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Application of inverse gas chromatography for polymer characterization

Primena inverzne gasne hromatografije za karakterizaciju polimera

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2007
326.pdf (894.7Kb)
Authors
Nastasović, Aleksandra
Onjia, Antonije E.
Milonjić, Slobodan K.
Jovanović, Slobodan M.
Article (Published version)
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Abstract
The possibility of polymer characterization by inverse gas chromatography (IGC) was illustrated with the study of sorption properties of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), PGME, synthesized by suspension copolymerization, and copolymer modified with ethylene diamine, PGME-en. The data collected from IGC experiments at infinite dilution are used for the calculation of the thermodynamic parameters of adsorption, dispersive components of the surface free energies, and the acid/base constants. .
U okviru rada prikazane su mogućnosti korišćenja inverzne gasne hromatografije (IGC) za karakterizaciju polimera. Umreženi makroporozni kopolimer glicidilmetakrilata, GMA, i etilenglikoldimetakrilata, EGDMA, poli (GMA-co-EGDMA) sintetizovan je suspenzionom kopolimerizacijom, a zatim modifikovan reakcijom sa etilendiaminom. Uzorcima polaznog i modifikovanog kopolimera, poli(GMA-co-EGDMA)-en, su pri nultoj prekrivenosti određeni termodinamički parametri adsorpcije, disperzivna komponenta slobodne površinske energije i kiselo/bazna svojstva.
Keywords:
IGC / glycidyl methacrylate based copolymers / IGC / kopolimeri na bazi glicidilmetakrilata
Source:
Hemijska industrija, 2007, 61, 6, 342-349
Publisher:
  • Association of Chemical Engineers of Serbia

DOI: 10.2298/HEMIND0706342N

ISSN: 0367-598X

WoS: 000255027100002

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URI
https://cer.ihtm.bg.ac.rs/handle/123456789/328
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije E.
AU  - Milonjić, Slobodan K.
AU  - Jovanović, Slobodan M.
PY  - 2007
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/328
AB  - The possibility of polymer characterization by inverse gas chromatography (IGC) was illustrated with the study of sorption properties of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), PGME, synthesized by suspension copolymerization, and copolymer modified with ethylene diamine, PGME-en. The data collected from IGC experiments at infinite dilution are used for the calculation of the thermodynamic parameters of adsorption, dispersive components of the surface free energies, and the acid/base constants. .
AB  - U okviru rada prikazane su mogućnosti korišćenja inverzne gasne hromatografije (IGC) za karakterizaciju polimera. Umreženi makroporozni kopolimer glicidilmetakrilata, GMA, i etilenglikoldimetakrilata, EGDMA, poli (GMA-co-EGDMA) sintetizovan je suspenzionom kopolimerizacijom, a zatim modifikovan reakcijom sa etilendiaminom. Uzorcima polaznog i modifikovanog kopolimera, poli(GMA-co-EGDMA)-en, su pri nultoj prekrivenosti određeni termodinamički parametri adsorpcije, disperzivna komponenta slobodne površinske energije i kiselo/bazna svojstva.
PB  - Association of Chemical Engineers of Serbia
T2  - Hemijska industrija
T1  - Application of inverse gas chromatography for polymer characterization
T1  - Primena inverzne gasne hromatografije za karakterizaciju polimera
VL  - 61
IS  - 6
SP  - 342
EP  - 349
DO  - 10.2298/HEMIND0706342N
ER  - 
@article{
author = "Nastasović, Aleksandra and Onjia, Antonije E. and Milonjić, Slobodan K. and Jovanović, Slobodan M.",
year = "2007",
abstract = "The possibility of polymer characterization by inverse gas chromatography (IGC) was illustrated with the study of sorption properties of macroporous crosslinked poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate), PGME, synthesized by suspension copolymerization, and copolymer modified with ethylene diamine, PGME-en. The data collected from IGC experiments at infinite dilution are used for the calculation of the thermodynamic parameters of adsorption, dispersive components of the surface free energies, and the acid/base constants. ., U okviru rada prikazane su mogućnosti korišćenja inverzne gasne hromatografije (IGC) za karakterizaciju polimera. Umreženi makroporozni kopolimer glicidilmetakrilata, GMA, i etilenglikoldimetakrilata, EGDMA, poli (GMA-co-EGDMA) sintetizovan je suspenzionom kopolimerizacijom, a zatim modifikovan reakcijom sa etilendiaminom. Uzorcima polaznog i modifikovanog kopolimera, poli(GMA-co-EGDMA)-en, su pri nultoj prekrivenosti određeni termodinamički parametri adsorpcije, disperzivna komponenta slobodne površinske energije i kiselo/bazna svojstva.",
publisher = "Association of Chemical Engineers of Serbia",
journal = "Hemijska industrija",
title = "Application of inverse gas chromatography for polymer characterization, Primena inverzne gasne hromatografije za karakterizaciju polimera",
volume = "61",
number = "6",
pages = "342-349",
doi = "10.2298/HEMIND0706342N"
}
Nastasović, A., Onjia, A. E., Milonjić, S. K.,& Jovanović, S. M.. (2007). Application of inverse gas chromatography for polymer characterization. in Hemijska industrija
Association of Chemical Engineers of Serbia., 61(6), 342-349.
https://doi.org/10.2298/HEMIND0706342N
Nastasović A, Onjia AE, Milonjić SK, Jovanović SM. Application of inverse gas chromatography for polymer characterization. in Hemijska industrija. 2007;61(6):342-349.
doi:10.2298/HEMIND0706342N .
Nastasović, Aleksandra, Onjia, Antonije E., Milonjić, Slobodan K., Jovanović, Slobodan M., "Application of inverse gas chromatography for polymer characterization" in Hemijska industrija, 61, no. 6 (2007):342-349,
https://doi.org/10.2298/HEMIND0706342N . .

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