Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers

Dordevic, Milena; Jeremić, Dejan; Kaluđerović, Goran N.; Gómez-Ruiz, Santiago; Anđelković, Boban D.; Radanović, Dušanka; Brčeski, Ilija

doi:10.1016/j.poly.2014.05.056

2014

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Authors

Dordevic, Milena
Jeremić, Dejan

Kaluđerović, Goran N.

Gómez-Ruiz, Santiago

Anđelković, Boban D.

Radanović, Dušanka

Brčeski, Ilija

Article (Accepted Version)

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Abstract

Three new 1D coordination polymers, [Pb-2(CH3SO3)(4)(H2O)(2)](n), [Hg(CH3SO3)(2)(H2O)(2)](n) and [Sr(CH3SO3)(2)(H2O)](n), were synthesized as large single crystals. The crystals were analyzed and characterized by the means of X-ray analysis, IR and NMR spectroscopy, elemental analysis and solid state UV-Vis spectroscopy. The formation of 1D polymeric chains in the crystal structures of the title compounds is affected by the various bonding modes of the bridging methanesulfonate groups. The studied compounds showed no decomposition in the air.

Keywords:

Lead(II) / Mercury(II) / Strontium(II) / Methanesulfonates / Spectroscopy

Source:
Polyhedron, 2014, 80, 282-289

Publisher:

Pergamon-Elsevier Science Ltd, Oxford

Projects:

Mechanistic studies of the reactions of transition metal ion complexes with biologically relevant molecules (RS-172011)

Note:

This is the peer-reviewed version of the article: M. Đorđević, D. Jeremić, G.N. Kaluđerović, S. Gómez-Ruiz, B. Anđelković, D. Radanović, I. Brčeski, Synthesis and spectroscopic properties of large single-crystals of Pb(II), Hg(II) and Sr(II) methanesulfonato 1D coordination polymers, Polyhedron (2014), doi: http://dx.doi.org/10.1016/j.poly.2014.05.056
http://cer.ihtm.bg.ac.rs/handle/123456789/1429