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Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent

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2017
10.1080@00958972.2017.1343945.pdf (1.170Mb)
Authors
Romanović, Mima
Čobeljić, Božidar
Pevec, Andrej
Turel, Iztok
Anđelković, Katarina
Milenković, Marina
Radanović, Dušanka
Belosevic, Svetlana
Milenković, Milica R.
Article (Accepted Version)
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Abstract
Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .
Keywords:
Zn(II) complexes / hydrazones / crystal structure / antimicrobial activity / pseudohalides
Source:
Journal of Coordination Chemistry, 2017, 70, 14, 2425-2435
Publisher:
  • Taylor & Francis Ltd, Abingdon
Projects:
  • Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-172055)
  • Slovenian Research Agency [P1-0175]
Note:
  • This is the peer-reviewed version of the article: https://doi.org/10.1080/00958972.2017.1343945
  • http://cer.ihtm.bg.ac.rs/handle/123456789/2139

DOI: 10.1080/00958972.2017.1343945

ISSN: 0095-8972

WoS: 000406491100006

Scopus: 2-s2.0-85021292283
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/3069
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