluminate melt
dc.subjectXRD
dc.titleElectrochemical Deposition of Al-Ti Alloys from Equimolar AlCl3 + NaCl Containing Electrochemically Dissolved Titaniumen
dc.typearticleen
dc.rights.licenseBY
dcterms.abstractФриедрицх, Бернд; Стопић, Срећко; Цветковић, Весна; Јовићевић, Јован Н.; Вукићевић, Наташа; Милићевић-Неуманн, Ксенија;
dc.rights.holderThe authors
dc.citation.volume10
dc.citation.issue1
dc.citation.spage88
dc.citation.rankM21~
dc.identifier.doi10.3390/met10010088
dc.identifier.fulltexthttps://cer.ihtm.bg.ac.rs/bitstream/id/15992/metals-10-00088-v2.pdf
dc.identifier.scopus2-s2.0-85077691425
dc.identifier.wos000516827800088
dc.type.versionpublishedVersion


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Приказ основних података о документу