Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram
Eksperimentalno ispitivanje i termodinamička analiza Bi-Ni-Pb faznog dijagrama
Authors
Minić, D.Premović, Milena

Tošković, N.
Manasijević, Dragan

Ćosović, Vladan

Janaćković, M.
Tomović, Milica

Article (Published version)
Metadata
Show full item recordAbstract
The article presents an experimental study of a phase diagram of a ternary Bi-Ni-Pb system using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) analysis. The investigated ternary alloys were selected from three vertical sections (x(Bi)=0.75, x(Ni)=0.1 and x(Pb)=0.9) and two isothermal sections at 100 and at 300°C. The obtained experimental results were compared with the thermodynamically extrapolated phase diagram of the Bi-Ni-Pb ternary system based on the thermodynamic parameters for the constitutive binary systems available in literature. Reasonably close agreement between the experimental data and the calculated phase diagram was obtained.
U ovom radu je predstavljeno eksperimentalno ispitivanje faznog dijagrama Bi-Ni-Pb ternarnog sistema uz pomoć diferencijalne termijske analize (DTA), skenirajućeg elektronskog mikroskopa (SEM) sa energijsko disperzivno spektrometrijom (EDS) i rentgenskom difrakcijom praha (XRD). Ispitivane ternarne legure su izabrane iz tri vertikalna preseka (x(Bi)=0.75, x(Ni)=0.1 i x(Pb)=0.9), i dva izotermalna preseka na 100 i 300°C. Rezultati eksperimenta su upoređeni sa termodinamički ekstrapolisanim faznim dijagramom Bi-Ni-Pb ternarnog sistema na osnovu termodinamičkih parametara sastavnih binarnih sistema koji su dostupni u literaturi. Utvrđeno je dobro slaganje između eksperimentalnih rezultata i proračunatog faznog dijagrama.
Keywords:
Bi–Ni-Pb system / Vertical sections x(Bi)=0.75, x(Ni)=0.1 and x(Pb)=0.9 / Isothermal sections at 100 and at 300 °C / Thermal analysis / Thermodynamic prediction / Vertikalni preseci (x(Bi)=0.75, x(Ni)=0.1 i x(Pb)=0.9) / Izoterermalni preseci na 100 i 300°C / Termijska analiza / Termodinamičko predviđanjeSource:
Journal of Mining and Metallurgy, Section B: Metallurgy, 2019, 55, 2, 157-166Publisher:
- Beograd : Univerzitet u Beogradu - Tehnički fakultet u Boru
Funding / projects:
- Advanced multicomponent metal systems and nanostructured materials with diverse functional properties (RS-172037)
- Advanced multicomponent metal systems and nanostructured materials with diverse functional properties (RS-172037)
DOI: 10.2298/JMMB181128024M
ISSN: 1450-5339; 2217-7175
WoS: 000473285100003
Scopus: 2-s2.0-85069494972
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Institution/Community
IHTMTY - JOUR AU - Minić, D. AU - Premović, Milena AU - Tošković, N. AU - Manasijević, Dragan AU - Ćosović, Vladan AU - Janaćković, M. AU - Tomović, Milica PY - 2019 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3210 AB - The article presents an experimental study of a phase diagram of a ternary Bi-Ni-Pb system using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) analysis. The investigated ternary alloys were selected from three vertical sections (x(Bi)=0.75, x(Ni)=0.1 and x(Pb)=0.9) and two isothermal sections at 100 and at 300°C. The obtained experimental results were compared with the thermodynamically extrapolated phase diagram of the Bi-Ni-Pb ternary system based on the thermodynamic parameters for the constitutive binary systems available in literature. Reasonably close agreement between the experimental data and the calculated phase diagram was obtained. AB - U ovom radu je predstavljeno eksperimentalno ispitivanje faznog dijagrama Bi-Ni-Pb ternarnog sistema uz pomoć diferencijalne termijske analize (DTA), skenirajućeg elektronskog mikroskopa (SEM) sa energijsko disperzivno spektrometrijom (EDS) i rentgenskom difrakcijom praha (XRD). Ispitivane ternarne legure su izabrane iz tri vertikalna preseka (x(Bi)=0.75, x(Ni)=0.1 i x(Pb)=0.9), i dva izotermalna preseka na 100 i 300°C. Rezultati eksperimenta su upoređeni sa termodinamički ekstrapolisanim faznim dijagramom Bi-Ni-Pb ternarnog sistema na osnovu termodinamičkih parametara sastavnih binarnih sistema koji su dostupni u literaturi. Utvrđeno je dobro slaganje između eksperimentalnih rezultata i proračunatog faznog dijagrama. PB - Beograd : Univerzitet u Beogradu - Tehnički fakultet u Boru T2 - Journal of Mining and Metallurgy, Section B: Metallurgy T1 - Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram T1 - Eksperimentalno ispitivanje i termodinamička analiza Bi-Ni-Pb faznog dijagrama VL - 55 IS - 2 SP - 157 EP - 166 DO - 10.2298/JMMB181128024M ER -
@article{ author = "Minić, D. and Premović, Milena and Tošković, N. and Manasijević, Dragan and Ćosović, Vladan and Janaćković, M. and Tomović, Milica", year = "2019", abstract = "The article presents an experimental study of a phase diagram of a ternary Bi-Ni-Pb system using differential thermal analysis (DTA), scanning electron microscopy (SEM) with energy dispersive spectrometry (EDS), and X-ray powder diffraction (XRD) analysis. The investigated ternary alloys were selected from three vertical sections (x(Bi)=0.75, x(Ni)=0.1 and x(Pb)=0.9) and two isothermal sections at 100 and at 300°C. The obtained experimental results were compared with the thermodynamically extrapolated phase diagram of the Bi-Ni-Pb ternary system based on the thermodynamic parameters for the constitutive binary systems available in literature. Reasonably close agreement between the experimental data and the calculated phase diagram was obtained., U ovom radu je predstavljeno eksperimentalno ispitivanje faznog dijagrama Bi-Ni-Pb ternarnog sistema uz pomoć diferencijalne termijske analize (DTA), skenirajućeg elektronskog mikroskopa (SEM) sa energijsko disperzivno spektrometrijom (EDS) i rentgenskom difrakcijom praha (XRD). Ispitivane ternarne legure su izabrane iz tri vertikalna preseka (x(Bi)=0.75, x(Ni)=0.1 i x(Pb)=0.9), i dva izotermalna preseka na 100 i 300°C. Rezultati eksperimenta su upoređeni sa termodinamički ekstrapolisanim faznim dijagramom Bi-Ni-Pb ternarnog sistema na osnovu termodinamičkih parametara sastavnih binarnih sistema koji su dostupni u literaturi. Utvrđeno je dobro slaganje između eksperimentalnih rezultata i proračunatog faznog dijagrama.", publisher = "Beograd : Univerzitet u Beogradu - Tehnički fakultet u Boru", journal = "Journal of Mining and Metallurgy, Section B: Metallurgy", title = "Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram, Eksperimentalno ispitivanje i termodinamička analiza Bi-Ni-Pb faznog dijagrama", volume = "55", number = "2", pages = "157-166", doi = "10.2298/JMMB181128024M" }
Minić, D., Premović, M., Tošković, N., Manasijević, D., Ćosović, V., Janaćković, M.,& Tomović, M.. (2019). Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram. in Journal of Mining and Metallurgy, Section B: Metallurgy Beograd : Univerzitet u Beogradu - Tehnički fakultet u Boru., 55(2), 157-166. https://doi.org/10.2298/JMMB181128024M
Minić D, Premović M, Tošković N, Manasijević D, Ćosović V, Janaćković M, Tomović M. Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram. in Journal of Mining and Metallurgy, Section B: Metallurgy. 2019;55(2):157-166. doi:10.2298/JMMB181128024M .
Minić, D., Premović, Milena, Tošković, N., Manasijević, Dragan, Ćosović, Vladan, Janaćković, M., Tomović, Milica, "Experimental investigation and thermodynamic calculations of the Bi-Ni-Pb phase diagram" in Journal of Mining and Metallurgy, Section B: Metallurgy, 55, no. 2 (2019):157-166, https://doi.org/10.2298/JMMB181128024M . .