Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers

Dordevic, Milena; Jeremić, Dejan; Kaluđerović, Goran N.; Gómez-Ruiz, Santiago; Anđelković, Boban D.; Radanović, Dušanka; Brčeski, Ilija

doi:10.1016/j.poly.2014.05.056

2014

j.poly.2014.05.056.pdf (2.899Mb)

Authors

Dordevic, Milena
Jeremić, Dejan

Kaluđerović, Goran N.

Gómez-Ruiz, Santiago

Anđelković, Boban D.

Radanović, Dušanka

Brčeski, Ilija

Article (Accepted Version)

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Abstract

Three new 1D coordination polymers, [Pb-2(CH3SO3)(4)(H2O)(2)](n), [Hg(CH3SO3)(2)(H2O)(2)](n) and [Sr(CH3SO3)(2)(H2O)](n), were synthesized as large single crystals. The crystals were analyzed and characterized by the means of X-ray analysis, IR and NMR spectroscopy, elemental analysis and solid state UV-Vis spectroscopy. The formation of 1D polymeric chains in the crystal structures of the title compounds is affected by the various bonding modes of the bridging methanesulfonate groups. The studied compounds showed no decomposition in the air.

Keywords:

Lead(II) / Mercury(II) / Strontium(II) / Methanesulfonates / Spectroscopy

Source:
Polyhedron, 2014, 80, 282-289

Publisher:

Pergamon-Elsevier Science Ltd, Oxford

Projects:

Mechanistic studies of the reactions of transition metal ion complexes with biologically relevant molecules (RS-172011)

Note:

This is the peer-reviewed version of the article: M. Đorđević, D. Jeremić, G.N. Kaluđerović, S. Gómez-Ruiz, B. Anđelković, D. Radanović, I. Brčeski, Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers, Polyhedron (2014), doi: http://dx.doi.org/10.1016/j.poly.2014.05.056
http://cer.ihtm.bg.ac.rs/handle/123456789/1429

DOI: 10.1016/j.poly.2014.05.056

ISSN: 0277-5387

WoS: 000341348300037

Scopus: 2-s2.0-84905435373

[ Google Scholar ]


	1
	1

TY  - JOUR
AU  - Dordevic, Milena
AU  - Jeremić, Dejan
AU  - Kaluđerović, Goran N.
AU  - Gómez-Ruiz, Santiago
AU  - Anđelković, Boban D.
AU  - Radanović, Dušanka
AU  - Brčeski, Ilija
PY  - 2014
UR  - http://cer.ihtm.bg.ac.rs/handle/123456789/3164
AB  - Three new 1D coordination polymers, [Pb-2(CH3SO3)(4)(H2O)(2)](n), [Hg(CH3SO3)(2)(H2O)(2)](n) and [Sr(CH3SO3)(2)(H2O)](n), were synthesized as large single crystals. The crystals were analyzed and characterized by the means of X-ray analysis, IR and NMR spectroscopy, elemental analysis and solid state UV-Vis spectroscopy. The formation of 1D polymeric chains in the crystal structures of the title compounds is affected by the various bonding modes of the bridging methanesulfonate groups. The studied compounds showed no decomposition in the air.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers
VL  - 80
SP  - 282
EP  - 289
DO  - 10.1016/j.poly.2014.05.056
ER  -

@article{
author = "Dordevic, Milena and Jeremić, Dejan and Kaluđerović, Goran N. and Gómez-Ruiz, Santiago and Anđelković, Boban D. and Radanović, Dušanka and Brčeski, Ilija",
year = "2014",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/3164",
abstract = "Three new 1D coordination polymers, [Pb-2(CH3SO3)(4)(H2O)(2)](n), [Hg(CH3SO3)(2)(H2O)(2)](n) and [Sr(CH3SO3)(2)(H2O)](n), were synthesized as large single crystals. The crystals were analyzed and characterized by the means of X-ray analysis, IR and NMR spectroscopy, elemental analysis and solid state UV-Vis spectroscopy. The formation of 1D polymeric chains in the crystal structures of the title compounds is affected by the various bonding modes of the bridging methanesulfonate groups. The studied compounds showed no decomposition in the air.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers",
volume = "80",
pages = "282-289",
doi = "10.1016/j.poly.2014.05.056"
}

Dordevic, M., Jeremić, D., Kaluđerović, G. N., Gómez-Ruiz, S., Anđelković, B. D., Radanović, D.,& Brčeski, I. (2014). Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers.
Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 80, 282-289.
https://doi.org/10.1016/j.poly.2014.05.056

Dordevic M, Jeremić D, Kaluđerović GN, Gómez-Ruiz S, Anđelković BD, Radanović D, Brčeski I. Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers. Polyhedron. 2014;80:282-289

Dordevic Milena, Jeremić Dejan, Kaluđerović Goran N., Gómez-Ruiz Santiago, Anđelković Boban D., Radanović Dušanka, Brčeski Ilija, "Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers" Polyhedron, 80 (2014):282-289,
https://doi.org/10.1016/j.poly.2014.05.056 .