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Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction

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2018
zdolsek2017.pdf (1.715Mb)
Authors
Zdolsek, Nikola
Dimitrijević, Aleksandra
Bendova, Magdalena
Krstić, Jugoslav
Rocha, Raquel P.
Figueiredo, Jose L.
Bajuk-Bogdanovic, Danica
Trtic-Petrovic, Tatjana
Šljukić, Biljana
Article (Accepted Version)
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Abstract
Carbon materials, prepared by using different methods with ionic liquids, are compared as electrocatalysts for the oxygen reduction reaction (ORR). Materials were synthesized through the hydrothermal carbonization of glucose and by using the same method in the presence of 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3] as an additive. Another two carbon-based materials were prepared by using ionic-liquid-based methods: ionothermal carbonization of glucose using [bmim][MeSO3] as a recyclable medium for the carbonization reaction and by direct carbonization of the ionic liquid in a one-step method using [bmim][MeSO3] as the precursor for N- and S-doped porous carbon (Carb-IL). Characterization results showed the possibility of morphology and porosity control by using [bmim][MeSO3]. All materials were subsequently tested for the ORR in alkaline media. Carb-IL showed enhanced and stable electrocatalytic ORR activity, even in the presence of methanol, ethanol, and borohydride, op...ening the possibility for its application in fuel cells.

Keywords:
ionic liquids / porous carbon materials / ionothermal carbonization / oxygen reduction reaction / fuel cells
Source:
Chemelectrochem, 2018, 5, 7, 1037-1046
Publisher:
  • Wiley-V C H Verlag Gmbh, Weinheim
Funding / projects:
  • Physics and Chemistry with Ion Beams (RS-45006)
  • Lithium-ion batteries and fuel cells - research and development (RS-45014)
  • Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes (RS-45001)
  • ERDF through COMPETE - Programa Operacional Competitividade e Internacionalizacao (POCI) - POCI-01-0145-FEDER-006984
  • FCT - Fundacao para a Ciencia e a Tecnologia
  • FCT - SFRH/BD/95411/2013
  • Ministry of Education, Sports, and Youth of the Czech Republic - COST LD14090
  • COST Action - CM1206
Note:
  • This the peer-reviewed vr+ersion of the article: https://doi.org/10.1002/celc.201701369
  • http://cer.ihtm.bg.ac.rs/handle/123456789/2337

DOI: 10.1002/celc.201701369

ISSN: 2196-0216

WoS: 000429413700007

Scopus: 2-s2.0-85041637185
[ Google Scholar ]
22
16
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/3138
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Zdolsek, Nikola
AU  - Dimitrijević, Aleksandra
AU  - Bendova, Magdalena
AU  - Krstić, Jugoslav
AU  - Rocha, Raquel P.
AU  - Figueiredo, Jose L.
AU  - Bajuk-Bogdanovic, Danica
AU  - Trtic-Petrovic, Tatjana
AU  - Šljukić, Biljana
PY  - 2018
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/3138
AB  - Carbon materials, prepared by using different methods with ionic liquids, are compared as electrocatalysts for the oxygen reduction reaction (ORR). Materials were synthesized through the hydrothermal carbonization of glucose and by using the same method in the presence of 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3] as an additive. Another two carbon-based materials were prepared by using ionic-liquid-based methods: ionothermal carbonization of glucose using [bmim][MeSO3] as a recyclable medium for the carbonization reaction and by direct carbonization of the ionic liquid in a one-step method using [bmim][MeSO3] as the precursor for N- and S-doped porous carbon (Carb-IL). Characterization results showed the possibility of morphology and porosity control by using [bmim][MeSO3]. All materials were subsequently tested for the ORR in alkaline media. Carb-IL showed enhanced and stable electrocatalytic ORR activity, even in the presence of methanol, ethanol, and borohydride, opening the possibility for its application in fuel cells.
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - Chemelectrochem
T1  - Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction
VL  - 5
IS  - 7
SP  - 1037
EP  - 1046
DO  - 10.1002/celc.201701369
ER  - 
@article{
author = "Zdolsek, Nikola and Dimitrijević, Aleksandra and Bendova, Magdalena and Krstić, Jugoslav and Rocha, Raquel P. and Figueiredo, Jose L. and Bajuk-Bogdanovic, Danica and Trtic-Petrovic, Tatjana and Šljukić, Biljana",
year = "2018",
abstract = "Carbon materials, prepared by using different methods with ionic liquids, are compared as electrocatalysts for the oxygen reduction reaction (ORR). Materials were synthesized through the hydrothermal carbonization of glucose and by using the same method in the presence of 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3] as an additive. Another two carbon-based materials were prepared by using ionic-liquid-based methods: ionothermal carbonization of glucose using [bmim][MeSO3] as a recyclable medium for the carbonization reaction and by direct carbonization of the ionic liquid in a one-step method using [bmim][MeSO3] as the precursor for N- and S-doped porous carbon (Carb-IL). Characterization results showed the possibility of morphology and porosity control by using [bmim][MeSO3]. All materials were subsequently tested for the ORR in alkaline media. Carb-IL showed enhanced and stable electrocatalytic ORR activity, even in the presence of methanol, ethanol, and borohydride, opening the possibility for its application in fuel cells.",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "Chemelectrochem",
title = "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction",
volume = "5",
number = "7",
pages = "1037-1046",
doi = "10.1002/celc.201701369"
}
Zdolsek, N., Dimitrijević, A., Bendova, M., Krstić, J., Rocha, R. P., Figueiredo, J. L., Bajuk-Bogdanovic, D., Trtic-Petrovic, T.,& Šljukić, B.. (2018). Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in Chemelectrochem
Wiley-V C H Verlag Gmbh, Weinheim., 5(7), 1037-1046.
https://doi.org/10.1002/celc.201701369
Zdolsek N, Dimitrijević A, Bendova M, Krstić J, Rocha RP, Figueiredo JL, Bajuk-Bogdanovic D, Trtic-Petrovic T, Šljukić B. Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in Chemelectrochem. 2018;5(7):1037-1046.
doi:10.1002/celc.201701369 .
Zdolsek, Nikola, Dimitrijević, Aleksandra, Bendova, Magdalena, Krstić, Jugoslav, Rocha, Raquel P., Figueiredo, Jose L., Bajuk-Bogdanovic, Danica, Trtic-Petrovic, Tatjana, Šljukić, Biljana, "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction" in Chemelectrochem, 5, no. 7 (2018):1037-1046,
https://doi.org/10.1002/celc.201701369 . .

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