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dc.creatorMiladinović, Marija R.
dc.creatorZdujić, Miodrag
dc.creatorVeljović, Đorđe
dc.creatorKrstić, Jugoslav
dc.creatorBanković-Ilić, Ivana B.
dc.creatorVeljković, Vlada B.
dc.creatorStamenković, Olivera
dc.date.accessioned2019-12-27T12:59:07Z
dc.date.available2021-09-17
dc.date.issued2020
dc.identifier.issn0960-1481
dc.identifier.urihttp://dais.sanu.ac.rs/123456789/6903
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/3319
dc.description.abstractThe catalytic activity of the walnut shell ash was investigated in the biodiesel production by the sunflower oil methanolysis. The catalyst was characterized by the TG-DTA, XRD, Hg porosimetry, N2 physisorption, SEM, and Hammett method. In addition, the effects of the catalyst loading and the methanol-to-oil molar ratio on the methyl esters synthesis were tested at the reaction temperature of 60 °C. The walnut shell ash provided a very fast reaction and a high FAME content (over 98%). As the reaction occurred in the absence of triacylglycerols mass transfer limitation, the pseudo-first-order model was employed for describing the kinetics of the reaction. The catalyst was successfully reused four times after the regeneration of the catalytic activity by recalcination at 800 °C.en
dc.language.isoensr
dc.publisherElseviersr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45001/RS//sr
dc.relationProject 0-14-18 of the SASA Branch in Niš, Serbiasr
dc.rightsembargoedAccesssr
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceRenewable Energysr
dc.subjectwalnut shellsr
dc.subjectsunflower oilsr
dc.subjectmethanolysissr
dc.subjectkineticssr
dc.subjectbiodieselsr
dc.subjectashsr
dc.titleValorization of walnut shell ash as a catalyst for biodiesel productionen
dc.typearticlesr
dc.rights.licenseBY-NC-NDsr
dcterms.abstractВељовић, Ђорђе; Крстић, Југослав Б.; Банковић Илић, Ивана Б.; Вељковић, Влада Б.; Стаменковић, Оливера С.; Здујић, Миодраг; Миладиновић, Марија Р.;
dc.citation.volume147
dc.citation.spage1033
dc.citation.epage1043
dc.citation.rankM21~
dc.description.otherThis is the peer reviewed version of the following article: Miladinović, M.R., Zdujić, M.V., Veljović, D.N., Krstić, J.B., Banković-Ilić, I.B., Veljković, V.B., Stamenković, O.S., 2020. Valorization of walnut shell ash as a catalyst for biodiesel production. Renewable Energy 147, 1033–1043. [https://doi.org/10.1016/j.renene.2019.09.056]
dc.description.otherThe published version: [https://cer.ihtm.bg.ac.rs/handle/123456789/3217]
dc.identifier.doi10.1016/j.renene.2019.09.056
dc.identifier.fulltexthttps://cer.ihtm.bg.ac.rs/bitstream/id/15806/10.1016.j.renene.2019.09.056.pdf
dc.identifier.scopus2-s2.0-85072388245
dc.identifier.wos000502880700091
dc.type.versionacceptedVersionsr


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