Приказ основних података о документу
Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction
dc.creator | Džambaski, Zdravko | |
dc.creator | Tzaras, Dimitrios‐Ioannis | |
dc.creator | Lee, Sunggi | |
dc.creator | Kokotos, Christoforos G. | |
dc.creator | Bondžić, Bojan | |
dc.date.accessioned | 2019-06-28T13:11:33Z | |
dc.date.available | 2020-02-01 | |
dc.date.issued | 2019 | |
dc.identifier.issn | 1615-4150 | |
dc.identifier.issn | 1615-4169 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/2954 | |
dc.description.abstract | α,β‐unsaturated aldehydes have been traditionally used in LUMO lowering asymmetric aminocatalysis (iminium catalysis), while the use of saturated aldehydes as substrates in this type of catalysis has been elusive, until recently. Herein, we demonstrate that organic, single‐electron oxidants in the presence of diarylprolinol silylether type catalysts serve as effective tools for the transformation of electron rich enamines to iminium ions which partake in a subsequent Diels‐Alder reaction. This enantioselective one‐pot transformation represents the first example of saturated aldehydes being used in domino Diels‐Alder reaction processes and demonstrates the power of this protocol for construction of stereo‐defined chiral compounds and building blocks. | en |
dc.publisher | Wiley | en |
dc.relation | COST action CA15106: CH activation in organic synthesis (CHAOS) | en |
dc.relation | Special Account for Research Grants of the National and Kapodistrian University of Athens | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172020/RS// | |
dc.rights | embargoedAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Advanced Synthesis & Catalysis | en |
dc.subject | Asymmetric catalysis | |
dc.subject | Cycloaddition | |
dc.subject | C−H oxidation | |
dc.subject | Diarylprolinols | |
dc.subject | Organocatalysis | |
dc.title | Enantioselective Organocatalytic Enamine C−H Oxidation/Diels‐ Alder Reaction | en |
dc.type | article | en |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Кокотос, Цхристофорос Г.; Лее, Сунгги; Бондзиц, Бојан П.; Тзарас, Димитриос‐Иоаннис; Джамбаски, Здравко; | |
dc.citation.volume | 361 | |
dc.citation.issue | 8 | |
dc.citation.spage | 1792 | |
dc.citation.epage | 1797 | |
dc.citation.rank | aM21~ | |
dc.description.other | This is peer-reviewed version of the article: Zdravko Dzambaski, Dimitrios Ioannis Tzaras, Sunggi Lee, Christoforos Kokotos, and Bojan Bondzic, Advanced Synthesis & Catalysis, 2019, 361, 8, 1792-1797, [http://dx.doi.org/10.1002/adsc.201900061] | |
dc.description.other | [http://cer.ihtm.bg.ac.rs/handle/123456789/2953] | |
dc.identifier.doi | 10.1002/adsc.201900061 | |
dc.identifier.fulltext | https://cer.ihtm.bg.ac.rs/bitstream/id/7212/10.1002_adsc.201900061.pdf | |
dc.identifier.scopus | 2-s2.0-85061776252 | |
dc.identifier.wos | 000467075800011 | |
dc.type.version | acceptedVersion |