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dc.creatorBerkesi, Kata
dc.creatorŽivković, Predrag M.
dc.creatorElezović, Nevenka
dc.creatorLačnjevac, Uroš
dc.creatorHristoforou, Evangelos
dc.creatorNikolić, Nebojša
dc.date.accessioned2019-07-01T10:48:05Z
dc.date.available2019-07-01T10:48:05Z
dc.date.issued2019
dc.identifier.issn1572-6657
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/2986
dc.description.abstractElectrodeposition of copper in the hydrogen co-deposition range by the regime of reversing current (RC) in the second range has been investigated by determination of the average current efficiency for hydrogen evolution reaction and by scanning electron (SEM) and optical (OM) microscopic analysis of the obtained deposits. Keeping the cathodic current density, the cathodic and the anodic pulses constant in all experiments, the anodic current density (ja) values were varied: 40, 80, 160, 240 and 320 mA cm−2. The Cu deposits produced by the RC regimes with different anodic current density values were compared with that obtained in a constant galvanostatic regime (DC) at the current density equal to the cathodic current density in the RC regimes. The honeycomb-like structures were formed in the DC regime and by the RC regimes with ja of 40 and 80 mA cm−2. The hole size in them was in the 60–70 μm range. Due to the decrease of quantity of evolved hydrogen with increasing anodic current density, the larger dish-like holes with dendrites at their bottom and shoulder were formed with ja values of 160, 240 and 320 mA cm−2. The maximum number of holes, and hence, the largest specific surface area of the honeycomb-like electrodes was obtained with ja = 80 mA cm−2, that can be ascribed to a suppression of coalescence of neighboring hydrogen bubbles. Application of the RC regime also led to the increase of uniformity of structures, what is concluded by cross section analysis of the formed honeycomb-like electrodes. For the first time, mechanism of Cu electrodeposition in the hydrogen co-deposition range by the RC regime in the second range was proposed and discussed.
dc.publisherElsevier BVen
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS//en
dc.relationCOST Action MP1407-STSM grant ECOST-STSM-MP1407-39458
dc.rightsrestrictedAccess
dc.sourceJournal of Electroanalytical Chemistryen
dc.subjectCopper
dc.subjectReversing current (RC) regime
dc.subjectScanning electron microscope (SEM)
dc.subjectOptical microscope (OM)
dc.subjectElectrodeposition
dc.titleMechanism of formation of the honeycomb-like structures by the regime of the reversing current (RC) in the second rangeen
dc.typearticleen
dc.rights.licenseARRen
dcterms.abstractЕлезовић, Невенка; Живковић, Предраг М.; Лачњевац, Урош; Беркеси, Ката; Христофороу, Евангелос; Николић, Небојша Д.;
dc.rights.holderElsevier BV
dc.citation.volume833
dc.citation.spage401
dc.citation.epage410
dc.citation.rankM21~
dc.description.otherPeer-reviewed version: [http://cer.ihtm.bg.ac.rs/handle/123456789/2987]
dc.identifier.doi10.1016/j.jelechem.2018.12.021
dc.identifier.scopus2-s2.0-85058668102
dc.identifier.wos000456759900048
dc.type.versionpublishedVersion


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