Synthesis, crystal structures and antimicrobial activity of azido and isocyanato Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
Authors
Romanović, Mima
Čobeljić, Božidar

Pevec, Andrej

Turel, Iztok

Anđelković, Katarina

Milenković, Marina

Radanović, Dušanka

Belosevic, Svetlana
Milenković, Milica R.

Article (Accepted Version)

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Show full item recordAbstract
Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .
Keywords:
Zn(II) complexes / hydrazones / crystal structure / antimicrobial activity / pseudohalidesSource:
Journal of Coordination Chemistry, 2017, 70, 14, 2425-2435Publisher:
- Taylor & Francis Ltd, Abingdon
Projects:
- Interactions of natural products, their derivatives and coordination compounds with proteins and nucleic acids (RS-172055)
- Slovenian Research Agency [P1-0175]
Note:
- This is the peer-reviewed version of the article: https://doi.org/10.1080/00958972.2017.1343945
- http://cer.ihtm.bg.ac.rs/handle/123456789/2139
DOI: 10.1080/00958972.2017.1343945
ISSN: 0095-8972