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dc.creatorMilojkov, Dušan
dc.creatorStanić, Vojislav
dc.creatorDimović, Slavko
dc.creatorMutavdžić, Dragosav
dc.creatorŽivković-Radovanović, Vukosava
dc.creatorJanjić, Goran
dc.creatorRadotić, Ksenija
dc.date.accessioned2019-12-18T07:41:53Z
dc.date.available2019-12-18T07:41:53Z
dc.date.issued2019
dc.identifier.issn0587-4246
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/3254
dc.description.abstractIn the present study we have analyzed effects of Ag+ ions doping on energetic profiles of nanophosphors materials based on fluorapatite crystal system. The UV radiation absorption and luminescence properties of monophase fluorapatite (FAP) and Ag+ doped fluorapatite (AgFAP) nanomaterials obtained by neutralization method were investigated using the photoluminescence spectrophotometry. The excitation-emission profiles of nanomaterials were analyzed statistically by MCR-ALS method and number of fluorophores was extracted. FAP lattice absorbed light at 350 nm in the UVA part of spectrum, and with increasing concentration of Ag+ ions new absorption maximum appeared at 270 nm in the UVC part. Fluorescence of FAP nanoparticles was in violet region of visible part of the spectrum, with a red shift to the green region when Ag+ was doped in lattice. MCR-ALS analyses of fluorescence spectra confirm formation of two maxima, at 484 and 505 nm, as a consequence of Ag+ ions doping in FAP lattice at Ca1 (4f) sites. The results of quantum chemical calculations showed that an Ag+ ion is stronger bonded to the binding site 1 (-1352:6 kcal/mol) than to the binding site 2 (-1249:0 kcal/mol). Considering that AgFAP1 nanopowder absorbs photons over all part of UV radiation spectrum, this material might be used as potential radiation protective nanomaterial.en
dc.publisherPolish Academy of Sciences
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43009/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/173017/RS//
dc.rightsopenAccess
dc.sourceActa Physica Polonica A
dc.subjectDFT
dc.subjectFluorescence
dc.subjectSilver doped fluorapatite
dc.subjectUV radiation
dc.titleEffects of Ag+ ion doping on UV radiation absorption and luminescence profiles of fluorapatite nanomaterials obtained by neutralization methoden
dc.typearticle
dc.rights.licenseARR
dcterms.abstractМилојков, Душан; Живковић-Радовановић, Вукосава; Јањић, Горан; Радотић, Ксенија; Димовић, Славко; Станић, Војислав; Мутавджић, Драгосав;
dc.citation.volume136
dc.citation.issue1
dc.citation.spage86
dc.citation.epage91
dc.citation.rankM23~
dc.identifier.doi10.12693/APhysPolA.136.86
dc.identifier.fulltexthttps://cer.ihtm.bg.ac.rs/bitstream/id/15603/Effects_of_Ag+_pub_2019.pdf
dc.identifier.scopus2-s2.0-85074542549
dc.identifier.wos000495444100013
dc.type.versionpublishedVersion


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