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dc.creatorČupić, Željko
dc.creatorIvanović-Šašić, Ana
dc.date.accessioned2019-07-10T09:48:08Z
dc.date.available2019-07-10T09:48:08Z
dc.date.issued2019
dc.identifier.issn1878-5190
dc.identifier.issn1878-5204
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/3024
dc.description.abstractThe application of alternating current is advantageous in energy transfer over long distances. It is a well-known fact now, but subject of long conflict in the era of pioneering works in electric power production. There are also some processes in physical chemistry, organic and inorganic chemistry, in biochemistry and related sciences, which take place in opposite directions, with consecutive alternations in time. However, the very existence of alternate reactions, now known as the oscillatory or oscillating reactions, has long been disputed because it was thought that it is contrary to the basic principles of thermodynamics. Nevertheless, according to our knowledge, there are no oscillatory reactions without catalytic loop as the essential part of a mechanism. There could be a fundamental rule that catalysis is necessary to generate oscillations in concentrations and reaction rates. Particularly, homogeneous oscillatory reactions are often subject of research as relatively simple systems with good chance to clearly define feedbacks responsible for instability phenomena. However, oscillations can at least equally often be found in heterogeneous catalytic reactions. Recently, changes in product selectivity was proved when Pd catalyzed carbonylation of phenylacetylene was moved to the oscillatory dynamic state. With this simple result, the doors are now open for wide spectrum of research projects and applications.sr
dc.language.isoensr
dc.publisherSpringersr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172015/RS//sr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45001/RS//sr
dc.rightsrestrictedAccesssr
dc.sourceReaction Kinetics, Mechanisms and Catalysissr
dc.subjectOscillatory reactionsr
dc.subjectCarbon monoxide oxidationsr
dc.subjectPhenylacetylene carbonilationsr
dc.titleAlternating catalytic reactionssr
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractЧупић, Жељко; Ивановић-Шашић, Aна;
dc.rights.holderSpringersr
dc.citation.volume126
dc.citation.issue2
dc.citation.spage577
dc.citation.epage586
dc.citation.rankM23~
dc.identifier.doi10.1007/s11144-018-1501-2
dc.identifier.scopus2-s2.0-85057099538
dc.identifier.wos000463627000002
dc.type.versionpublishedVersionsr


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