Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds
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2020
Authors
Dodevski, Vladimir
Janković, Bojan
Radović, Ivana

Stojmenović, Marija

Čebela, Maria

Nikolić, Željka
Pagnacco, Maja

Panić, Ivan
Stanković, Miroslav

Article (Published version)

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In this work, plane tree seed-based activated carbons were characterized in detail for a variety of applications. The particularly important area of application would be in the artificial photosynthesis. After carbonization process of biomass precursor at 650°C, the resulting preliminary activated carbons were activated at various temperatures. The activated carbons were characterized by oxygen functionalities (a particularly important role has ester oxygen groups) which provide a unique microstructure. The chemical compositions of as-prepared activated carbons were analyzed through Fourier transform infrared and Raman spectra as well as gas chromatography–mass spectroscopy analysis, while morphology was observed by scanning electron microscopy analysis. Applied analysis showed that detected graphite mainly becomes uniformly nanocrystalline system. The current study also explored the applicability of carbon material obtained from plane tree seed as a potential gaseous adsorbent. The ch...aracterization showed that the tested material contains both mesopores and micropores, and this should be advantageous for the gas sorption process, since mesopores may provide low-resistant pathways for the diffusion of CO2 molecules, while the micropores are the most suitable for trapping of CO2. The sorption process analysis (including adsorption/desorption isotherms behavior) shows indication that the rate-limiting step of CO2 adsorption onto activated carbon is probably governed by diffusion-controlled process, especially at temperatures below 850°C.
Keywords:
Plane tree seeds biomass / eco-friendly material / activated carbon / pyrolysis / activation / characterizationsSource:
Energy & Environment, 2020, 31, 4, 583-612Publisher:
- SAGE Publications
Funding / projects:
- Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions (RS-172015)
- Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)
- Functional, Functionalized and Advanced Nanomaterials (RS-45005)
DOI: 10.1177/0958305X19880878
ISSN: 0958-305X; 2048-4070
WoS: 000491749700001
Scopus: 2-s2.0-85074569785
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IHTMTY - JOUR AU - Dodevski, Vladimir AU - Janković, Bojan AU - Radović, Ivana AU - Stojmenović, Marija AU - Čebela, Maria AU - Nikolić, Željka AU - Pagnacco, Maja AU - Panić, Ivan AU - Stanković, Miroslav PY - 2020 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3230 AB - In this work, plane tree seed-based activated carbons were characterized in detail for a variety of applications. The particularly important area of application would be in the artificial photosynthesis. After carbonization process of biomass precursor at 650°C, the resulting preliminary activated carbons were activated at various temperatures. The activated carbons were characterized by oxygen functionalities (a particularly important role has ester oxygen groups) which provide a unique microstructure. The chemical compositions of as-prepared activated carbons were analyzed through Fourier transform infrared and Raman spectra as well as gas chromatography–mass spectroscopy analysis, while morphology was observed by scanning electron microscopy analysis. Applied analysis showed that detected graphite mainly becomes uniformly nanocrystalline system. The current study also explored the applicability of carbon material obtained from plane tree seed as a potential gaseous adsorbent. The characterization showed that the tested material contains both mesopores and micropores, and this should be advantageous for the gas sorption process, since mesopores may provide low-resistant pathways for the diffusion of CO2 molecules, while the micropores are the most suitable for trapping of CO2. The sorption process analysis (including adsorption/desorption isotherms behavior) shows indication that the rate-limiting step of CO2 adsorption onto activated carbon is probably governed by diffusion-controlled process, especially at temperatures below 850°C. PB - SAGE Publications T2 - Energy & Environment T1 - Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds VL - 31 IS - 4 SP - 583 EP - 612 DO - 10.1177/0958305X19880878 ER -
@article{ author = "Dodevski, Vladimir and Janković, Bojan and Radović, Ivana and Stojmenović, Marija and Čebela, Maria and Nikolić, Željka and Pagnacco, Maja and Panić, Ivan and Stanković, Miroslav", year = "2020", abstract = "In this work, plane tree seed-based activated carbons were characterized in detail for a variety of applications. The particularly important area of application would be in the artificial photosynthesis. After carbonization process of biomass precursor at 650°C, the resulting preliminary activated carbons were activated at various temperatures. The activated carbons were characterized by oxygen functionalities (a particularly important role has ester oxygen groups) which provide a unique microstructure. The chemical compositions of as-prepared activated carbons were analyzed through Fourier transform infrared and Raman spectra as well as gas chromatography–mass spectroscopy analysis, while morphology was observed by scanning electron microscopy analysis. Applied analysis showed that detected graphite mainly becomes uniformly nanocrystalline system. The current study also explored the applicability of carbon material obtained from plane tree seed as a potential gaseous adsorbent. The characterization showed that the tested material contains both mesopores and micropores, and this should be advantageous for the gas sorption process, since mesopores may provide low-resistant pathways for the diffusion of CO2 molecules, while the micropores are the most suitable for trapping of CO2. The sorption process analysis (including adsorption/desorption isotherms behavior) shows indication that the rate-limiting step of CO2 adsorption onto activated carbon is probably governed by diffusion-controlled process, especially at temperatures below 850°C.", publisher = "SAGE Publications", journal = "Energy & Environment", title = "Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds", volume = "31", number = "4", pages = "583-612", doi = "10.1177/0958305X19880878" }
Dodevski, V., Janković, B., Radović, I., Stojmenović, M., Čebela, M., Nikolić, Ž., Pagnacco, M., Panić, I.,& Stanković, M.. (2020). Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds. in Energy & Environment SAGE Publications., 31(4), 583-612. https://doi.org/10.1177/0958305X19880878
Dodevski V, Janković B, Radović I, Stojmenović M, Čebela M, Nikolić Ž, Pagnacco M, Panić I, Stanković M. Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds. in Energy & Environment. 2020;31(4):583-612. doi:10.1177/0958305X19880878 .
Dodevski, Vladimir, Janković, Bojan, Radović, Ivana, Stojmenović, Marija, Čebela, Maria, Nikolić, Željka, Pagnacco, Maja, Panić, Ivan, Stanković, Miroslav, "Characterization analysis of activated carbon derived from the carbonization process of plane tree (Platanus orientalis) seeds" in Energy & Environment, 31, no. 4 (2020):583-612, https://doi.org/10.1177/0958305X19880878 . .