Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment

Stojmenović, Marija; Milenković, Maja C.; Banković, Predrag; Žunić, Milan; Gulicovski, Jelena; Pantic, Jelena R; Boskovic, Snezana B

doi:10.1016/j.dyepig.2015.07.030

2015

10.1016.j.dyepig.2015.07.030.pdf (5.107Mb)

Authors

Žunić, Milan

Pantic, Jelena R
Boskovic, Snezana B

Article (Accepted Version)

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Abstract

Ceramic pigments based on cerium oxide were synthesized by self-propagating room temperature method and their color properties were assessed from the viewpoint of potential environmentally nontoxic pink pigments. Thermal stabilities of the pigments were examined at 600, 900 and 1200 degrees C. According to X-ray powder diffraction and Raman spectroscopy results, all obtained pigments were singlephase solid solutions of cerium oxide, independent of the concentration of dopants. The X-ray analysis showed that the crystallites were of nanometric dimensions, as recorded and by transmission electron microscopy analysis. Color characteristics of solid solutions, which depended on concentration erbium ions and calcination temperature, and their position in the chromaticity diagram were studied by ultraviolet visible spectrophotometry, which confirmed potential application of environmentally friendly pigments of desired color. The color efficiency of pigments was also evaluated by calorimetric...

Keywords:

Rare earth pigments / Non-toxic pigments / Optical properties / Band gap / Colorimetric / Solid solution

Source:
Dyes and Pigments, 2015, 123, 116-124

Publisher:

Elsevier Sci Ltd, Oxford

Projects:

Note:

This is peer-reviewed version of the artcle: M. Stojmenović, M.C. Milenković, P.T. Banković, M. Žunić, J.J. Gulicovski, J.R. Pantić, S.B. Bošković, Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1−xErxO2−δ (x = 0.05–0.20) as a pigment, Dye. Pigment. 123 (2015) 116–124 https://doi.org/10.1016/j.dyepig.2015.07.030
Published version: http://cer.ihtm.bg.ac.rs/handle/123456789/1694

DOI: 10.1016/j.dyepig.2015.07.030

ISSN: 0143-7208

WoS: 000367768300016

Scopus: 2-s2.0-84939153089

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TY  - JOUR
AU  - Stojmenović, Marija
AU  - Milenković, Maja C.
AU  - Banković, Predrag
AU  - Žunić, Milan
AU  - Gulicovski, Jelena
AU  - Pantic, Jelena R
AU  - Boskovic, Snezana B
PY  - 2015
UR  - http://cer.ihtm.bg.ac.rs/handle/123456789/3174
AB  - Ceramic pigments based on cerium oxide were synthesized by self-propagating room temperature method and their color properties were assessed from the viewpoint of potential environmentally nontoxic pink pigments. Thermal stabilities of the pigments were examined at 600, 900 and 1200 degrees C. According to X-ray powder diffraction and Raman spectroscopy results, all obtained pigments were singlephase solid solutions of cerium oxide, independent of the concentration of dopants. The X-ray analysis showed that the crystallites were of nanometric dimensions, as recorded and by transmission electron microscopy analysis. Color characteristics of solid solutions, which depended on concentration erbium ions and calcination temperature, and their position in the chromaticity diagram were studied by ultraviolet visible spectrophotometry, which confirmed potential application of environmentally friendly pigments of desired color. The color efficiency of pigments was also evaluated by calorimetric analysis.
PB  - Elsevier Sci Ltd, Oxford
T2  - Dyes and Pigments
T1  - Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment
VL  - 123
SP  - 116
EP  - 124
DO  - 10.1016/j.dyepig.2015.07.030
ER  -

@article{
author = "Stojmenović, Marija and Milenković, Maja C. and Banković, Predrag and Žunić, Milan and Gulicovski, Jelena and Pantic, Jelena R and Boskovic, Snezana B",
year = "2015",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/3174",
abstract = "Ceramic pigments based on cerium oxide were synthesized by self-propagating room temperature method and their color properties were assessed from the viewpoint of potential environmentally nontoxic pink pigments. Thermal stabilities of the pigments were examined at 600, 900 and 1200 degrees C. According to X-ray powder diffraction and Raman spectroscopy results, all obtained pigments were singlephase solid solutions of cerium oxide, independent of the concentration of dopants. The X-ray analysis showed that the crystallites were of nanometric dimensions, as recorded and by transmission electron microscopy analysis. Color characteristics of solid solutions, which depended on concentration erbium ions and calcination temperature, and their position in the chromaticity diagram were studied by ultraviolet visible spectrophotometry, which confirmed potential application of environmentally friendly pigments of desired color. The color efficiency of pigments was also evaluated by calorimetric analysis.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Dyes and Pigments",
title = "Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment",
volume = "123",
pages = "116-124",
doi = "10.1016/j.dyepig.2015.07.030"
}

Stojmenović M, Milenković MC, Banković P, Žunić M, Gulicovski J, Pantic JR, Boskovic SB. Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment. Dyes and Pigments. 2015;123:116-124

Stojmenović, M., Milenković, M. C., Banković, P., Žunić, M., Gulicovski, J., Pantic, J. R.,& Boskovic, S. B. (2015). Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment.
Dyes and PigmentsElsevier Sci Ltd, Oxford., 123, 116-124.
https://doi.org/10.1016/j.dyepig.2015.07.030

Stojmenović Marija, Milenković Maja C., Banković Predrag, Žunić Milan, Gulicovski Jelena, Pantic Jelena R, Boskovic Snezana B, "Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment" 123 (2015):116-124,
https://doi.org/10.1016/j.dyepig.2015.07.030 .