Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent

Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .

Keywords:

Zn(II) complexes / hydrazones / crystal structure / antimicrobial activity / pseudohalides

Source:
Journal of Coordination Chemistry, 2017, 70, 14, 2425-2435

Publisher:

Taylor & Francis Ltd, Abingdon

Projects:

Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-172055)
Slovenian Research Agency [P1-0175]

Note:

This is the peer-reviewed version of the article: https://doi.org/10.1080/00958972.2017.1343945
http://cer.ihtm.bg.ac.rs/handle/123456789/2139

DOI: 10.1080/00958972.2017.1343945

ISSN: 0095-8972

WoS: 000406491100006

Scopus: 2-s2.0-85021292283

[ Google Scholar ]


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	8

TY  - JOUR
AU  - Romanović, Mima
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Anđelković, Katarina
AU  - Milenković, Marina
AU  - Radanović, Dušanka
AU  - Belosevic, Svetlana
AU  - Milenković, Milica R.
PY  - 2017
UR  - http://cer.ihtm.bg.ac.rs/handle/123456789/3069
AB  - Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
VL  - 70
IS  - 14
SP  - 2425
EP  - 2435
DO  - 10.1080/00958972.2017.1343945
ER  -

@article{
author = "Romanović, Mima and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Anđelković, Katarina and Milenković, Marina and Radanović, Dušanka and Belosevic, Svetlana and Milenković, Milica R.",
year = "2017",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/3069",
abstract = "Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent",
volume = "70",
number = "14",
pages = "2425-2435",
doi = "10.1080/00958972.2017.1343945"
}

Romanović M, Čobeljić B, Pevec A, Turel I, Anđelković K, Milenković M, Radanović D, Belosevic S, Milenković MR. Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. Journal of Coordination Chemistry. 2017;70(14):2425-2435

Romanović, M., Čobeljić, B., Pevec, A., Turel, I., Anđelković, K., Milenković, M., Radanović, D., Belosevic, S.,& Milenković, M. R. (2017). Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent.
Journal of Coordination ChemistryTaylor & Francis Ltd, Abingdon., 70(14), 2425-2435.
https://doi.org/10.1080/00958972.2017.1343945

Romanović Mima, Čobeljić Božidar, Pevec Andrej, Turel Iztok, Anđelković Katarina, Milenković Marina, Radanović Dušanka, Belosevic Svetlana, Milenković Milica R., "Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent" 70, no. 14 (2017):2425-2435,
https://doi.org/10.1080/00958972.2017.1343945 .