Fullerene bisadduct regioisomers containing an asymmetric diamide tether
Article (Accepted Version)
Metadata
Show full item recordAbstract
Four macrocyclic bis(pyrrolidino)fullerene regioisomers with e-edge, e-face, trans-4 and cis-2 addition patterns were synthesized from the corresponding monoadduct by Prato's cycloaddition in a yield of 50%, and fully characterized by spectroscopic techniques. Bisadduct regioisomers were isolated easily in a pure form using dry-flash column chromatography. The relative ratio of the isolated regioisomers e-edge/e-face/trans-41cis-2 was 1.0:1.9:1.5:4.9. Morphology of self-assembled structures of the four bisadduct regioisomers in solution was characterized using scanning electron microscopy.
Keywords:
bis(pyrrolidino)fullerene regioisomers / Prato's cycloaddition / Hexamethylene-Gly-Gaba diamide tether / NMR analysis / Self-orderingSource:
Tetrahedron, 2017, 73, 50, 7073-7078Publisher:
- Oxford : Pergamon-Elsevier Science Ltd
Funding / projects:
Note:
- This is peer-reviewed version f the article: Kop TJ, Đorđević J, Bjelaković MS, Milić D, Fullerene bisadduct regioisomers containing an asymmetric diamide tether, Tetrahedron, 2017, 73, 50, 7073-7078, doi: dx.doi.org/10.1016/j.tet.2017.10.069
- http://cer.ihtm.bg.ac.rs/handle/123456789/2124
DOI: 10.1016/j.tet.2017.10.069
ISSN: 0040-4020
WoS: 000417664100011
Scopus: 2-s2.0-85032815771
Collections
Institution/Community
IHTMTY - JOUR AU - Kop, Tatjana AU - Dordevic, Jelena AU - Bjelaković, Mira AU - Milić, Dragana PY - 2017 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2124 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3004 AB - Four macrocyclic bis(pyrrolidino)fullerene regioisomers with e-edge, e-face, trans-4 and cis-2 addition patterns were synthesized from the corresponding monoadduct by Prato's cycloaddition in a yield of 50%, and fully characterized by spectroscopic techniques. Bisadduct regioisomers were isolated easily in a pure form using dry-flash column chromatography. The relative ratio of the isolated regioisomers e-edge/e-face/trans-41cis-2 was 1.0:1.9:1.5:4.9. Morphology of self-assembled structures of the four bisadduct regioisomers in solution was characterized using scanning electron microscopy. PB - Oxford : Pergamon-Elsevier Science Ltd T2 - Tetrahedron T1 - Fullerene bisadduct regioisomers containing an asymmetric diamide tether VL - 73 IS - 50 SP - 7073 EP - 7078 DO - 10.1016/j.tet.2017.10.069 ER -
@article{ author = "Kop, Tatjana and Dordevic, Jelena and Bjelaković, Mira and Milić, Dragana", year = "2017", abstract = "Four macrocyclic bis(pyrrolidino)fullerene regioisomers with e-edge, e-face, trans-4 and cis-2 addition patterns were synthesized from the corresponding monoadduct by Prato's cycloaddition in a yield of 50%, and fully characterized by spectroscopic techniques. Bisadduct regioisomers were isolated easily in a pure form using dry-flash column chromatography. The relative ratio of the isolated regioisomers e-edge/e-face/trans-41cis-2 was 1.0:1.9:1.5:4.9. Morphology of self-assembled structures of the four bisadduct regioisomers in solution was characterized using scanning electron microscopy.", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "Tetrahedron", title = "Fullerene bisadduct regioisomers containing an asymmetric diamide tether", volume = "73", number = "50", pages = "7073-7078", doi = "10.1016/j.tet.2017.10.069" }
Kop, T., Dordevic, J., Bjelaković, M.,& Milić, D.. (2017). Fullerene bisadduct regioisomers containing an asymmetric diamide tether. in Tetrahedron Oxford : Pergamon-Elsevier Science Ltd., 73(50), 7073-7078. https://doi.org/10.1016/j.tet.2017.10.069
Kop T, Dordevic J, Bjelaković M, Milić D. Fullerene bisadduct regioisomers containing an asymmetric diamide tether. in Tetrahedron. 2017;73(50):7073-7078. doi:10.1016/j.tet.2017.10.069 .
Kop, Tatjana, Dordevic, Jelena, Bjelaković, Mira, Milić, Dragana, "Fullerene bisadduct regioisomers containing an asymmetric diamide tether" in Tetrahedron, 73, no. 50 (2017):7073-7078, https://doi.org/10.1016/j.tet.2017.10.069 . .