Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption
Authors
Marković, Bojana
Vuković, Zorica

Spasojević, Vojislav

Kusigerski, Vladan B.

Pavlović, Vladimir B.

Onjia, Antonije E.

Nastasović, Aleksandra

Article (Accepted Version)
Metadata
Show full item recordAbstract
Magnetic macroporous crosslinked copolymer glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) samples with different magnetite content were prepared by suspension copolymerization and functionalized with diethylene triamine. Samples were characterized by elemental analysis, mercury porosimetry, Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, transmission electron microscopy, SQUID magnetometry and X-ray photoelectron spectroscopy (XPS). The selected amino-functionalized sample was tested as a potential sorbent for the Mo(VI) and Re(VII) oxyanions from aqueous solutions. The influence of pH, ionic strength and possible interfering of cations and anions was investigated. Equilibrium data were analyzed with Langmuir, Freundlich and Tempkin adsorption isotherm models. Sorption studies were carried out in a batch competitive experiments, in the pH range 1-8, at 298 K. Obtained results indica...te that 92% of Re(VII) and 98% of Mo(VI) were sorbed at pH 2.
Keywords:
Magnetic macroporous copolymer / Diethylene triamine / Mo(VI) and Re(VII) sorptionSource:
Journal of Alloys and Compounds, 2017, 705, 38-50Publisher:
- Elsevier
Funding / projects:
- Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-43009)
- Magnetic and radionuclide labeled nanostructured materials for medical applications (RS-45015)
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-172062)
- Directed synthesis, structure and properties of multifunctional materials (RS-172057)
Note:
- This is peer-reviewed version of the article: B.M. Marković, Z.M. Vuković, V.V. Spasojević, V.B. Kusigerski, V.B. Pavlović, A.E. Onjia, A.B. Nastasović, Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption, Journal of Alloys and Compounds, 2017, 705, 38-50, https://dx.doi.org/10.1016/j.jallcom.2017.02.108
- http://cer.ihtm.bg.ac.rs/handle/123456789/2191
DOI: 10.1016/j.jallcom.2017.02.108
ISSN: 0925-8388
WoS: 000397994700006
Scopus: 2-s2.0-85012965542
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IHTMTY - JOUR AU - Marković, Bojana AU - Vuković, Zorica AU - Spasojević, Vojislav AU - Kusigerski, Vladan B. AU - Pavlović, Vladimir B. AU - Onjia, Antonije E. AU - Nastasović, Aleksandra PY - 2017 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2191 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3014 AB - Magnetic macroporous crosslinked copolymer glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) samples with different magnetite content were prepared by suspension copolymerization and functionalized with diethylene triamine. Samples were characterized by elemental analysis, mercury porosimetry, Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, transmission electron microscopy, SQUID magnetometry and X-ray photoelectron spectroscopy (XPS). The selected amino-functionalized sample was tested as a potential sorbent for the Mo(VI) and Re(VII) oxyanions from aqueous solutions. The influence of pH, ionic strength and possible interfering of cations and anions was investigated. Equilibrium data were analyzed with Langmuir, Freundlich and Tempkin adsorption isotherm models. Sorption studies were carried out in a batch competitive experiments, in the pH range 1-8, at 298 K. Obtained results indicate that 92% of Re(VII) and 98% of Mo(VI) were sorbed at pH 2. PB - Elsevier T2 - Journal of Alloys and Compounds T1 - Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption VL - 705 SP - 38 EP - 50 DO - 10.1016/j.jallcom.2017.02.108 ER -
@article{ author = "Marković, Bojana and Vuković, Zorica and Spasojević, Vojislav and Kusigerski, Vladan B. and Pavlović, Vladimir B. and Onjia, Antonije E. and Nastasović, Aleksandra", year = "2017", abstract = "Magnetic macroporous crosslinked copolymer glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) samples with different magnetite content were prepared by suspension copolymerization and functionalized with diethylene triamine. Samples were characterized by elemental analysis, mercury porosimetry, Fourier transform infrared spectroscopy (FTIR) analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, transmission electron microscopy, SQUID magnetometry and X-ray photoelectron spectroscopy (XPS). The selected amino-functionalized sample was tested as a potential sorbent for the Mo(VI) and Re(VII) oxyanions from aqueous solutions. The influence of pH, ionic strength and possible interfering of cations and anions was investigated. Equilibrium data were analyzed with Langmuir, Freundlich and Tempkin adsorption isotherm models. Sorption studies were carried out in a batch competitive experiments, in the pH range 1-8, at 298 K. Obtained results indicate that 92% of Re(VII) and 98% of Mo(VI) were sorbed at pH 2.", publisher = "Elsevier", journal = "Journal of Alloys and Compounds", title = "Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption", volume = "705", pages = "38-50", doi = "10.1016/j.jallcom.2017.02.108" }
Marković, B., Vuković, Z., Spasojević, V., Kusigerski, V. B., Pavlović, V. B., Onjia, A. E.,& Nastasović, A.. (2017). Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption. in Journal of Alloys and Compounds Elsevier., 705, 38-50. https://doi.org/10.1016/j.jallcom.2017.02.108
Marković B, Vuković Z, Spasojević V, Kusigerski VB, Pavlović VB, Onjia AE, Nastasović A. Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption. in Journal of Alloys and Compounds. 2017;705:38-50. doi:10.1016/j.jallcom.2017.02.108 .
Marković, Bojana, Vuković, Zorica, Spasojević, Vojislav, Kusigerski, Vladan B., Pavlović, Vladimir B., Onjia, Antonije E., Nastasović, Aleksandra, "Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption" in Journal of Alloys and Compounds, 705 (2017):38-50, https://doi.org/10.1016/j.jallcom.2017.02.108 . .