Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram
Eksperimentalno ispitivanje i termodinamička analiza Bi-Ni-Pb faznog dijagrama
Autori
Minić, D.Premović, Milena
Tošković, N.
Manasijević, Dragan
Ćosović, Vladan
Janaćković, M.
Tomović, Milica
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The article presents an experimental study of a phase diagram of a ternary Bi-Ni-Pb system using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) analysis. The investigated ternary alloys were selected from three vertical sections (x(Bi)=0.75, x(Ni)=0.1 and x(Pb)=0.9) and two isothermal sections at 100 and at 300°C. The obtained experimental results were compared with the thermodynamically extrapolated phase diagram of the Bi-Ni-Pb ternary system based on the thermodynamic parameters for the constitutive binary systems available in literature. Reasonably close agreement between the experimental data and the calculated phase diagram was obtained.
U ovom radu je predstavljeno eksperimentalno ispitivanje faznog dijagrama Bi-Ni-Pb ternarnog sistema uz pomoć diferencijalne termijske analize (DTA), skenirajućeg elektronskog mikroskopa (SEM) sa energijsko disperzivno spektrometrijom (EDS) i rentgenskom difrakcijom praha (XRD). Ispitivane ternarne legure su izabrane iz tri vertikalna preseka (x(Bi)=0.75, x(Ni)=0.1 i x(Pb)=0.9), i dva izotermalna preseka na 100 i 300°C. Rezultati eksperimenta su upoređeni sa termodinamički ekstrapolisanim faznim dijagramom Bi-Ni-Pb ternarnog sistema na osnovu termodinamičkih parametara sastavnih binarnih sistema koji su dostupni u literaturi. Utvrđeno je dobro slaganje između eksperimentalnih rezultata i proračunatog faznog dijagrama.
Ključne reči:
Bi–Ni-Pb system / Vertical sections x(Bi)=0.75, x(Ni)=0.1 and x(Pb)=0.9 / Isothermal sections at 100 and at 300 °C / Thermal analysis / Thermodynamic prediction / Vertikalni preseci (x(Bi)=0.75, x(Ni)=0.1 i x(Pb)=0.9) / Izoterermalni preseci na 100 i 300°C / Termijska analiza / Termodinamičko predviđanjeIzvor:
Journal of Mining and Metallurgy, Section B: Metallurgy, 2019, 55, 2, 157-166Izdavač:
- Beograd : Univerzitet u Beogradu - Tehnički fakultet u Boru
Finansiranje / projekti:
- Savremeni višekomponentni metalni sistemi i nanostrukturni materijali sa različitim funkcionalnim svojstvima (RS-MESTD-Basic Research (BR or ON)-172037)
- Savremeni višekomponentni metalni sistemi i nanostrukturni materijali sa različitim funkcionalnim svojstvima (RS-MESTD-Basic Research (BR or ON)-172037)
DOI: 10.2298/JMMB181128024M
ISSN: 1450-5339; 2217-7175
WoS: 000473285100003
Scopus: 2-s2.0-85069494972
Institucija/grupa
IHTMTY - JOUR AU - Minić, D. AU - Premović, Milena AU - Tošković, N. AU - Manasijević, Dragan AU - Ćosović, Vladan AU - Janaćković, M. AU - Tomović, Milica PY - 2019 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3210 AB - The article presents an experimental study of a phase diagram of a ternary Bi-Ni-Pb system using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) analysis. The investigated ternary alloys were selected from three vertical sections (x(Bi)=0.75, x(Ni)=0.1 and x(Pb)=0.9) and two isothermal sections at 100 and at 300°C. The obtained experimental results were compared with the thermodynamically extrapolated phase diagram of the Bi-Ni-Pb ternary system based on the thermodynamic parameters for the constitutive binary systems available in literature. Reasonably close agreement between the experimental data and the calculated phase diagram was obtained. AB - U ovom radu je predstavljeno eksperimentalno ispitivanje faznog dijagrama Bi-Ni-Pb ternarnog sistema uz pomoć diferencijalne termijske analize (DTA), skenirajućeg elektronskog mikroskopa (SEM) sa energijsko disperzivno spektrometrijom (EDS) i rentgenskom difrakcijom praha (XRD). Ispitivane ternarne legure su izabrane iz tri vertikalna preseka (x(Bi)=0.75, x(Ni)=0.1 i x(Pb)=0.9), i dva izotermalna preseka na 100 i 300°C. Rezultati eksperimenta su upoređeni sa termodinamički ekstrapolisanim faznim dijagramom Bi-Ni-Pb ternarnog sistema na osnovu termodinamičkih parametara sastavnih binarnih sistema koji su dostupni u literaturi. Utvrđeno je dobro slaganje između eksperimentalnih rezultata i proračunatog faznog dijagrama. PB - Beograd : Univerzitet u Beogradu - Tehnički fakultet u Boru T2 - Journal of Mining and Metallurgy, Section B: Metallurgy T1 - Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram T1 - Eksperimentalno ispitivanje i termodinamička analiza Bi-Ni-Pb faznog dijagrama VL - 55 IS - 2 SP - 157 EP - 166 DO - 10.2298/JMMB181128024M ER -
@article{ author = "Minić, D. and Premović, Milena and Tošković, N. and Manasijević, Dragan and Ćosović, Vladan and Janaćković, M. and Tomović, Milica", year = "2019", abstract = "The article presents an experimental study of a phase diagram of a ternary Bi-Ni-Pb system using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) analysis. The investigated ternary alloys were selected from three vertical sections (x(Bi)=0.75, x(Ni)=0.1 and x(Pb)=0.9) and two isothermal sections at 100 and at 300°C. The obtained experimental results were compared with the thermodynamically extrapolated phase diagram of the Bi-Ni-Pb ternary system based on the thermodynamic parameters for the constitutive binary systems available in literature. Reasonably close agreement between the experimental data and the calculated phase diagram was obtained., U ovom radu je predstavljeno eksperimentalno ispitivanje faznog dijagrama Bi-Ni-Pb ternarnog sistema uz pomoć diferencijalne termijske analize (DTA), skenirajućeg elektronskog mikroskopa (SEM) sa energijsko disperzivno spektrometrijom (EDS) i rentgenskom difrakcijom praha (XRD). Ispitivane ternarne legure su izabrane iz tri vertikalna preseka (x(Bi)=0.75, x(Ni)=0.1 i x(Pb)=0.9), i dva izotermalna preseka na 100 i 300°C. Rezultati eksperimenta su upoređeni sa termodinamički ekstrapolisanim faznim dijagramom Bi-Ni-Pb ternarnog sistema na osnovu termodinamičkih parametara sastavnih binarnih sistema koji su dostupni u literaturi. Utvrđeno je dobro slaganje između eksperimentalnih rezultata i proračunatog faznog dijagrama.", publisher = "Beograd : Univerzitet u Beogradu - Tehnički fakultet u Boru", journal = "Journal of Mining and Metallurgy, Section B: Metallurgy", title = "Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram, Eksperimentalno ispitivanje i termodinamička analiza Bi-Ni-Pb faznog dijagrama", volume = "55", number = "2", pages = "157-166", doi = "10.2298/JMMB181128024M" }
Minić, D., Premović, M., Tošković, N., Manasijević, D., Ćosović, V., Janaćković, M.,& Tomović, M.. (2019). Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram. in Journal of Mining and Metallurgy, Section B: Metallurgy Beograd : Univerzitet u Beogradu - Tehnički fakultet u Boru., 55(2), 157-166. https://doi.org/10.2298/JMMB181128024M
Minić D, Premović M, Tošković N, Manasijević D, Ćosović V, Janaćković M, Tomović M. Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram. in Journal of Mining and Metallurgy, Section B: Metallurgy. 2019;55(2):157-166. doi:10.2298/JMMB181128024M .
Minić, D., Premović, Milena, Tošković, N., Manasijević, Dragan, Ćosović, Vladan, Janaćković, M., Tomović, Milica, "Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram" in Journal of Mining and Metallurgy, Section B: Metallurgy, 55, no. 2 (2019):157-166, https://doi.org/10.2298/JMMB181128024M . .